Search Results - "Orpen, A.Guy"

Synthesis and properties of new tris(cyanoethyl)phosphine complexes of platinum (0,II), palladium (0,II), iridium (I) and rhodium (I) by Orpen, A.Guy, Pringle, Paul G., Smith, Martin B., Worboys, Kerry

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Oxidative addition of boron–boron, boron–chlorine and boron–bromine bonds to platinum(0)1Dedicated to Professor Ken Wade on the occasion of his 65th birthday and in recognition of his outstanding contributions to the understanding of the chemistry of boron.1 by Clegg, William, Lawlor, Fiona J., Lesley, Gerry, Marder, Todd B., Norman, Nicholas C., Orpen, A.Guy, Quayle, Michael J., Rice, Craig R., Scott, Andrew J., Souza, Fabio E.S.

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Oxidative addition of boron–boron, boron–chlorine and boron–bromine bonds to platinum(0) by Clegg, William, Lawlor, Fiona J., Lesley, Gerry, Marder, Todd B., Norman, Nicholas C., Orpen, A.Guy, Quayle, Michael J., Rice, Craig R., Scott, Andrew J., Souza, Fabio E.S.

“…The synthesis and spectroscopic characterisation of the new diborane(4) compounds B 2(1,2-O 2C 6Cl 4) 2 and B 2(1,2-O 2C 6Br 4) 2 are reported together with…”
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The preparation and structural characterisation of thiolato anions of bismuth(III) by Charmant, Jonathan P.H., Jahan, A.H.M.Monowar, Norman, Nicholas C., Orpen, A.Guy

“…The preparation and structures of the bismuth thiolato anions [Bi 2(SC 6F 5) 6(μ-SC 6F 5)] − and [Bi 2(SC 6F 5) 6(μ-SC 6F 5) 2] 2− and the halothiolato anions…”
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para-Ethynyl aniline as a building block for fully π-conjugated ligands and acetylide complexes: crystal structures of trans-[Pt(PPh 3) 2(CCC 6H 4NH 2) 2] and [(μ-H)Ru 3(CO) 9(μ 3-CCC 6H 4NH 2)] by Deeming, Antony J, Hogarth, Graeme, Lee, Mo-yin (Venus), Saha, Malini, Redmond, Simon P, Phetmung, Hirihattaya (Taya), Orpen, A.Guy

“…para-Ethynyl aniline has been prepared, structurally characterised and investigated as a building block towards fully π-conjugated multifunctional ligands and…”
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Synthesis and characterization of new cyclometallated Pd(II) complexes with bridging or terminal imidato ligands. Crystal structures of [{Pd(μ-succinimide)(phpy)} 2] and [Pd(azb)(succinimide)(PPh 3)] (phpy = 2-phenylpyridine; azb=azobenzene) by Serrano, José Luis, Garcı́a, Luis, Pérez, José, Pérez, Eduardo, Vives, Jorge, Sánchez, Gregorio, López, Gregorio, Molins, Elies, Orpen, A.Guy

“…Two series of new dinuclear cyclometallated palladium complexes [{Pd(μ-NCO)(C ∧N)} 2] containing asymmetric imidato –NCO– bridging units have been synthesized…”
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Synthesis and reactivity of μ-butadienyl diruthenium cations by Dennett, James N.L, Knox, Selby A.R, Charmant, Jonathan P.H, Gillon, Amy L, Orpen, A.Guy

“…Propargyl alcohols HCCCR 2OH (R=H, Me or Ph) react with [Ru 2(CO)(MeCN)(μ-CO)(μ-CH 2)(η-C 5H 5) 2] ( 2) to form the allylidene complexes [Ru 2(CO)(μ-CO){μ-η…”
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Diphosphine analogues of proton sponge: X-ray crystal structure of [Pd(η3-allyl)(dppn)]BF4·CH2Cl2 (dppn = 1,8-bis(diphenylphosphino)naphthalene) by James, Stuart L., Orpen, A.Guy, Pringle, Paul G.

