Search Results - "Oswald, Victoria F."
-
1
Effects of Noncovalent Interactions on High-Spin Fe(IV)–Oxido Complexes
Published in Journal of the American Chemical Society (08-07-2020)“…High-valent nonheme FeIV–oxido species are key intermediates in biological oxidation, and their properties are proposed to be influenced by the unique…”
Get full text
Journal Article -
2
Towards Catalytic Ammonia Oxidation to Dinitrogen: A Synthetic Cycle by Using a Simple Manganese Complex
Published in Chemistry : a European journal (25-08-2017)“…Oxidation of the nucleophilic nitride, (salen)Mn≡N (1) with stoichiometric [Ar3N][X] initiated a nitride coupling reaction to N2, a major step toward catalytic…”
Get full text
Journal Article -
3
Tyrosine-Coordinated P‑Cluster in G. diazotrophicus Nitrogenase: Evidence for the Importance of O‑Based Ligands in Conformationally Gated Electron Transfer
Published in Journal of the American Chemical Society (17-08-2016)“…The P-cluster is a unique iron–sulfur center that likely functions as a dynamic electron (e–) relay site between the Fe-protein and the catalytic FeMo-cofactor…”
Get full text
Journal Article -
4
Identification of the Active Catalyst for Nickel‐Catalyzed Stereospecific Kumada Coupling Reactions of Ethers
Published in Chemistry : a European journal (09-03-2020)“…A series of nickel complexes in varying oxidation states were evaluated as precatalysts for the stereospecific cross‐coupling of benzylic ethers. These results…”
Get full text
Journal Article -
5
Stepwise assembly of heterobimetallic complexes: synthesis, structure, and physical properties
Published in Dalton transactions : an international journal of inorganic chemistry (15-06-2021)“…Bimetallic active sites are ubiquitous in metalloenzymes and have sparked investigations of synthetic models to aid in the establishment of structure-function…”
Get more information
Journal Article -
6
Manganese–Hydroxido Complexes Supported by a Urea/Phosphinic Amide Tripodal Ligand
Published in Inorganic chemistry (05-11-2018)“…Hydrogen bonds (H-bonds) within the secondary coordination sphere are often invoked as essential noncovalent interactions that lead to productive chemistry in…”
Get full text
Journal Article -
7
Probing Hydrogen Bonding Interactions to Iron-Oxido/Hydroxido Units by 57 Fe Nuclear Resonance Vibrational Spectroscopy
Published in Angewandte Chemie (International ed.) (03-12-2018)“…Hydrogen bonds (H-bonds) have been shown to modulate the chemical reactivities of iron centers in iron-containing dioxygen-activating enzymes and model…”
Get full text
Journal Article -
8
Probing Hydrogen Bonding Interactions to Iron‐Oxido/Hydroxido Units by 57Fe Nuclear Resonance Vibrational Spectroscopy
Published in Angewandte Chemie International Edition (03-12-2018)“…Hydrogen bonds (H‐bonds) have been shown to modulate the chemical reactivities of iron centers in iron‐containing dioxygen‐activating enzymes and model…”
Get full text
Journal Article -
9
Frontispiece: Towards Catalytic Ammonia Oxidation to Dinitrogen: A Synthetic Cycle by Using a Simple Manganese Complex
Published in Chemistry : a European journal (25-08-2017)“…Using ammonia as a clean hydrogen storage medium, and subsequent utilization as an energy source, requires an understanding of the multi‐electron ammonia…”
Get full text
Journal Article -
10
Hemilabile Proton Relays and Redox Activity Lead to {FeNO} x and Significant Rate Enhancements in NO 2 - Reduction
Published in Journal of the American Chemical Society (12-12-2018)“…Incorporation of the triad of redox activity, hemilability, and proton responsivity into a single ligand scaffold is reported. Due to this triad, the complexes…”
Get full text
Journal Article -
11
Hemilabile Proton Relays and Redox Activity Lead to {FeNO} x and Significant Rate Enhancements in NO2 – Reduction
Published in Journal of the American Chemical Society (12-12-2018)“…Incorporation of the triad of redox activity, hemilability, and proton responsivity into a single ligand scaffold is reported. Due to this triad, the complexes…”
Get full text
Journal Article -
12
KO t Bu-Initiated Aryl C–H Iodination: A Powerful Tool for the Synthesis of High Electron Affinity Compounds
Published in Journal of the American Chemical Society (30-03-2016)“…An efficient iodination reaction of electron-deficient heterocycles is described. The reaction utilizes KO t Bu as an initiator and likely proceeds by a…”
Get full text
Journal Article -
13
Overexpression, purification, and enthalpy of unfolding of ferricytochrome c552 from a psychrophilic microorganism
Published in Journal of inorganic biochemistry (01-02-2014)“…The psychrophilic, hydrocarbonoclastic microorganism Colwellia psychrerythraea is important in global nutrient cycling and bioremediation. In order to…”
Get full text
Journal Article -
14
Rücktitelbild: Probing Hydrogen Bonding Interactions to Iron‐Oxido/Hydroxido Units by 57Fe Nuclear Resonance Vibrational Spectroscopy (Angew. Chem. 49/2018)
Published in Angewandte Chemie (03-12-2018)“…Die Stärke der Wasserstoffbrücken in Eisen(III)‐Oxido/Hydroxido‐Einheiten (FeIII‐O/OH) in Nichthäm‐Eisenkomplexen wird durch…”
Get full text
Journal Article -
15
Probing Hydrogen Bonding Interactions to Iron‐Oxido/Hydroxido Units by 57Fe Nuclear Resonance Vibrational Spectroscopy
Published in Angewandte Chemie (03-12-2018)“…Hydrogen bonds (H‐bonds) have been shown to modulate the chemical reactivities of iron centers in iron‐containing dioxygen‐activating enzymes and model…”
Get full text
Journal Article -
16
-
17
Back Cover: Probing Hydrogen Bonding Interactions to Iron‐Oxido/Hydroxido Units by 57Fe Nuclear Resonance Vibrational Spectroscopy (Angew. Chem. Int. Ed. 49/2018)
Published in Angewandte Chemie International Edition (03-12-2018)“…Hydrogen bond strength to iron(III)–oxido/hydroxido (FeIII–O/OH) units in nonheme iron complexes is revealed by FeIII–O/OH stretching vibrations detected with…”
Get full text
Journal Article -
18
Probing hydrogen bonding interactions to iron-oxido/hydroxido units via 57Fe nuclear resonance vibrational spectroscopy
Published in Angewandte Chemie International Edition (14-11-2018)“…Hydrogen bonds (H-bonds) have been shown to modulate the chemical reactivities of iron centers in iron-containing dioxygen-activating enzymes and model…”
Get full text
Journal Article -
19
Effects of Non-covalent Interactions on High-spin Fe(IV)–oxido Complexes
Published in Journal of the American Chemical Society (24-06-2020)“…High-valent non-heme Fe IV –oxido species are key intermediates in biological oxidation, and their properties are proposed to be influenced by the unique…”
Get full text
Journal Article -
20
Tripodal Phosphoryl Amide Frameworks: Investigating The Relationship Between High Valent Metal-Oxido And Metal-Hydroxido Complexes
Published 01-01-2018“…Metal ion cofactors within active sites are essential components for many proteins and have been directly linked to function. Active sites contain either a…”
Get full text
Dissertation