Search Results - "Orth, Nicole"
-
1
Self-assembled M12L24 nanospheres as a reaction vessel to facilitate a dinuclear Cu(i) catalyzed cyclization reaction
Published in Chemical science (Cambridge) (2019)“…The application of large M12L24 nanospheres allows the pre-concentration of catalysts to reach high local concentrations, facilitating reactions that proceed…”
Get full text
Journal Article -
2
A “Pretender” Croconate-Bridged Macrocyclic Tetraruthenium Complex: Sizable Redox Potential Splittings despite Electronically Insulated Divinylphenylene Diruthenium Entities
Published in Molecules (Basel, Switzerland) (29-08-2021)“…Careful optimization of the reaction conditions provided access to the particularly small tetraruthenium macrocycle 2Ru2Ph-Croc, which is composed out of two…”
Get full text
Journal Article -
3
On the Way to a Trisanionic {Cu3O2} Core for Oxidase Catalysis: Evidence of an Asymmetric Trinuclear Precursor Stabilized by Perfluoropinacolate Ligands
Published in Chemistry : a European journal (16-06-2017)“…CuI complexes of the form K[(R3P)Cu(pinF)], in which (pinF)2− is the bidentate, oxygen‐donating ligand perfluoropinacolate, were synthesized and characterized…”
Get full text
Journal Article -
4
An Isolable Terminal Imido Complex of Palladium and Catalytic Implications
Published in Angewandte Chemie International Edition (03-12-2018)“…Herein, we report the isolation and a reactivity study of the first example of an elusive palladium(II) terminal imido complex. This scaffold is an alleged key…”
Get full text
Journal Article -
5
Self-assembled M12L24 nanospheres as a reaction vessel to facilitate a dinuclear Cu(i) catalyzed cyclization reaction† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c8sc03767a
Published in Chemical science (Cambridge) (07-02-2019)“…The application of large M 12 L 24 nanospheres allows the pre-concentration of catalysts to reach high local concentrations, facilitating reactions that…”
Get full text
Journal Article -
6
Control over Electrochemical Water Oxidation Catalysis by Preorganization of Molecular Ruthenium Catalysts in Self‐Assembled Nanospheres
Published in Angewandte Chemie International Edition (27-08-2018)“…Oxygen formation through water oxidation catalysis is a key reaction in the context of fuel generation from renewable energies. The number of homogeneous…”
Get full text
Journal Article -
7
Hydrogenase Mimics in M12L24 Nanospheres to Control Overpotential and Activity in Proton‐Reduction Catalysis
Published in Angewandte Chemie International Edition (12-10-2020)“…Hydrogenase enzymes are excellent proton reduction catalysts and therefore provide clear blueprints for the development of nature‐inspired synthetic analogues…”
Get full text
Journal Article -
8
Hydrogenase Mimics in M 12 L 24 Nanospheres to Control Overpotential and Activity in Proton-Reduction Catalysis
Published in Angewandte Chemie International Edition (12-10-2020)“…Hydrogenase enzymes are excellent proton reduction catalysts and therefore provide clear blueprints for the development of nature-inspired synthetic analogues…”
Get full text
Journal Article -
9
Catalytic H 2 O 2 Activation by a Diiron Complex for Methanol Oxidation
Published in Inorganic chemistry (02-11-2020)Get full text
Journal Article -
10
Redox-Induced Hydrogen Bond Reorientation Mimicking Electronic Coupling in Mixed-Valent Diruthenium and Macrocyclic Tetraruthenium Complexes
Published in Inorganic chemistry (16-11-2020)“…We present the coordination-driven self-assembly of three tetranuclear metallacycles containing intracyclic NH2, OH, or OMe functionalities through the…”
Get full text
Journal Article -
11
Catalytic H2O2 Activation by a Diiron Complex for Methanol Oxidation
Published in Inorganic chemistry (02-11-2020)“…In nature, C–H bond oxidation of CH4 involves a peroxo intermediate that decays to the high-valent active species of either a “closed” {FeIV(μ-O)2FeIV} core or…”
Get full text
Journal Article -
12
Structural Versatility and Supramolecular Isomerism in Redox‐Active Tetra‐ and Hexaruthenium Macrocycles
Published in European journal of inorganic chemistry (09-08-2020)“…We report on six macrocyclic tetra‐ and hexaruthenium complexes formed by the self‐assembly of 2,5‐divinylthiophene‐ or 2,5‐divinylfuran‐bridged diruthenium…”
Get full text
Journal Article -
13
Two Unsupported Terminal Hydroxido Ligands in a μ‑Oxo-Bridged Ferric Dimer: Protonation and Kinetic Lability Studies
Published in Inorganic chemistry (20-08-2018)“…The dinuclear complex [(susan){FeIII(OH)(μ-O)FeIII(OH)}](ClO4)2 (Fe 2 (OH) 2 (ClO4)2; susan =…”
Get full text
Journal Article -
14
Self-Assembled Redox-Active Tetraruthenium Macrocycles with Large Intracyclic Cavities
Published in Organometallics (26-05-2020)“…We report on five tetranuclear metallamacrocycles with particularly large inner voids of up to 19.4 × 18.9 Å. The macrocyclic complexes were obtained by the…”
Get full text
Journal Article -
15
Designed To React: Terminal Copper Nitrenes and Their Application in Catalytic C−H Aminations
Published in Angewandte Chemie International Edition (16-07-2018)“…Heteroscorpionate ligands of the bis(pyrazolyl)methane family have been applied in the stabilisation of terminal copper tosyl nitrenes. These species are…”
Get full text
Journal Article -
16
Self-assembled M12L24 nanospheres as a reaction vessel to facilitate a dinuclear Cu(i) catalyzed cyclization reactionElectronic supplementary information (ESI) available. See DOI: 10.1039/c8sc03767a
Published 30-01-2019“…The application of large M 12 L 24 nanospheres allows the pre-concentration of catalysts to reach high local concentrations, facilitating reactions that…”
Get full text
Journal Article -
17
Self-assembled M 12 L 24 nanospheres as a reaction vessel to facilitate a dinuclear Cu(i) catalyzed cyclization reaction
Published in Chemical science (Cambridge) (07-02-2019)“…The application of large M L nanospheres allows the pre-concentration of catalysts to reach high local concentrations, facilitating reactions that proceed…”
Get full text
Journal Article -
18
Synthesis of a Hybrid between SOD Mimetic and Ebselen to Target Oxidative Stress
Published in European journal of inorganic chemistry (14-07-2019)“…Oxidative stress emerged as target in drug discovery due to its diverse role in various diseases, such as cardiovascular, neurodegenerative, and autoimmune…”
Get full text
Journal Article -
19
Hydrogenase Mimics in M 12 L 24 Nanospheres to Control Overpotential and Activity in Proton‐Reduction Catalysis
Published in Angewandte Chemie (12-10-2020)“…Abstract Hydrogenase enzymes are excellent proton reduction catalysts and therefore provide clear blueprints for the development of nature‐inspired synthetic…”
Get full text
Journal Article -
20
Hydrogenase Mimics in M12 L24 Nanospheres to Control Overpotential and Activity in Proton-Reduction Catalysis
Published in Angewandte Chemie International Edition (12-10-2020)“…Hydrogenase enzymes are excellent proton reduction catalysts and therefore provide clear blueprints for the development of nature-inspired synthetic analogues…”
Get full text
Journal Article