Search Results - "Noyori, Ryoji"
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Facts are the Enemy of Truth-Reflections on Serendipitous Discovery and Unforeseen Developments in Asymmetric Catalysis
Published in Angewandte Chemie International Edition (02-01-2013)“…As Louis Pasteur said, “Chance favors only a prepared mind.” Serendipitous events reorienting the pathway of science often occur through the actions of…”
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Asymmetric Catalysis: Science and Opportunities (Nobel Lecture 2001)
Published in Advanced synthesis & catalysis (01-01-2003)“…Asymmetric catalysis, in its infancy in the 1960s, has dramatically changed the procedures of chemical synthesis, and resulted in an impressive progression to…”
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Hydration of Terminal Alkynes Catalyzed by Water-Soluble Cobalt Porphyrin Complexes
Published in Journal of the American Chemical Society (09-01-2013)“…Water-soluble cobalt(III) porphyrin complexes were found to promote the hydration of terminal alkynes to give methyl ketones. The alkyne hydration proceeded in…”
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Asymmetric Catalysis by Architectural and Functional Molecular Engineering: Practical Chemo- and Stereoselective Hydrogenation of Ketones
Published in Angewandte Chemie International Edition (05-01-2001)“…Hydrogenation is a core technology in chemical synthesis. High rates and selectivities are attainable only by the coordination of structurally well‐designed…”
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Metal−Ligand Bifunctional Catalysis: A Nonclassical Mechanism for Asymmetric Hydrogen Transfer between Alcohols and Carbonyl Compounds
Published in Journal of organic chemistry (30-11-2001)Get full text
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Toward Efficient Asymmetric Hydrogenation: Architectural and Functional Engineering of Chiral Molecular Catalysts
Published in Proceedings of the National Academy of Sciences - PNAS (13-04-2004)“…Asymmetric hydrogenation uses inexpensive, clean hydrogen gas and a very small amount of a chiral molecular catalyst, providing the most powerful way to…”
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Mechanism of Asymmetric Hydrogenation of Ketones Catalyzed by BINAP/1,2-Diamine−Ruthenium(II) Complexes
Published in Journal of the American Chemical Society (05-11-2003)“…Asymmetric hydrogenation of acetophenone with trans-RuH(η1-BH4)[(S)-tolbinap][(S,S)-dpen] (TolBINAP = 2,2‘-bis(di-4-tolylphosphino)-1,1‘-binaphthyl; DPEN =…”
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Rh-Catalyzed Arylation and Alkenylation of C60 Using Organoboron Compounds
Published in Journal of the American Chemical Society (04-07-2007)“…A new organoboron-based arylation and alkenylation of C60 catalyzed by a rhodium complex was developed. A treatment of C60 with an organoboron compound in the…”
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The Metal−Ligand Bifunctional Catalysis: A Theoretical Study on the Ruthenium(II)-Catalyzed Hydrogen Transfer between Alcohols and Carbonyl Compounds
Published in Journal of the American Chemical Society (23-02-2000)“…The ternary system consisting of [RuCl2(η6-benzene)]2, N-tosylethylenediamine or ethanolamine, and KOH (Ru:amine:KOH = 1:1:2 molar ratio) catalyzes reversible…”
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Ethical Conduct in Chemical Research and Publishing
Published in Advanced synthesis & catalysis (14-01-2013)“…In recent years the incidence of scientific misconduct has increased. While the direct responsibility lies with the individual researcher, the educational role…”
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trans-RuH(η-BH4)(binap)(1,2-diamine): A Catalyst for Asymmetric Hydrogenation of Simple Ketones under Base-Free Conditions
Published in Journal of the American Chemical Society (12-06-2002)“…Reaction of a chiral RuCl2(diphosphine)(1,2-diamine) complex and NaBH4 forms trans-RuH(η1-BH4)(diphosphine)(1,2-diamine) quantitatively. The TolBINAP/DPEN Ru…”
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The Hydrogenation/Transfer Hydrogenation Network in Asymmetric Reduction of Ketones Catalyzed by [RuCl2(binap)(pica)] Complexes
Published in Chemistry, an Asian journal (06-10-2008)“…Chiral binap/pica‐RuII complexes (binap=(S)‐ or (R)‐2,2′‐bis(diphenylphosphino)‐1,1′‐binaphthyl; pica=α‐picolylamine) catalyze both asymmetric hydrogenation…”
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An Efficient Diphosphine/Hybrid-Amine Combination for Ruthenium(II)-Catalyzed Asymmetric Hydrogenation of Aryl Ketones
Published in Advanced synthesis & catalysis (11-02-2011)“…Readily available and modular hybrid amine/benzimidazole‐based 1H‐benzimidazole‐2‐methanamine (BIMA) ligands in combination with…”
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Asymmetric Hydrogenation of Amino Ketones Using Chiral RuCl2(diphophine)(1,2-diamine) Complexes
Published in Journal of the American Chemical Society (12-07-2000)Get full text
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Ruthenium(II)-Catalyzed Asymmetric Transfer Hydrogenation of Ketones Using a Formic Acid−Triethylamine Mixture
Published in Journal of the American Chemical Society (13-03-1996)Get full text
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Synthesizing our future
Published in Nature chemistry (01-04-2009)“…Chemistry has a central role in science, and synthesis has a central role in chemistry. Ryoji Noyori from Nagoya University considers where synthetic chemists…”
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Asymmetric Transfer Hydrogenation Catalyzed by Chiral Ruthenium Complexes
Published in Accounts of chemical research (01-02-1997)Get full text
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Metal–ligand bifunctional catalysis for asymmetric hydrogenation
Published in Philosophical transactions of the Royal Society of London. Series A: Mathematical, physical, and engineering sciences (15-04-2005)“…(diphosphine)(diamine) complex without interaction between the unsaturated moiety and the metallic centre. The Ru atom donates a hydride and the NH…”
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An Ab Initio Molecular Orbital Study on the Amino Alcohol-Promoted Reaction of Dialkylzincs and Aldehydes
Published in Journal of the American Chemical Society (01-06-1995)Get full text
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