Search Results - "Oliveira, João C. A"

Electroremovable Traceless Hydrazides for Cobalt-Catalyzed Electro-Oxidative C–H/N–H Activation with Internal Alkynes by Mei, Ruhuai, Sauermann, Nicolas, Oliveira, João C. A, Ackermann, Lutz

“…Electrochemical oxidative C–H/N–H activations have been accomplished with a versatile cobalt catalyst in terms of [4 + 2] annulations of internal alkynes. The…”
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Cobalt-Catalyzed Enantioselective C–H Arylation of Indoles by Jacob, Nicolas, Zaid, Yassir, Oliveira, João C. A, Ackermann, Lutz, Wencel-Delord, Joanna

“…Atropoisomeric (hetero)­biaryls are scaffolds with increasing importance in the pharmaceutical and agrochemical industries. Although it is the most obvious…”
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Flow Rhodaelectro-Catalyzed Alkyne Annulations by Versatile C–H Activation: Mechanistic Support for Rhodium(III/IV) by Kong, Wei-Jun, Finger, Lars H, Messinis, Antonis M, Kuniyil, Rositha, Oliveira, João C. A, Ackermann, Lutz

“…A flow-metallaelectro-catalyzed C–H activation was realized in terms of robust rhodaelectro-catalyzed alkyne annulations. To this end, a modular electro-flow…”
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Enantioselective Cobalt(III)‐Catalyzed C−H Activation Enabled by Chiral Carboxylic Acid Cooperation by Pesciaioli, Fabio, Dhawa, Uttam, Oliveira, João C. A., Yin, Rongxin, John, Michael, Ackermann, Lutz

“…The enantioselective cobalt(III)‐catalyzed C−H alkylation was achieved through the design of a novel chiral acid. The cobalt(III)‐catalyzed enantioselective…”
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Enantioselective Pallada‐Electrocatalyzed C−H Activation by Transient Directing Groups: Expedient Access to Helicenes by Dhawa, Uttam, Tian, Cong, Wdowik, Tomasz, Oliveira, João C. A., Hao, Jiping, Ackermann, Lutz

“…Asymmetric pallada‐electrocatalyzed C−H olefinations were achieved through the synergistic cooperation with transient directing groups. The electrochemical,…”
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Enantioselective Ruthenium-Catalyzed C–H Alkylations by a Chiral Carboxylic Acid with Attractive Dispersive Interactions by Dhawa, Uttam, Connon, Robert, Oliveira, João C. A, Steinbock, Ralf, Ackermann, Lutz

“…Asymmetric ruthenium-catalyzed C–H alkylations were enabled by a chiral C2-symmetric carboxylic acid. The mild cooperative ruthenium­(II) catalysis set the…”
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Synergistic Manganese(I) C−H Activation Catalysis in Continuous Flow: Chemoselective Hydroarylation by Wang, Hui, Pesciaioli, Fabio, Oliveira, João C. A., Warratz, Svenja, Ackermann, Lutz

“…Chemoselective hydroarylations were accomplished by a novel synergistic Brønsted acid/manganese(I)‐catalyzed C−H activation manifold. Thus, alkynes bearing…”
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Palladium-Catalyzed Electrooxidative Double C–H Arylation by Lin, Zhipeng, Oliveira, João C. A., Scheremetjew, Alexej, Ackermann, Lutz

“…The electrochemical transition metal-catalyzed cross-dehydrogenative reaction has emerged as a promising platform to achieve a sustainable and atom-economic…”
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Enantioselective palladaelectro-catalyzed C-H olefinations and allylations for N-C axial chirality by Dhawa, Uttam, Wdowik, Tomasz, Hou, Xiaoyan, Yuan, Binbin, Oliveira, João C. A, Ackermann, Lutz

“…Enantioselective palladaelectro-catalyzed C-H alkenylations and allylations were achieved with easily-accessible amino acids as transient directing groups…”
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Reactivity-Controlling Factors in Carboxylate-Assisted C–H Activation under 4d and 3d Transition Metal Catalysis by Rogge, Torben, Oliveira, João C. A, Kuniyil, Rositha, Hu, Lianrui, Ackermann, Lutz

