Search Results - "O'Brien, Cate T."
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RAFT Dispersion Polymerization of Benzyl Methacrylate in Silicone Oil Using a Silicone-Based Methacrylic Stabilizer Provides Convenient Access to Spheres, Worms, and Vesicles
Published in Macromolecules (10-03-2020)“…Reversible addition–fragmentation chain transfer (RAFT) solution polymerization of 3-[tris(trimethylsiloxy)silyl] propyl methacrylate (SiMA) was conducted in…”
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Effect of Core Cross-linking on the Physical Properties of Poly(dimethylsiloxane)-Based Diblock Copolymer Worms Prepared in Silicone Oil
Published in Macromolecules (24-09-2019)“…A trithiocarbonate-capped poly(dimethylsiloxane) (PDMS) precursor is chain-extended via reversible addition–fragmentation chain transfer dispersion…”
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Small‐Angle X‐Ray Scattering Studies of Block Copolymer Nano‐Objects: Formation of Ordered Phases in Concentrated Solution During Polymerization‐Induced Self‐Assembly
Published in Angewandte Chemie International Edition (01-06-2021)“…We report that polymerization‐induced self‐assembly (PISA) can be used to prepare lyotropic phases comprising diblock copolymer nano‐objects in non‐polar…”
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Unique aqueous self-assembly behavior of a thermoresponsive diblock copolymer
Published in Chemical science (Cambridge) (14-01-2020)“…It is well-recognized that block copolymer self-assembly in solution typically produces spheres, worms or vesicles, with the relative volume fraction of each…”
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RAFT Dispersion Polymerization in Silicone Oil
Published in Macromolecules (09-04-2019)“…A near-monodisperse monohydroxy-terminated polydimethylsiloxane (PDMS; mean degree of polymerization = 66) was esterified using a carboxylic…”
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Control of the aqueous solubility of cellulose by hydroxyl group substitution and its effect on processing
Published in Polymer (Guilford) (03-05-2021)“…Native cellulose is insoluble in water, despite the high number of hydrogen bonding sites per chain, as molecules preferably hydrogen bond to each other,…”
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Small‐Angle X‐Ray Scattering Studies of Block Copolymer Nano‐Objects: Formation of Ordered Phases in Concentrated Solution During Polymerization‐Induced Self‐Assembly
Published in Angewandte Chemie (01-06-2021)“…We report that polymerization‐induced self‐assembly (PISA) can be used to prepare lyotropic phases comprising diblock copolymer nano‐objects in non‐polar…”
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Unique aqueous self-assembly behavior of a thermoresponsive diblock copolymer† †Electronic supplementary information (ESI) available: Materials and methods, polymer characterization techniques, SAXS models, supporting figures: GPC chromatograms, assigned 1H NMR spectra, calibration plot for determining the mean DP of the PDMAC precursor, temperature-dependent rheological studies, SIPLI rheology data, full spectra for the variable temperature 1H NMR spectroscopy study, apparent z-average diameter
Published in Chemical science (Cambridge) (12-11-2019)“…A new amphiphilic diblock copolymer prepared via polymerization-induced self-assembly forms spheres, worms, vesicles or lamellae in aqueous solution on…”
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