Search Results - "Opila, J."
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1
Stability of the Y2O3–SiO2 system in high‐temperature, high‐velocity water vapor
Published in Journal of the American Ceramic Society (01-04-2020)“…High‐temperature, high‐velocity water vapor (steam‐jet) exposures were conducted on Y2O3, Y2SiO5, Y2Si2O7, and SiO2 for 60 hours at 1400°C. Volatility of Y2O3…”
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Journal Article -
2
Oxidation and Volatilization of Silica Formers in Water Vapor
Published in Journal of the American Ceramic Society (01-08-2003)“…At high temperatures, SiC and Si3N4 react with water vapor to form a SiO2 scale. SiO2 scales also react with water vapor to form a volatile Si(OH)4 species…”
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Journal Article Conference Proceeding -
3
High-temperature oxidation of yttrium silicides
Published in Journal of materials science (01-03-2018)“…Current silicon melt-infiltrated (SMI) ceramic matrix composites (CMCs) are limited by the melting temperature of silicon (1414 °C) and the volatility of the…”
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Journal Article -
4
Part I: Theoretical predictions of preferential oxidation in refractory high entropy materials
Published in Acta materialia (15-09-2020)“…High entropy materials, which include high entropy alloys, carbides, and borides, are a topic of substantial research interest due to the possibility of a…”
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Journal Article -
5
Water Vapor-Mediated Volatilization of High-Temperature Materials
Published in Annual review of materials research (01-07-2013)“…Volatilization in water vapor-containing atmospheres is an important and often unexpected mechanism of degradation of high-temperature materials during…”
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Journal Article -
6
Part II: Experimental verification of computationally predicted preferential oxidation of refractory high entropy ultra-high temperature ceramics
Published in Acta materialia (15-09-2020)“…Refractory high entropy materials have garnered significant research interest due to their potential ability to fill a need in high temperature structural…”
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Journal Article -
7
Observation of solid-state bidirectional thermal conductivity switching in antiferroelectric lead zirconate (PbZrO3)
Published in Nature communications (23-03-2022)“…Materials with tunable thermal properties enable on-demand control of temperature and heat flow, which is an integral component in the development of…”
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8
Phase stability and tensorial thermal expansion properties of single to high‐entropy rare‐earth disilicates
Published in Journal of the American Ceramic Society (01-05-2023)“…Temperature limitations in nickel‐base superalloys have resulted in the emergence of SiC‐based ceramic matrix composites as a viable replacement for gas…”
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Journal Article -
9
Variation of the Oxidation Rate of Silicon Carbide with Water-Vapor Pressure
Published in Journal of the American Ceramic Society (01-03-1999)“…Chemically vapor deposited silicon carbide (CVD SiC) was oxidized at temperatures of 1000°‐1400°C in H2O/O2 gas mixtures with compositions of 10‐90 vol% water…”
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Journal Article -
10
Alumina Volatility in Water Vapor at Elevated Temperatures
Published in Journal of the American Ceramic Society (01-09-2004)“…The volatility of alumina in high‐temperature water vapor was determined by a weight loss technique. Sapphire coupons were exposed at temperatures between…”
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Journal Article -
11
Computational and Experimental Study of Thermodynamics of the Reaction of Titania and Water at High Temperatures
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (14-12-2017)“…Gaseous titanium hydroxide and oxyhydroxide species were studied with quantum chemical methods. The results are used in conjunction with an experimental…”
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12
Evaluation of ultra-high temperature ceramics for aeropropulsion use
Published in Journal of the European Ceramic Society (2002)“…Among the ultra-high temperature ceramics (UHTC) are a group of materials consisting of zirconium diboride or hafnium diboride plus silicon carbide, and in…”
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Conference Proceeding Journal Article -
13
A method for assessing the volatility of oxides in high-temperature high-velocity water vapor
Published in Journal of the European Ceramic Society (01-04-2016)“…A steam-jet furnace was utilized to assess the volatility of SiO2, TiO2 and Y2O3 in a simulated turbine engine environment. Specimens were exposed in the…”
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Journal Article -
14
Oxidation of Carbon Fiber-Reinforced Silicon Carbide Matrix Composites at Reduced Oxygen Partial Pressures
Published in Journal of the American Ceramic Society (01-07-2011)“…Carbon fibers (Polyacrylonitrile‐derived T‐300) and T‐300 carbon fiber‐reinforced silicon carbide composites (C/SiC) were oxidized in flowing 0.1 MPa reduced…”
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Journal Article -
15
Predicting oxide stability in high-temperature water vapor
Published in JOM (1989) (01-01-2006)“…Many oxide phases, either as structural ceramics or thermally grown scales on alloys or non-oxide ceramics, find application in high-temperature corrosive…”
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Journal Article -
16
Paralinear Oxidation of CVD SiC in Water Vapor
Published in Journal of the American Ceramic Society (01-01-1997)“…The oxidation kinetics of CVDSiC were monitored by thermogravimetric analysis (TGA) in a 50% H2O/50% O2 gas mixture flowing at 1.4 cm/s for temperatures…”
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Journal Article -
17
SiC Recession Caused by SiO2 Scale Volatility under Combustion Conditions: II, Thermodynamics and Gaseous-Diffusion Model
Published in Journal of the American Ceramic Society (01-07-1999)“…In combustion environments, volatilization of SiO2 to Si‐O‐H(g) species is a critical issue. Available thermochemical data for Si‐O‐H(g) species were used in…”
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Journal Article -
18
Thermodynamic modeling of the Hf-Ta-O system for the design of oxidation resistant HfC-TaC ceramics
Published in Open ceramics (01-09-2024)“…An improved understanding of the oxidation resistance of HfC-TaC ultra-high temperature ceramics (UHTCs) is developed through modeling of the phase equilibria…”
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Journal Article -
19
Silicon carbide fiber oxidation behavior in the presence of boron nitride
Published in Journal of the American Ceramic Society (01-12-2018)“…The oxidation behavior of Sylramic SiC fibers without a boron nitride surface layer was compared to Sylramic iBN SiC fibers with a boron nitride surface layer…”
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Journal Article -
20
Composition dependence of oxidation resistance in high entropy ultra-high temperature ceramics
Published in Open ceramics (01-06-2024)“…High entropy ultra-high temperature ceramics (HE-UHTCs) have garnered intense research interest due to the potential for optimized oxidation and mechanical…”
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