Search Results - "O, Wylie W. N"

Enantioselective C–H Bond Addition of Pyridines to Alkenes Catalyzed by Chiral Half-Sandwich Rare-Earth Complexes by Song, Guoyong, O, Wylie W. N, Hou, Zhaomin

“…Cationic half-sandwich scandium alkyl complexes bearing monocyclopentadienyl ligands embedded in chiral binaphthyl backbones act as excellent catalysts for the…”
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PNP-Ligated Heterometallic Rare-Earth/Ruthenium Hydride Complexes Bearing Phosphinophenyl and Phosphinomethyl Bridging Ligands by O, Wylie W. N, Kang, Xiaohui, Luo, Yi, Hou, Zhaomin

“…The reaction of rare-earth bis­(alkyl) complexes containing a bis­(phosphinophenyl)­amido pincer (PNP), LnPNP iPr(CH2SiMe3)2 (1-Ln, Ln = Y, Ho, Dy), with…”
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Copper-Catalyzed Formal CH Carboxylation of Aromatic Compounds with Carbon Dioxide through Arylaluminum Intermediates by Ueno, Atsushi, Takimoto, Masanori, O, Wylie W. N., Nishiura, Masayoshi, Ikariya, Takao, Hou, Zhaomin

“…The CH bond carboxylation of various aromatic compounds with CO2 was achieved by the deprotonative alumination with a mixed alkyl amido lithium aluminate…”
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Transmetalation of a Primary Amino-Functionalized N-Heterocyclic Carbene Ligand from an Axially Chiral Square-Planar Nickel(II) Complex to a Ruthenium(II) Precatalyst for the Transfer Hydrogenation of Ketones by O, Wylie W. N, Lough, Alan J, Morris, Robert H

“…The first homoleptic nickel(II) complex with primary amino-functionalized N-heterocyclic carbene (C−NH2) ligands ([Ni(m-CH2NH2)2](PF6)2, 2) was prepared under…”
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Primary Amine Functionalized N‑Heterocyclic Carbene Complexes of Iridium: Synthesis, Structure, and Catalysis by O, Wylie W. N, Lough, Alan J, Morris, Robert H

“…The square-planar iridium(I) complex [Ir(cod)(C–NH2)]PF6 (3·PF 6 ) containing a primary amine based N-heterocyclic carbene ligand (C–NH2) ligand was…”
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Ester Hydrogenation Catalyzed by a Ruthenium(II) Complex Bearing an N‑Heterocyclic Carbene Tethered with an “NH2” Group and a DFT Study of the Proposed Bifunctional Mechanism by O, Wylie W. N, Morris, Robert H

“…A ruthenium(II) catalyst containing an NHC–amine (NHC = N-heterocyclic carbene) ligand (C–NH2) catalyzes the H2-hydrogenation of various esters and lactones at…”
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Factors Favoring Efficient Bifunctional Catalysis. Study of a Ruthenium(II) Hydrogenation Catalyst Containing an N-Heterocyclic Carbene with a Primary Amine Donor by O, Wylie W. N, Lough, Alan J, Morris, Robert H

“…An alcohol-assisted outer-sphere bifunctional mechanism is proposed for the H2 hydrogenation of ketones catalyzed by the ruthenium­(II) precatalyst…”
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Bifunctional Mechanism with Unconventional Intermediates for the Hydrogenation of Ketones Catalyzed by an Iridium(III) Complex Containing an N-Heterocyclic Carbene with a Primary Amine Donor by O, Wylie W. N, Lough, Alan J, Morris, Robert H

“…An alcohol-assisted outer-sphere bifunctional mechanism for the H2 hydrogenation of ketones catalyzed by an iridium system is presented on the basis of…”
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Palladium(II) and Platinum(II) Complexes Featuring a Nitrile-Functionalized N-Heterocyclic Carbene Ligand by O, Wylie W. N, Lough, Alan J, Morris, Robert H

“…The transmetalation reaction of 2 equiv of trans-PdCl2(CH3CN)2 or Pd(cod)Cl2 with a nitrile-functionalized N-heterocyclic carbene complex of silver(I),…”
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Synthesis and Characterization of Nitrile-Functionalized N-Heterocyclic Carbenes and Their Complexes of Silver(I) and Rhodium(I) by O, Wylie W. N, Lough, Alan J, Morris, Robert H

“…A series of unsymmetrical nitrile-functionalized N-heterocyclic carbene precursors were synthesized by N-alkylation and N-arylation of 2-cyanophenylimidazole…”
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Mechanistic Investigation of the Hydrogenation of Ketones Catalyzed by a Ruthenium(II) Complex Featuring an N-Heterocyclic Carbene with a Tethered Primary Amine Donor: Evidence for an Inner Sphere Mechanism by O, Wylie W. N., Lough, Alan J., Morris, Robert H.

“…The complex [Ru(p-cymene)(m-CH2NH2)Cl]PF6 (1) catalyzes the H2-hydrogenation of ketones in basic THF under 25 bar of H2 at 50 °C with a turnover frequency…”
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Ester Hydrogenation Catalyzed by a Ruthenium(II) Complex Bearing an N-Heterocyclic Carbene Tethered with an “NH 2 ” Group and a DFT Study of the Proposed Bifunctional Mechanism by O, Wylie W. N., Morris, Robert H.

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Copper-Catalyzed Formal CH Carboxylation of Aromatic Compounds with Carbon Dioxide through Arylaluminum Intermediates by Ueno, Atsushi, Takimoto, Masanori, O, Wylie W N, Nishiura, Masayoshi, Ikariya, Takao, Hou, Zhaomin

“…The CH bond carboxylation of various aromatic compounds with CO2 was achieved by the deprotonative alumination with a mixed alkyl amido lithium aluminate…”
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(η 5 -Pentamethylcyclopentadienyl)(η 6 -toluene)ruthenium(II) hexafluoridophosphate by O, Wylie W. N., Lough, Alan J., Morris, Robert H.

“…In the title complex, [Ru(C7H8)(C10H15)]PF6, the cation lies on a mirror plane and the anion lies on an inversion center. The distance between the Ru atom and…”
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(η-Penta-methyl-cyclo-penta-dien-yl)(η-toluene)-ruthenium(II) hexa-fluorido-phosphate by O, Wylie W N, Lough, Alan J, Morris, Robert H

“…In the title complex, [Ru(C(7)H(8))(C(10)H(15))]PF(6), the cation lies on a mirror plane and the anion lies on an inversion center. The distance between the Ru…”
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