Search Results - "OZDEMIR, Ismail"
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Palladium(II)‐N‐Heterocyclic Carbene Complexes: Efficient Catalysts for the Direct C‐H Bond Arylation of Furans with Aryl Halides
Published in Applied organometallic chemistry (01-07-2018)“…This paper contains the synthesis and characterization of the seven new benzimidazolium salts and their corresponding new palladium(II)‐NHC complexes with the…”
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Biological determination, molecular docking and Hirshfeld surface analysis of rhoduim(I)-N-heterocyclic carbene complex: Synthesis, crystal structure, DFT calculations, optical and non linear optical properties
Published in Inorganica Chimica Acta (01-06-2023)“…[Display omitted] •New rhodium(I) N-heterocyclic carbene complex was synthesized in good.•The coordination mode of the complex was confirmed by single crystal…”
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Synthesis, characterization and catalytic activity of PEPPSI-type palladium–NHC complexes
Published in Inorganica Chimica Acta (24-01-2021)“…Eight benzimidazolium salts (2a–h), having two nitrogen atoms substituted by various alkyl groups, have been synthesized in high yields. The benzimidazolium…”
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An efficient palladium catalyzed mizoroki-heck cross-coupling in water: synthesis, characterization and catalytic activities
Published in Polyhedron (15-05-2024)“…A series of new palladium complexes known as PEPPSI-type complexes 3 were successfully synthesized by reacting benzimidazolium salts 2a-e, potassium carbonate…”
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Direct Arylation of Arene C−H Bonds by Cooperative Action of NHCarbene−Ruthenium(II) Catalyst and Carbonate via Proton Abstraction Mechanism
Published in Journal of the American Chemical Society (30-01-2008)“…Direct functionalization of sp2 C−H bonds via ortho diarylation of 2-pyridyl benzene with arylbromides was achieved using ruthenium(II) catalysts containing a…”
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Evaluation of Ruthenium(II) N -Heterocyclic Carbene Complexes as Enzymatic Inhibitory Agents with Antioxidant, Antimicrobial, Antiparasitical and Antiproliferative Activity
Published in Molecules (Basel, Switzerland) (31-01-2023)“…A series of [RuCl (p-cymene)(NHC)] complexes were obtained by reacting [RuCl (p-cymene)]2 with in situ generated Ag-N-heterocyclic carbene (NHC) complexes. The…”
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N‑Alkylation and N,C-Dialkylation of Amines with Alcohols in the Presence of Ruthenium Catalysts with Chelating N‑Heterocyclic Carbene Ligands
Published in Organometallics (08-06-2015)“…A series of new benzimidazolium salts and ruthenium(II) complexes containing chelating N-heterocyclic carbenes (NHCs) functionalized with a benzylic group and…”
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Wear Performance Evaluation of Polymer Overlays on Engine Bearings
Published in Materials (01-08-2024)“…Modern engine bearing materials encounter the challenge of functioning under conditions of mixed lubrication, low viscosity oils, downsizing, start-stop…”
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Synthesis, antimicrobial activity and molecular docking study of benzyl functionalized benzimidazole silver(I) complexes
Published in Journal of biological inorganic chemistry (01-12-2023)“…In this study, a series of N- functionalized benzimidazole silver(I) complexes were prepared and characterized by FT-IR, 1 H, 13 C{ 1 H} NMR spectroscopy, and…”
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An efficient (NHC) Copper (I)-catalyst for azide–alkyne cycloaddition reactions for the synthesis of 1,2,3-trisubstituted triazoles: Click chemistry
Published in Inorganica Chimica Acta (01-10-2017)“…[Display omitted] •A serie of new benzimidazolium salts (2a–c) were synthesized and used for the synthesis of cupper-N-heterocyclic carbene (Cu-NHC) complexes…”
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Microstructural refinement and wear property of Al–Si–Cu composite subjected to extrusion and high-pressure torsion
Published in Materials science & engineering. A, Structural materials : properties, microstructure and processing (01-11-2014)“…The effect of high-pressure torsion (HPT) on the microstructure and the mechanical properties, especially the wear properties, of an Al–Si–Cu alloy…”
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The first use of [PdBr2(imidazolidin-2-ylidene)(pyridine)] catalysts in the direct C-H bond arylation of C2-substituted furan and thiophene
Published in Research on chemical intermediates (01-07-2021)“…N -Heterocyclic carbene (NHC)-linked PEPPSI-type palladium complexes have recently been used in the direct C-H bond arylation of heteroarenes. However, in most…”
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Synthesis, crystal structures, DFT calculations, and catalytic application in hydrosilylation of acetophenone derivatives with triethylsilane of novel rhoduim-N-heterocyclic carbene (NHCs) complex
Published in Journal of molecular structure (05-10-2022)“…•In this study, a new rhodium based was synthetized and fully characterized by single crystal X-ray.•This complex was used as a catalyst precursor in the…”
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Pd–PEPPSI-type expanded ring N-heterocyclic carbene complexes: synthesis, characterization, and catalytic activity in Suzuki–Miyaura cross coupling
Published in Green chemistry letters and reviews (31-12-2024)“…In this work, we synthesized a series of six unsymmetrical benzimidazolium salts 2 and their pyridine-enhanced precatalyst preparation stabilization and…”
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Synthesis, Characterization, Antimicrobial Properties, and Antioxidant Activities of Silver-N-Heterocyclic Carbene Complexes
Published in Bioinorganic chemistry and applications (26-05-2023)“…The emergence of antimicrobial resistance has become a major handicap in the fight against bacterial infections, prompting researchers to develop new, more…”
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Benzimidazolium sulfonate ligand precursors and application in ruthenium-catalyzed aromatic amine alkylation with alcohols
Published in Catalysis communications (10-01-2016)“…New benzimidazolium sulfonate salts have been prepared and fully characterized. They have been associated in situ with [RuCl2(p-cymene)]2 to generate efficient…”
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Theoretical analysis of frontier orbitals, electronic transitions, and global reactivity descriptors of M(CO)4L2 type metal carbonyl complexes: a DFT/TDDFT study
Published in Structural chemistry (01-06-2019)“…Metal carbonyl complexes, which have been known as effective catalysts since early days, find use in many fields both directly and indirectly. Although the use…”
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Well‐defined PEPPSI‐themed palladium–NHC complexes: synthesis, and catalytic application in the direct arylation of heteroarenes
Published in Applied organometallic chemistry (01-02-2020)“…In this study, a series of benzimidazolium salts were synthesized as unsymmetrical N‐heterocyclic carbene (NHC) precursors. Benzimidazolium salts were used for…”
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Palladium Complexes with Tetrahydropyrimidin-2-ylidene Ligands: Catalytic Activity for the Direct Arylation of Furan, Thiophene, and Thiazole Derivatives
Published in Organometallics (08-06-2015)“…The synthesis and characterization of novel 1,3-benzyl-3,4,5,6-tetrahydropyrimidin-2-ylidene-based N-heterocyclic carbene palladium(II) complexes (1a–d) were…”
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Pentacoordinated Rhodium(I) Complexes Supported by Coumarin-Functionalized N‑Heterocyclic Carbene Ligands
Published in Organometallics (22-01-2018)“…New coumarin-tethered benzimidazolium (BzICouRHCl) and imidazolium (ICouRHCl) salts have been prepared as precursors for coumarin–NHC rhodium(I) complexes…”
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