Search Results - "Orsino, Alessio"

Nickel-Catalyzed Alkyne Cyclotrimerization Assisted by a Hemilabile Acceptor Ligand: A Computational Study by Orsino, Alessio F, Moret, Marc-Etienne

“…π-coordinating units incorporated in the supporting ligand of an organometallic complex may open up specific reactive pathways. The diphosphine ketone…”
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Enhanced Catalytic Activity of Nickel Complexes of an Adaptive Diphosphine–Benzophenone Ligand in Alkyne Cyclotrimerization by Orsino, Alessio F, Gutiérrez del Campo, Manuel, Lutz, Martin, Moret, Marc-Etienne

“…Adaptive ligands, which can adapt their coordination mode to the electronic structure of various catalytic intermediates, offer the potential to develop…”
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Programming big data analysis: principles and solutions by Belcastro, Loris, Cantini, Riccardo, Marozzo, Fabrizio, Orsino, Alessio, Talia, Domenico, Trunfio, Paolo

“…In the age of the Internet of Things and social media platforms, huge amounts of digital data are generated by and collected from many sources, including…”
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Xai-driven knowledge distillation of large language models for efficient deployment on low-resource devices by Cantini, Riccardo, Orsino, Alessio, Talia, Domenico

“…Large Language Models (LLMs) are characterized by their inherent memory inefficiency and compute-intensive nature, making them impractical to run on…”
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Edge-cloud continuum solutions for urban mobility prediction and planning by Belcastro, Loris, Marozzo, Fabrizio, Orsino, Alessio, Talia, Domenico, Trunfio, Paolo

“…In recent years, there has been an increase in the use of edge-cloud continuum solutions to efficiently collect and analyze data generated by IoT devices. In…”
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Cooperative Si–H Addition to Side-On Ni(0)-Imine Complexes Forms Reactive Hydrosilazane Complexes by Verhoeven, Dide G. A, Orsino, Alessio F, Bienenmann, Roel L. M, Lutz, Martin, Moret, Marc-Etienne

“…Activation of a Si–H bond is commonly a critical step in catalytic hydrosilylation reactions. Herein, we investigate the cooperative reactivity of Ni(0)…”
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Versatile Coordination and C–C Coupling of Diphosphine-Tethered Imine Ligands with Ni(II) and Ni(0) by Verhoeven, Dide G. A, Negenman, Hidde A, Orsino, Alessio F, Lutz, Martin, Moret, Marc-Etienne

“…Ligands that can adapt their coordination mode to the electronic properties of a metal center are of interest to support catalysis or small molecule activation…”
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Exploiting Machine Learning for Improving In-Memory Execution of Data-Intensive Workflows on Parallel Machines by Cantini, Riccardo, Marozzo, Fabrizio, Orsino, Alessio, Talia, Domenico, Trunfio, Paolo

“…Workflows are largely used to orchestrate complex sets of operations required to handle and process huge amounts of data. Parallel processing is often vital to…”
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Block size estimation for data partitioning in HPC applications using machine learning techniques by Cantini, Riccardo, Marozzo, Fabrizio, Orsino, Alessio, Talia, Domenico, Trunfio, Paolo, Badia, Rosa M., Ejarque, Jorge, Vázquez-Novoa, Fernando

“…The extensive use of HPC infrastructures and frameworks for running data-intensive applications has led to a growing interest in data partitioning techniques…”
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Nickel-Catalyzed Diastereoselective Alkyl–Alkyl Kumada Coupling Reactions by Perez Garcia, Pablo M, Di Franco, Thomas, Orsino, Alessio, Ren, Peng, Hu, Xile

“…A nickel pincer complex is found to catalyze alkyl–alkyl Kumada coupling reactions of 1,3- and 1,4-substituted cyclohexyl halides and tetrahydropyrans with an…”
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Are Large Language Models Really Bias-Free? Jailbreak Prompts for Assessing Adversarial Robustness to Bias Elicitation by Cantini, Riccardo, Cosenza, Giada, Orsino, Alessio, Talia, Domenico

“…Large Language Models (LLMs) have revolutionized artificial intelligence, demonstrating remarkable computational power and linguistic capabilities. However,…”
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Scaling Machine Learning at the Edge-Cloud: A Distributed Computing Perspective by Marozzo, Fabrizio, Orsino, Alessio, Talia, Domenico, Trunfio, Paolo

“…The widespread diffusion of Internet of Things (IoT) devices has led to an exponential growth in the volume of data generated at the edge of the network. With…”
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Using the Compute Continuum for Data Analysis: Edge-cloud Integration for Urban Mobility by Belcastro, Loris, Marozzo, Fabrizio, Orsino, Alessio, Talia, Domenico, Trunfio, Paolo

“…More and more in recent years, IT companies have adopted edge-cloud continuum solutions to efficiently perform analysis tasks on data generated by IoT devices…”
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Edge Computing Solutions for Distributed Machine Learning by Marozzo, Fabrizio, Orsino, Alessio, Talia, Domenico, Trunfio, Paolo

“…The rapid spread of the Internet of Things (IoT), with billions of connected devices, has generated huge amounts of data and asks for decentralized solutions…”
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A visual tool for reducing returns in e-commerce platforms by Cantini, Riccardo, Marozzo, Fabrizio, Orsino, Alessio, Passarelli, Martina, Trunfio, Paolo

“…Nowadays, the number of people who prefer to make online purchases on e-commerce platforms is constantly increasing. Online shopping turns out to be fast and…”
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Block size estimation for data partitioning in HPC applications using machine learning techniques by Cantini, Riccardo, Marozzo, Fabrizio, Orsino, Alessio, Talia, Domenico, Trunfio, Paolo, Badia, Rosa M, Ejarque, Jorge, Vazquez, Fernando

“…Journal of Big Data, vol. 11, n. 19, 2024 The extensive use of HPC infrastructures and frameworks for running dataintensive applications has led to a growing…”
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