Search Results - "Nonat, Aline M."
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Optical spin-state polarization in a binuclear europium complex towards molecule-based coherent light-spin interfaces
Published in Nature communications (12-04-2021)“…The success of the emerging field of solid-state optical quantum information processing (QIP) critically depends on the access to resonant optical materials…”
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Mixed d−f3 Coordination Complexes Possessing Improved Near-Infrared (NIR) Lanthanide Luminescent Properties in Aqueous Solution
Published in Inorganic chemistry (20-09-2010)“…The cyclen-based ligand 1, possessing a [1,10]-phenanthroline moiety as a pendant arm, has been used as a ditopic ligand for the complexation of d- and near…”
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3
Mixed f−d Coordination Complexes as Dual Visible- and Near-Infrared-Emitting Probes for Targeting DNA
Published in Inorganic chemistry (01-06-2009)“…A new family of mixed-lanthanide (YbIII and NdIII) transition-metal (f−d) cyclen-RuII(phen)3 (phen = 1,10-phenanthroline) complexes were synthesized as dual…”
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Formation of Heteropolynuclear Lanthanide Complexes Using Macrocyclic Phosphonated Cyclam-Based Ligands
Published in Inorganic chemistry (20-07-2020)“…Ligands L 1 and L 2 , respectively based on a cyclam and a cross-bridged cyclam scaffold functionalized at N1 and N8 by 6-phosphonic-2-methylene pyridyl…”
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5
Formation of Mono- and Polynuclear Luminescent Lanthanide Complexes based on the Coordination of Preorganized Phosphonated Pyridines
Published in Inorganic chemistry (21-05-2018)“…A series of polynuclear assemblies based on ligand L (1,4,7-tris[hydrogen (6-methylpyridin-2-yl)phosphonate]-1,4,7-triazacyclononane) has been developed. The…”
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6
Yb to Tb Cooperative Upconversion in Supramolecularly Assembled Complexes in a Solution
Published in Chemistry an international journal (01-09-2021)“…The podand-type ligand L, based on a tertiary amine substituted by three pyridyl-6-phosphonic acid functions, forms hydrated complexes with Ln3+ cations. The…”
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Octadentate Bispidine Chelators for Tb(III) Complexation: Pyridine Carboxylate versus Pyridine Phosphonate Donors
Published in Inorganic chemistry (19-11-2024)“…With their rigid and preorganized skeleton, bispidine (3,7-diazabicyclo[3.3.1]nonane) chelators are very appealing for the preparation of metal complexes with…”
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Unprecedented Kinetic Inertness for a Mn2+‐Bispidine Chelate: A Novel Structural Entry for Mn2+‐Based Imaging Agents
Published in Angewandte Chemie International Edition (13-07-2020)“…The search for more biocompatible alternatives to Gd3+‐based MRI agents, and the interest in 52Mn for PET imaging call for ligands that form inert Mn2+…”
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9
2,4-Substituted bispidines as rigid hosts for versatile applications: from κ-opioid receptor to metal coordination
Published in Dalton transactions : an international journal of inorganic chemistry (12-11-2019)“…Bispidones (3,7-diazabicyclo[3.3.1]nonan-9-one) are bicyclic analogues of the natural antiarrhythmic agent, spartein. They can straightforwardly be obtained…”
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Structural Variations in Carboxylated Bispidine Ligands: Influence of Positional Isomerism and Rigidity on the Conformation, Stability, Inertness and Relaxivity of their Mn2+ Complexes
Published in Chemistry : a European journal (08-11-2023)“…Mn2+ complexes of 2,4‐pyridyl‐disubstituted bispidine ligands have emerged as more biocompatible alternatives to Gd3+‐based MRI probes. They display…”
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11
Lanthanide-Complex-Loaded Polymer Nanoparticles for Background-Free Single-Particle and Live-Cell Imaging
Published in Chemistry of materials (11-06-2019)“…Imaging single molecules and nanoparticles in complex biological media is highly challenging notably due to autofluorescence of cells and tissues. Lanthanides…”
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12
55/52Mn2+ Complexes with a Bispidine-Phosphonate Ligand: High Kinetic Inertness for Imaging Applications
Published in Inorganic chemistry (29-08-2022)“…Bispidine (3,7-diazabicyclo[3.3.1]nonane) provides a rigid and preorganized scaffold that is particularly interesting for the stable and inert complexation of…”
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13
Upconverting photons at the molecular scale with lanthanide complexes
Published in Chemical science (Cambridge) (28-02-2024)“…In this perspective, we summarise the major milestones to date in the field of molecular upconversion (UC) with lanthanide based coordination complexes. This…”
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14
Yb-to-Eu Cooperative Sensitization Upconversion in a Multifunctional Molecular Nonanuclear Lanthanide Cluster in Solution
Published in Journal of the American Chemical Society (15-05-2024)“…Lanthanide metal clusters excel in combining molecular and material chemistry properties. Here, we report an efficient cooperative sensitization UC phenomenon…”
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From Mono- to Polynuclear Coordination Complexes with a 2,2′-Bipyrimidine-4,4′-dicarboxylate Ligand
Published in Inorganic chemistry (07-06-2021)“…The coordination properties of the ligand 2,2′-bipyrimidine-4,4′-dicarboxylic acid (H2 bpd) with lanthanide(III) ions (Ln = Eu, Tb, or Lu) were investigated…”
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Unprecedented Kinetic Inertness for a Mn 2+ -Bispidine Chelate: A Novel Structural Entry for Mn 2+ -Based Imaging Agents
Published in Angewandte Chemie International Edition (13-07-2020)“…The search for more biocompatible alternatives to Gd -based MRI agents, and the interest in Mn for PET imaging call for ligands that form inert Mn chelates…”
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17
Kinetically Inert Bispidol-Based Cu(II) Chelate for Potential Application to (64/67)Cu Nuclear Medicine and Diagnosis
Published in Inorganic chemistry (04-05-2015)“…A family of 2,4-pyridyl-disubstituted bispidol derivatives bearing methylene carboxylic acid ethyl esters (L1-L3), methylene carboxylic acids (L4 and L5), or…”
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Evaluation of a Bispidine‐Based Chelator for Gallium‐68 and of the Porphyrin Conjugate as PET/PDT Theranostic Agent
Published in Chemistry : a European journal (18-06-2020)“…In this study a bispidine ligand has been applied to the complexation of gallium(III) and radiolabelled with gallium‐68 for the first time. Despite its…”
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A Bispidol Chelator with a Phosphonate Pendant Arm: Synthesis, Cu(II) Complexation, and 64 Cu Labeling
Published in Inorganic chemistry (02-10-2017)“…Here we present the synthesis and characterization of a new bispidine (3,7-diazabicyclo[3.3.1]nonane) ligand with N-methanephosphonate substituents (L ). Its…”
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20
Self-assembled Ln(III) cyclen-based micelles and AuNPs conjugates as candidates for luminescent and magnetic resonance imaging (MRI) agents
Published in Supramolecular chemistry (02-06-2020)“…The tetra-substituted heptadentate cyclen (1,4,7,10-tetraazacyclododecane) based Eu(III)/Tb(III)/Gd(III)-complexes 1.Ln and 2.Ln were developed. 1.Eu/Tb and…”
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