Search Results - "PINK, Maren"
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1
Thermally and Magnetically Robust Triplet Ground State Diradical
Published in Journal of the American Chemical Society (20-03-2019)“…High spin (S = 1) organic diradicals may offer enhanced properties with respect to several emerging technologies, but typically exhibit low singlet triplet…”
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2
Tunable Adhesion from Stoichiometry-Controlled and Sequence-Defined Supramolecular Polymers Emerges Hierarchically from Cyanostar-Stabilized Anion–Anion Linkages
Published in Journal of the American Chemical Society (05-02-2020)“…Sequence-controlled supramolecular polymers offer new design paradigms for generating stimuli-responsive macromolecules with enhanced functionalities. The…”
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3
Catalytic Carbodiimide Guanylation by a Nucleophilic, High Spin Iron(II) Imido Complex
Published in Journal of the American Chemical Society (14-04-2021)“…Reduction of the three-coordinate iron(III) imido [Ph2B( t BuIm)2FeNDipp] (1) affords [Ph2B( t BuIm)2FeNDipp][K(18-C-6)THF2] (2), a rare example of a…”
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4
Synthesis and Thin Films of Thermally Robust Quartet (S = 3/2) Ground State Triradical
Published in Journal of the American Chemical Society (14-04-2021)“…High-spin (S = 3/2) organic triradicals may offer enhanced properties with respect to several emerging technologies, but those synthesized to date typically…”
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5
Synthesis and Reduction Kinetics of Sterically Shielded Pyrrolidine Nitroxides
Published in Organic letters (19-10-2012)“…A series of sterically shielded pyrrolidine nitroxides were synthesized, and their reduction by ascorbate (vitamin C) indicate that nitroxide 3, a tetraethyl…”
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6
Anions Stabilize Each Other inside Macrocyclic Hosts
Published in Angewandte Chemie International Edition (02-11-2016)“…Contrary to the simple expectations from Coulomb's law, Weinhold proposed that anions can stabilize each other as metastable dimers, yet experimental evidence…”
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7
Structural and spectroscopic characterization of an Fe(VI) bis(imido) complex
Published in Science (American Association for the Advancement of Science) (16-10-2020)“…Nitrogen lifts iron to hexavalence The myriad ways that iron can interact with oxygen have been amply studied in biochemical and geochemical contexts. More…”
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8
Linear Supramolecular Polymers Driven by Anion–Anion Dimerization of Difunctional Phosphonate Monomers Inside Cyanostar Macrocycles
Published in Journal of the American Chemical Society (27-03-2019)“…Supramolecular polymers have enabled far-reaching fundamental science and the development of diverse macromolecular technologies owing to the reversible and…”
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9
Influence of Iron Oleate Complex Structure on Iron Oxide Nanoparticle Formation
Published in Chemistry of materials (24-07-2007)“…The dependence of iron oxide nanoparticle formation on the structure and thermal properties of Fe oleate complexes has been studied using FTIR, elemental…”
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10
Stereoinversion of Unactivated Alcohols by Tethered Sulfonamides
Published in Angewandte Chemie International Edition (04-02-2019)“…The direct, catalytic substitution of unactivated alcohols remains an undeveloped area of organic synthesis. Moreover, catalytic activation of this difficult…”
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11
A Low Spin Manganese(IV) Nitride Single Molecule Magnet
Published in Chemical science (Cambridge) (01-01-2016)“…Structural, spectroscopic and magnetic methods have been used to characterize the tris(carbene)borate compound PhB(MesIm) Mn≡N as a four-coordinate…”
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12
Layer-by-Layer Synthesis of Metal-Containing Conducting Polymers: Caged Metal Centers for Interlayer Charge Transport
Published in Journal of the American Chemical Society (01-09-2010)“…Metal-templated [2 + 3]-type cocondensation of a π-extended boronic acid and nioxime furnished a series of cage molecules, which were electropolymerized to…”
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13
Extreme Stabilization and Redox Switching of Organic Anions and Radical Anions by Large-Cavity, CH Hydrogen-Bonding Cyanostar Macrocycles
Published in Journal of the American Chemical Society (16-11-2016)“…Encapsulation of unstable guests is a powerful way to enhance their stability. The lifetimes of organic anions and their radicals produced by reduction are…”
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14
Enantioselective Organocatalytic Amine-Isocyanate Capture-Cyclization: Regioselective Alkene Iodoamination for the Synthesis of Chiral Cyclic Ureas
Published in ACS catalysis (07-12-2018)“…Ureas of chiral diamines are prominent features of therapeutics, chiral auxiliaries, and intermediates in complex molecule synthesis. Although many methods for…”
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15
Electron and Oxygen Atom Transfer Chemistry of Co(II) in a Proton Responsive, Redox Active Ligand Environment
Published in Inorganic chemistry (21-05-2018)“…The bis-pyrazolato pyridine complex LCo(PEt3)2 serves as a masked form of three-coordinate CoII and shows diverse reactivity in its reaction with several…”
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16
Cross-Conjugated Oligothiophenes Derived from the (C2S) n Helix: Asymmetric Synthesis and Structure of Carbon−Sulfur [11]Helicene
Published in Journal of the American Chemical Society (12-10-2005)“…(−)-Sparteine-mediated asymmetric synthesis of di-n-octyl-substituted carbon−sulfur [11]helicene, a helical (C2S) n β-undecathiophene, is described. The…”
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17
Multi-state amine sensing by electron transfers in a BODIPY probe
Published in Organic & biomolecular chemistry (22-01-2020)“…Amines are ubiquitous in the chemical industry and are present in a wide range of biological processes, motivating the development of amine-sensitive sensors…”
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18
Catalytic Hydrosilylation of the Carbonyl Functionality via a Transient Nickel Hydride Complex
Published in Organometallics (13-04-2009)“…We report the syntheses and characterization of two new sterically demanding chelate ligands, denoted PNMe3…”
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19
Ligand Substituent Effects in Manganese Pyridinophane Complexes: Implications for Oxygen-Evolving Catalysis
Published in Inorganic chemistry (20-11-2017)“…A series of Mn(II) complexes of differently substituted pyridinophane ligands, (Py2NR2)MnCl2 (R = i Pr, Cy) and [(Py2NR2)MnF2](PF6) (R = i Pr, Cy, t Bu)…”
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20
Noncovalent Interactions in the Asymmetric Synthesis of Rigid, Conjugated Helical Structures
Published in Angewandte Chemie (International ed.) (01-01-2009)“…From helical folding to helical locking: Tetrakis(β‐trithiophene) 1 folds into a helical conformation (RRR) that facilitates double ring annelation, with high…”
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