Search Results - "Okajima, Masayuki"
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Microflow electroorganic synthesis without supporting electrolyte
Published in Chemical communications (Cambridge, England) (01-01-2005)“…Anodic methoxylation of several organic compounds has been successfully achieved in the absence of intentionally added supporting electrolyte using an…”
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Iterative Molecular Assembly Based on the Cation-Pool Method. Convergent Synthesis of Dendritic Molecules
Published in Journal of the American Chemical Society (20-08-2008)“…An iterative method for molecular assembly has been developed based on the cation-pool method using (trimethylsilyl)diphenylmethane as a building block. The…”
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Generation of Diarylcarbenium Ion Pools via Electrochemical C–H Bond Dissociation
Published in Bulletin of the Chemical Society of Japan (15-05-2009)“…The “cation pools” of diarylcarbenium ions have been generated by the low-temperature electrochemical oxidation of diphenylmethane derivatives. In addition to…”
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“Cation Pool” Method Based on C−C Bond Dissociation. Effective Generation of Monocations and Dications
Published in Journal of the American Chemical Society (18-05-2005)“…The “cation pools” of alkoxyarylcarbenium ions were effectively generated by the oxidative C−C bond dissociation using low temperature electrolysis. The…”
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Oxidative Generation of Diarylcarbenium Ion Pools
Published in Organic letters (26-10-2006)“…“Cation pools” of diarylcarbenium ions have been generated by the oxidative C−H bond dissociation of diarylmethanes using anodic oxidation. “Diarylcarbenium…”
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Reaction of an electrogenerated ‘iminium cation pool’ with organometallic reagents. Direct oxidative α-alkylation and -arylation of amine derivatives
Published in Tetrahedron letters (11-03-2001)“…We have developed an efficient direct oxidative α-alkylation and -arylation of carbamates based on the ‘cation pool’ method. Grignard reagents, organozinc…”
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Electrochemical Combinatorial Organic Syntheses Using Microflow Systems
Published in QSAR & combinatorial science (01-08-2005)“…The “cation flow” method, in which highly reactive carbocations are generated in the absence of nucleophiles by low temperature electrolysis and are allowed to…”
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