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Synthesis and properties of new tris(cyanoethyl)phosphine complexes of platinum (0,II), palladium (0,II), iridium (I) and rhodium (I).: Conformational analysis of tris(cyanoethyl)phosphine ligands by Orpen, A.Guy, Pringle, Paul G., Smith, Martin B., Worboys, Kerry

“…The tris(cyanoethyl)phosphine (tcep) complexes trans-[PtCl 2(tcep) 2], cis-[PtMe 2(tcep) 2], and trans-[PtMeCl(tcep) 2] are prepared by treatment of the…”
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Synthesis of novel C2 symmetrical and enantiomerically pure thiepines by Hudson, Andrew, Orpen, A.Guy, Phetmung, Hirihattaya, Wyatt, Paul

“…Novel thiepines were synthesised using a Sharpless asymmetric dihydroxylation reaction to introduce the two chiral centres and with ring closure achieved by…”
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Diphosphine analogues of proton sponge: X-ray crystal structure of [Pd( η3-allyl)(dppn)]BF 4·CH 2Cl 2 (dppn = 1,8-bis(diphenylphosphino)naphthalene) by James, Stuart L., Orpen, A.Guy, Pringle, Paul G.

“…The X-ray crystal structure of [Pd( η 3-ally)dppn)]BF 4·CH 2Cl 2 ( 1) where dppn = 1,8-bis(diphenylphosphino)naphthalene is reported. Comparison of the…”
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Synthesis and X-ray structure of a [4]ferrocenophane containing a boron–boron bond by Lesley, M.J.Gerry, Mock, Ulricke, Norman, Nicholas C., Orpen, A.Guy, Rice, Craig R., Starbuck, Jonathan

“…The synthesis and X-ray crystal structure of the [4]ferrocenophane compound [1,2-B 2(NMe 2) 2{1,1′-(SC 5H 4) 2Fe}] which contains a B–B bond are described. The…”
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2,2′-Bipyridyl and 1,10-phenanthroline adducts of the diborane (4) compound B2 (1,2-S2C6H4)2 by Dai, Chaoyang, Johnson, Stuart M., Lawlor, Fiona J., Lightfoot, Philip, Marder, Todd B., Norman, Nicholas C., Orpen, A.Guy, Pickett, Nigel L., Quayle, Michael J., Rice, Craig R.

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Linking of benzyne and carbon monoxide at a triruthenium centre by migratory insertion by Charmant, Jonathan P.H, Dickson, Helen A.A, Grist, Nigel J, Knox, Selby A.R, Orpen, A.Guy, Saynor, Kathryn, Viñas, Josep M

“…The μ 3-benzyne complex [Ru 3(CO) 7( μ-PPh 2) 2( μ 3-C 6H 4)] ( 1a) reacts at room temperature (r.t.) with carbon monoxide (1 atm), trimethylphosphite, or…”
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2,2′-Bipyridyl and 1,10-phenanthroline adducts of the diborane (4) compound B 2 (1,2-S 2C 6H 4) 2 by Dai, Chaoyang, Johnson, Stuart M., Lawlor, Fiona J., Lightfoot, Philip, Marder, Todd B., Norman, Nicholas C., Orpen, A.Guy, Pickett, Nigel L., Quayle, Michael J., Rice, Craig R.

“…The syntheses and structures of the 2,2′-bipyridyl and 1,10-phenanthroline adducts of the diborane (4) compound B 2 (1,2-S 2C 6H 4) 2 are described. In both…”
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Reactivity of bis(diphenylphosphino) methane at a di-iron centre: thermally induced rearrangements of dimetallacyclopentenone complexes [Fe 2(CO) 5{ μ- σ: η3-C(O)CRCr}( μ- dppm)] by Hogarth, Graeme, Knox, Selby A.R., Lloyd, Brian R., Macpherson, Kirsty A., Morton, David A.V., Orpen, A.Guy

“…In toluene at 100°C the dimetallacyclopentenone complex [Fe 2(CO) 5{ μ- σ: η 3-C(O)CHCH}( μ-dppm)] ( 1a) isomerises to the μ-vinyl complex [Fe 2(CO) 6{μ-C(CH…”
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