Search Results - "Oliver, Anna M."
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Synthesis of a rigid "ball-and-chain" donor-acceptor system through Diels-Alder functionalization of buckminsterfullerene (C60)
Published in Journal of the American Chemical Society (01-06-1993)“…Encouraged by our recent results in the functionalization of C[sub 60] through Diels-Alder reactions, we sought to develop a novel type of derivative of C[sub…”
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Remarkable Conformational Control of Photoinduced Charge Separation and Recombination in a Giant U-Shaped Tetrad
Published in Journal of the American Chemical Society (01-11-2000)“…Intramolecular photoinduced electron transfer (ET) with rates greater than 2 × 109 s-1 has been observed in polar solvents for the U-shaped, syn,syn isomer…”
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Through-space and through-bond effects on exciton interactions in rigidly linked dinaphthyl molecules
Published in Journal of the American Chemical Society (01-05-1993)Get full text
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Solvent Dynamical Effects on Electron Transfer in U-Shaped Donor-Bridge-Acceptor Molecules
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (12-02-2009)“…This study explores how the electron transfer in a class of donor-bridge-acceptor (DBA) supermolecules is affected by the dynamical response of the solvent…”
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Competing Electron-Transfer Pathways in Hydrocarbon Frameworks: Short-Circuiting Through-Bond Coupling by Nonbonded Contacts in Rigid U-Shaped Norbornylogous Systems Containing a Cavity-Bound Aromatic Pendant Group
Published in Journal of the American Chemical Society (21-03-2007)“…This work explores electron transfer through nonbonded contacts in two U-shaped DBA molecules 1DBA and 2DBA by measuring electron-transfer rates in organic…”
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Synthesis and Surface-Confined Electrochemistry of Dimethoxynaphthalene Fused through Rigid Norbornylogous Spacers to Thiolate, Dithiolate, and Disulfide Groups
Published in Langmuir (25-12-1996)“…A series of compounds (1−8) has been prepared in which a 1,4-dimethoxynaphthalene (DMN) group and either two thiol groups or a disulfide moiety are attached to…”
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Solvent Friction Effect on Intramolecular Electron Transfer
Published in Journal of the American Chemical Society (21-12-2005)“…U-shaped donor−bridge−acceptor molecules with different electronic couplings have been investigated as a function of temperature in solvents with slow…”
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Observation of Dynamic Solvent Effect for Electron Tunneling in U-Shaped Molecules
Published in Journal of the American Chemical Society (01-09-2004)“…The electron-transfer rate constant is measured in two U-shaped donor−bridge−acceptor molecules over a wide range of temperature in acetonitrile and…”
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Intramolecular electronic energy transfer between rigidly linked naphthalene and anthracene chromophores
Published in Journal of physical chemistry (1952) (01-11-1993)Get full text
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Use of U-shaped Donor-Bridge-Acceptor Molecules To Study Electron Tunneling through Nonbonded Contacts
Published in Journal of the American Chemical Society (28-08-2002)“…A systematic determination of electronic coupling matrix elements in U-shaped molecules is demonstrated. The unique architecture of these systems allows for…”
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Temperature effects on intramolecular electron transfer kinetics under "normal", "inverted", and "nearly optimal" conditions
Published in Journal of physical chemistry (1952) (01-05-1993)Get full text
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Factors affecting charge separation and recombination in photoexcited rigid donor-insulator-acceptor compounds
Published in Journal of physical chemistry (1952) (01-12-1988)Get full text
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Synthesis of a Variety of Bichromophoric “Ball-and-Chain” Systems Based on Buckminsterfullerene (C60) for the Study of Intramolecular Electron and Energy Transfer Processes
Published in Journal of organic chemistry (26-07-1996)“…Diels−Alder reaction of C60 with the 1,3-dienes 7e−h, 8a, 8b, and 8d−h affords the “ball-and-chain” systems 2e−h, 3a, 3b, and 3d−h bearing two chromophores…”
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Long-distance charge recombination within rigid molecular assemblies in nondipolar solvents
Published in Journal of physical chemistry (1952) (01-03-1991)Get full text
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Distance Dependence of Singlet and Triplet Charge Recombination Pathways in a Series of Rigid Bichromophoric Systems
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (03-07-1997)“…The recombination process of the charge-separated state in a series of rigid donor−bridge−acceptor compounds 1[n] follows two pathways, viz. recombination to…”
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A synthetic strategy for the construction of a novel series of buckminsterfullerene (C 60) Ball-and-Chain molecules containing the porphyrin chromophore
Published in Tetrahedron letters (01-07-1996)“…A general method is described for synthesizing rigid “Ball-and-Chain” bichromophoric systems of the type C 60-{rigid bridge}-porphyrin 2. A general method is…”
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A New Class of Giant Tetrads for Studying Aspects of Long-Range Intramolecular Electron Transfer Processes: Synthesis and Computational Studies
Published in Chemistry : a European journal (03-09-1999)“…The role of solvent‐mediated electron transfer can be studied in multichromophoric systems that possess “U‐shaped” cavities (see scheme). One approach to…”
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Observation of a remarkable dependence of the rate of singlet-singlet energy transfer on the configuration of the hydrocarbon bridge in bichromophoric systems
Published in Journal of the American Chemical Society (01-06-1990)“…Intramolecular singlet energy transfer can be detected in a series of rigid bichromophoric molecules (1(n)) where a dimethoxynaphthalene chromophore and a…”
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