Search Results - "Oliver, S"
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Photoactive Complexes with Earth-Abundant Metals
Published in Journal of the American Chemical Society (24-10-2018)“…In this invited Perspective, recent developments and possible future directions of research on photoactive coordination compounds made from nonprecious…”
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2
Is Iron the New Ruthenium?
Published in Chemistry : a European journal (26-04-2019)“…Ruthenium complexes with polypyridine ligands are very popular choices for applications in photophysics and photochemistry, for example, in lighting, sensing,…”
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3
Vapochromism in Organometallic and Coordination Complexes: Chemical Sensors for Volatile Organic Compounds
Published in Chemical reviews (08-05-2013)“…Wenger examines the vapochromism in organometallic and coordination complexes with regard to chemical sensors for volatile organic compounds…”
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4
Photoactive Nickel Complexes in Cross‐Coupling Catalysis
Published in Chemistry : a European journal (01-02-2021)“…Transition metal catalyzed cross‐coupling reactions are important in chemical synthesis for the formation of C−C and C‐heteroatom bonds. Suitable catalysts are…”
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5
Multi‐Photon Excitation in Photoredox Catalysis: Concepts, Applications, Methods
Published in Angewandte Chemie International Edition (22-06-2020)“…The energy of visible photons and the accessible redox potentials of common photocatalysts set thermodynamic limits to photochemical reactions that can be…”
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6
The Effect of Water upon Deep Eutectic Solvent Nanostructure: An Unusual Transition from Ionic Mixture to Aqueous Solution
Published in Angewandte Chemie International Edition (07-08-2017)“…The nanostructure of a series of choline chloride/urea/water deep eutectic solvent mixtures was characterized across a wide hydration range by neutron total…”
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7
A bright future for photosensitizers
Published in Nature chemistry (01-04-2020)“…Luminescent metal complexes play key roles in lighting, solar energy conversion, and photocatalysis. Now, a robust zirconium complex with spectacular…”
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8
Proton-Coupled Electron Transfer with Photoexcited Metal Complexes
Published in Accounts of chemical research (16-07-2013)“…Proton-coupled electron transfer (PCET) plays a crucial role in many enzymatic reactions and is relevant for a variety of processes including water oxidation,…”
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9
Luminescent First-Row Transition Metal Complexes
Published in JACS Au (22-11-2021)“…Precious and rare elements have traditionally dominated inorganic photophysics and photochemistry, but now we are witnessing a paradigm shift toward cheaper…”
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10
Unexpected Hydrated Electron Source for Preparative Visible-Light Driven Photoredox Catalysis
Published in Journal of the American Chemical Society (06-02-2019)“…The hydrated electron is experiencing a renaissance as a superreductant in lab-scale reductions driven by light, both for the degradation of recalcitrant…”
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11
Reductive Amination by Photoredox Catalysis and Polarity‐Matched Hydrogen Atom Transfer
Published in Angewandte Chemie International Edition (23-02-2018)“…The excitation of a RuII photosensitizer in the presence of ascorbic acid leads to the reduction of iminium ions to electron‐rich α‐aminoalkyl radical…”
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12
Photophysics of Perylene Diimide Dianions and Their Application in Photoredox Catalysis
Published in Angewandte Chemie International Edition (26-01-2022)“…The two‐electron reduced forms of perylene diimides (PDIs) are luminescent closed‐shell species whose photochemical properties seem underexplored. Our…”
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13
Photoredox Catalysis with Metal Complexes Made from Earth‐Abundant Elements
Published in Chemistry : a European journal (09-02-2018)“…Photoredox chemistry with metal complexes as sensitizers and catalysts frequently relies on precious elements such as ruthenium or iridium. Over the past 5…”
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14
How Donor−Bridge−Acceptor Energetics Influence Electron Tunneling Dynamics and Their Distance Dependences
Published in Accounts of chemical research (18-01-2011)“…Long-range electron transfer may occur via two fundamentally different mechanisms depending on the combination of electron donor, acceptor, and the bridging…”
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15
Reactivity control of a photocatalytic system by changing the light intensity
Published in Chemical science (Cambridge) (28-12-2019)“…We report a novel light-intensity dependent reactivity approach allowing us to selectively switch between triplet energy transfer and electron transfer…”
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16
The Nephelauxetic Effect Becomes an Important Design Factor for Photoactive First‐Row Transition Metal Complexes
Published in Angewandte Chemie International Edition (24-07-2023)“…The expansion of d‐orbitals as a result of metal‐ligand bond covalence, the so‐called nephelauxetic effect, is a well‐established concept of coordination…”
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Organic Mixed Valence
Published in Chemical reviews (10-08-2011)“…A study about organic mixed valence is discussed. The families of organic mixed systems, including diquinone radical anions, are discussed…”
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Sensitized triplet-triplet annihilation upconversion in water and its application to photochemical transformations
Published in Chemical science (Cambridge) (2018)“…Sensitized triplet-triplet annihilation (TTA) is a promising mechanism for solar energy conversion, but so far its application has been practically completely…”
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Sensitization-initiated electron transfer via upconversion: mechanism and photocatalytic applications
Published in Chemical science (Cambridge) (28-07-2021)“…Sensitization-initiated electron transfer (SenI-ET) describes a recently discovered photoredox strategy that relies on two consecutive light absorption events,…”
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20
Sensitizer-controlled photochemical reactivity via upconversion of red light
Published in Chemical science (Cambridge) (21-12-2022)“…By combining the energy input from two red photons, chemical reactions that would normally require blue or ultraviolet irradiation become accessible. Key…”
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