Search Results - "Nutz, Marco"
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Multiple complexation of CO and related ligands to a main-group element
Published in Nature (London) (18-06-2015)“…Transition metal–ligand fragments are often able to bind and release several carbon monoxide molecules, such as the catalysts used in industrial-scale acetic…”
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2
The Donor-Stabilized Silylene Bis[N,N′-diisopropylbenzamidinato(−)]silicon(II): Synthesis, Electronic Structure, and Reactivity
Published in Chemistry : a European journal (21-07-2014)“…A convenient and robust synthesis of bis[N,N′‐diisopropylbenzamidinato(−)]silicon(II) (1), a donor‐stabilized silylene, has been developed (35 g scale). To get…”
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3
Synthesis and Trapping of Iminoboranes by M=B/C=N Bond Metathesis
Published in Angewandte Chemie International Edition (26-06-2017)“…Although the metathesis of metal–boron double bonds with elemental chalcogenides is an established process, no similar reactivity has been observed with…”
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4
Reactivity of the Donor-Stabilized Silylenes [iPrNC(Ph)NiPr]2Si and [iPrNC(NiPr2)NiPr]2Si: Activation of CO2 and CS2
Published in Chemistry : a European journal (09-11-2015)“…Activation of CO2 by the bis(amidinato)silylene 1 and the analogous bis(guanidinato)silylene 2 leads to the structurally analogous six‐coordinate silicon(IV)…”
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5
Release of Isonitrile‐ and NHC‐Stabilized Borylenes from Group VI Terminal Borylene Complexes
Published in Chemistry : a European journal (07-05-2018)“…A family of doubly isonitrile‐stabilized terphenyl borylenes could be obtained by addition of three equivalents of isonitrile to the corresponding Cr and W…”
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6
Reactivity of the Donor-Stabilized Silylenes [iPrNC(Ph)NiPr] sub(2)Si and [iPrNC(NiPr sub(2))NiPr] sub(2)Si: Activation of CO sub(2) and CS sub(2)
Published in Chemistry : a European journal (01-11-2015)“…Activation of CO sub(2) by the bis(amidinato)silylene 1 and the analogous bis(guanidinato)silylene 2 leads to the structurally analogous six-coordinate…”
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7
Four-, Five-, and Six-Coordinate Silicon(IV) Complexes: Reactivity of the Donor-Stabilized Silylenes [iPrNC(Ph)NiPr]2Si and [iPrNC(NiPr2)NiPr]2Si Towards Me3SiN3 and PhSCH2N3
Published in European journal of inorganic chemistry (01-07-2016)“…Bis(amidinato)silylene 1 and the analogous bis(guanidinato)silylene 2 reacted with Me3SiN3 to form compounds 3 [a five‐coordinate silicon(IV) complex with an…”
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8
Four‐, Five‐, and Six‐Coordinate Silicon(IV) Complexes: Reactivity of the Donor‐Stabilized Silylenes [ i PrNC(Ph)N i Pr] 2 Si and [ i PrNC(N i Pr 2 )N i Pr] 2 Si Towards Me 3 SiN 3 and PhSCH 2 N 3
Published in European journal of inorganic chemistry (01-07-2016)“…Bis(amidinato)silylene 1 and the analogous bis(guanidinato)silylene 2 reacted with Me 3 SiN 3 to form compounds 3 [a five‐coordinate silicon(IV) complex with…”
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9
Four-, Five-, and Six-Coordinate Silicon(IV) Complexes: Reactivity of the Donor-Stabilized Silylenes [iPrNC(Ph)NiPr] sub(2)Si and [iPrNC(NiPr sub(2))NiPr] sub(2)Si Towards Me sub(3)SiN sub(3) and PhSCH sub(2)N sub(3)
Published in European journal of inorganic chemistry (01-07-2016)“…Bis(amidinato)silylene 1 and the analogous bis(guanidinato)silylene 2 reacted with Me sub(3)SiN sub(3) to form compounds 3 [a five-coordinate silicon(IV)…”
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10
Reactivity of the Donor‐Stabilized Silylenes [ i PrNC(Ph)N i Pr] 2 Si and [ i PrNC(N i Pr 2 )N i Pr] 2 Si: Activation of CO 2 and CS 2
Published in Chemistry : a European journal (09-11-2015)“…Abstract Activation of CO 2 by the bis(amidinato)silylene 1 and the analogous bis(guanidinato)silylene 2 leads to the structurally analogous six‐coordinate…”
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11
Synthese und Nachweis von Iminoboranen durch M=B/C=N‐Bindungsmetathese
Published in Angewandte Chemie (26-06-2017)“…Während die Metathese von Metall‐Bor‐Doppelbindungen mit elementaren Chalkogeniden gut beschrieben ist, kann keine vergleichbare Reaktivität für…”
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12
Reactivity of the Donor-Stabilized Silylenes [iPrNC(Ph)NiPr]2 Si and [iPrNC(NiPr2 )NiPr]2 Si: Activation of CO2 and CS2
Published in Chemistry : a European journal (09-11-2015)“…Activation of CO2 by the bis(amidinato)silylene 1 and the analogous bis(guanidinato)silylene 2 leads to the structurally analogous six-coordinate silicon(IV)…”
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13
Synthese und Nachweis von Iminoboranen durch M=B/C=N‐Bindungsmetathese
Published in Angewandte Chemie (26-06-2017)“…Abstract Während die Metathese von Metall‐Bor‐Doppelbindungen mit elementaren Chalkogeniden gut beschrieben ist, kann keine vergleichbare Reaktivität für…”
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