Search Results - "PEINTLER, Gabor"
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Coordination motifs of binary neodymium(III) D-gluconate, D-galactonate and L-gulonate complexes and the transition from inner- to outer-sphere coordination in neutral to strongly alkaline medium
Published in Journal of molecular structure (05-08-2022)“…•D-gluconate, D-galactonate and L-gulonate form complexes with Nd(III) atpH = 5–13.•The carboxylate group has an essential role in the coordination of…”
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Mn(II)–amino acid complexes intercalated in CaAl-layered double hydroxide – Well-characterized, highly efficient, recyclable oxidation catalysts
Published in Journal of catalysis (01-03-2016)“…[Display omitted] •Synthesis of pristine and Mn–amino acid intercalated CaAl-LDHs by two methods.•Identifying the samples having the complex exclusively among…”
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3
Revisiting the hydrolysis of ampicillin catalyzed by Temoneira‐1 β‐lactamase, and the effect of Ni(II), Cd(II) and Hg(II)
Published in Protein science (01-12-2023)“…β‐Lactamases grant resistance to bacteria against β‐lactam antibiotics. The active center of TEM‐1 β‐lactamase accommodates a Ser‐Xaa‐Xaa‐Lys motif. TEM‐1…”
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4
Dynamic origin of the surface conduction response in adsorption-induced electrical processes
Published in Chemical physics letters (27-06-2014)“…•Many adsorbent–adsorbate pairs exhibit a similar electrical conductivity response.•This is a universal phenomenon, which is not yet explained in the…”
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5
Configuration-dependent complex formation between Ca(II) and sugar carboxylate ligands in alkaline medium: Comparison of L-gulonate with D-gluconate and D-heptaguconate
Published in Carbohydrate research (02-05-2018)“…The calcium sugar carboxylate interactions in hyperalkaline solutions are of relevance in radioactive waste repositories and in certain industrial processes…”
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Stability and structural aspects of complexes forming between aluminum(III) and D-heptagluconate in acidic to strongly alkaline media: An unexpected diversity
Published in Journal of molecular liquids (15-09-2020)“…In the current contribution, the complex formation equilibria between Al3+ and α-D–heptagluconate (Hpgl−) ions, which is of relevance in, e.g., the Bayer…”
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Temperature dependence of the acid–base and Ca2+-complexation equilibria of d-gluconate in hyperalkaline aqueous solutions
Published in Polyhedron (15-01-2019)“…The composition and formation constants of the polynuclear calcium gluconate complexes forming in hypersaline and hyperalkaline conditions were determined up…”
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Formation of mono- and binuclear complexes of Nd3+ with d-gluconate ions in hyperalkaline solutions – Composition, equilibria and structure
Published in Journal of molecular liquids (15-01-2022)“…•Equilibria in strongly alkaline solutions of Nd3+ and d-gluconate were studied.•Formation of mono- and binuclear complexes was proven in solutions of…”
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The formation of Ca(II) enolato complexes with α- and β-ketoglutarate in strongly alkaline solutions
Published in Polyhedron (01-12-2018)“…In hyperalkaline aqueous solutions the calcium ion is capable of forming rare Ca2+-enolato type mono- and polynuclear chelate complexes both with α- and with…”
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Formation of mono- and binuclear neodymium(iii)-gluconate complexes in aqueous solutions in the pH range of 2-8
Published in Dalton transactions : an international journal of inorganic chemistry (09-05-2017)“…The complex formation between Nd(iii) and d-gluconate (Gluc ) is of relevance in modelling the chemical equilibria of radioactive waste repositories. In the…”
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The acidity and self-catalyzed lactonization of l-gulonic acid: Thermodynamic, kinetic and computational study
Published in Carbohydrate research (01-09-2018)“…Lactonization and proton dissociation of sugar acids take place simultaneously in acidic aqueous solutions. The protonation-deprotonation processes are always…”
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Calcium complexing behaviour of lactate in neutral to highly alkaline medium
Published in Journal of molecular structure (15-03-2019)“…The calcium complexing properties as well as the acid-base behaviour of d,l-lactate have been investigated in both neutral and alkaline media by Ca-ISE…”
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Some aspects of the aqueous solution chemistry of the Na+/Ca2+/OH−/Cit3− system: The structure of a new calcium citrate complex forming under hyperalkaline conditions
Published in Journal of molecular structure (15-08-2016)“…In the present study, we show that in hyperalkaline (pH > 13) aqueous solutions, Ca2+ forms a new, so far unknown complex species with the citrate ion, the…”
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14
Exploring the boundaries of direct detection and characterization of labile isomers - a case study of copper(ii)-dipeptide systems
Published in Dalton transactions : an international journal of inorganic chemistry (27-06-2017)“…The investigation of the linkage isomers of biologically essential and kinetically labile metal complexes in aqueous solutions poses a challenge, as these…”
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Complexation of Al(III) with gluconate in alkaline to hyperalkaline solutions: formation, stability and structure
Published in Dalton transactions : an international journal of inorganic chemistry (07-10-2013)“…Contrary to suggestions in the literature, it has been proven that Al(III) forms a 1 : 1 complex with gluconate (hereafter Gluc(-)) in strongly alkaline (pH >…”
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The solubility of Ca(OH)2 in extremely concentrated NaOH solutions at 25°C
Published in Open Chemistry (01-04-2012)Get full text
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Using low-frequency IR spectra for the unambiguous identification of metal ion–ligand coordination sites in purpose-built complexes
Published in Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy (25-03-2014)“…[Display omitted] •Registering the far IR spectra of metal ion-monofunctional ligand complexes.•Assigning metal ion–Nimidazole(amino) or metal…”
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Speciation and structure of tin(II) in hyper-alkaline aqueous solution
Published in Dalton transactions : an international journal of inorganic chemistry (28-12-2014)“…The identity of the predominating tin(ii)-hydroxide complex formed in hyper-alkaline aqueous solutions (0.2 ≤CNaOH≤ 12 mol dm(-3)) is determined by…”
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Effect of Chloride Ion on the Kinetics and Mechanism of the Reaction between Chlorite Ion and Hypochlorous Acid
Published in Inorganic chemistry (01-09-2008)“…The effect of chloride ion on the chlorine dioxide formation in the ClO2 −−HOCl reaction was studied by following ·ClO2 concentration spectrophotometrically at…”
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Determination of Reaction Stoichiometry by Applying Job’s Method and Digital Image Processing for Precipitation Reactions
Published in Journal of chemical education (12-03-2024)“…Herein we present a simple test tube experiment to demonstrate the application of Job’s method for the determination of reaction stoichiometry in high school…”
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