“…Detailed density functional theory calculations provide valuable insight into reactivity-controlling factors in transition metal-catalyzed C–H activation by…”
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Rhodaelectro-catalyzed access to chromones via formyl C–H activation towards peptide electro-labeling by Stangier, Maximilian, Messinis, Antonis M., Oliveira, João C. A., Yu, Hao, Ackermann, Lutz

“…Chromones represent a privileged scaffold in medicinal chemistry and are an omnipresent structural motif in natural products. Chemically encoded non-natural…”
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Electro-oxidative Intermolecular Allylic C(sp3)–H Aminations by Wang, Yulei, Lin, Zhipeng, Oliveira, João C. A, Ackermann, Lutz

“…The oxidative intermolecular nitrogenation of C­(sp3)–H bonds represents one of the most straightforward strategies to construct nitrogen-containing molecules…”
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Iridium‐Catalyzed Electrooxidative C−H Activation by Chemoselective Redox‐Catalyst Cooperation by Qiu, Youai, Stangier, Maximilian, Meyer, Tjark H., Oliveira, João C. A., Ackermann, Lutz

“…Iridium‐catalyzed electrochemical C−H activation was accomplished within a cooperative catalysis manifold, setting the stage for electrooxidative C−H…”
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1,4‐Iron Migration for Expedient Allene Annulations through Iron‐Catalyzed C−H/N−H/C−O/C−H Functionalizations by Mo, Jiayu, Müller, Thomas, Oliveira, João C. A., Ackermann, Lutz

“…C−H activation bears great potential for enabling sustainable molecular syntheses in a step‐ and atom‐economical manner, with major advances having been…”
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Asymmetric Iron‐Catalyzed C−H Alkylation Enabled by Remote Ligand meta‐Substitution by Loup, Joachim, Zell, Daniel, Oliveira, João C. A., Keil, Helena, Stalke, Dietmar, Ackermann, Lutz

“…Highly enantioselective iron‐catalyzed C−H alkylations by inner‐sphere C−H activation were accomplished with ample scope. High levels of enantiocontrol proved…”
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Rhodaelectrocatalysis for Annulative C−H Activation: Polycyclic Aromatic Hydrocarbons through Versatile Double Electrocatalysis by Kong, Wei‐Jun, Finger, Lars H., Oliveira, João C. A., Ackermann, Lutz

“…Rapid access to structurally diversified polycyclic aromatic hydrocarbons (PAHs) in a controlled manner is of key significance in materials sciences. Herein,…”
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Catalyst‐ and Reagent‐Free Electrochemical Azole C−H Amination by Qiu, Youai, Struwe, Julia, Meyer, Tjark H., Oliveira, João C. A., Ackermann, Lutz

“…Catalyst‐ and chemical oxidant‐free electrochemical azole C−H aminations were accomplished via cross‐dehydrogenative C−H/N−H functionalization. The…”
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Enantioselective Cobaltaphotoredox-Catalyzed C–H Activation by Xu, Yang, Lin, Ye, Homölle, Simon L., Oliveira, João C. A., Ackermann, Lutz

“…The quest for sustainable strategies in molecular synthesis has spurred the emergence of photocatalysis as a particularly powerful technique. In recent years,…”
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Electrochemical Enantioselective C–H Annulation by Achiral Rhodium(III)/Chiral Brønsted Base Domino Catalysis by Li, Yanjun, Xu, Jiawei, Oliveira, João C. A., Scheremetjew, Alexej, Ackermann, Lutz

“…Rhodium­(III)-catalyzed enantioselective C–H activation has emerged as a powerful tool for assembling enabling chiral molecules. However, this approach is…”
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Peptide late-stage C(sp)-H arylation by native asparagine assistance without exogenous directing groups by Weng, Yiyi, Ding, Xingxing, Oliveira, João C. A, Xu, Xiaobin, Kaplaneris, Nikolaos, Zhu, Meijie, Chen, Hantao, Chen, Zhuo, Ackermann, Lutz

“…There is a strong demand for novel native peptide motifs for post-synthetic modifications of peptides without pre-installation and subsequent removal of…”
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