Search Results - "Nohra, Brigitte"
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Polyoxometalate-Based Metal Organic Frameworks (POMOFs): Structural Trends, Energetics, and High Electrocatalytic Efficiency for Hydrogen Evolution Reaction
Published in Journal of the American Chemical Society (31-08-2011)“…The grafting of the triangular 1,3,5-benzene tricarboxylate linkers (denoted trim) on tetrahedral ε-Keggin polyoxometalates (POMs) capped by Zn(II) ions,…”
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Zeolitic Polyoxometalate-Based Metal−Organic Frameworks (Z-POMOFs): Computational Evaluation of Hypothetical Polymorphs and the Successful Targeted Synthesis of the Redox-Active Z-POMOF1
Published in Journal of the American Chemical Society (11-11-2009)“…The targeted design and simulation of a new family of zeolitic metal−organic frameworks (MOFs) based on benzenedicarboxylate (BDC) as the ligand and ε-type…”
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Heterometallic 3d-4f cubane clusters inserted in polyoxometalate matrices
Published in Chemical communications (Cambridge, England) (01-01-2009)“…Unprecedented molecular and bidimensional compounds based on monovacant polyoxometalates capped by heterometallic 3d-4f {LnCu(3)(OH)(3)O} (Ln = La, Gd, Eu)…”
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Assembly of Helicene-Capped N,P,N,P,N-Helicands within CuI Helicates: Impacting Chiroptical Properties by Ligand-Ligand Charge Transfer
Published in Angewandte Chemie International Edition (11-02-2013)“…Combining helicate and helicene chemistry: Pentadentate phosphole‐pyridine helicands (see scheme) coordinated to CuI or AgI centers afford configurationally…”
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Lanthanide Polyoxocationic Complexes: Experimental and Theoretical Stability Studies and Lewis Acid Catalysis
Published in Chemistry : a European journal (09-12-2011)“…The [ε‐PMoV8MoVI4O36(OH)4{LnIII(H2O)}4]5+ (Ln=La, Ce, Nd, Sm) polyoxocations, called εLn4, have been synthesized at room temperature as chloride salts soluble…”
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Chemistry of Bridging Phosphanes: CuI Dimers Bearing 2,5-Bis(2-pyridyl)phosphole Ligands
Published in Chemistry : a European journal (07-04-2008)“…Bis(2‐pyridyl)phosphole 1 reacted with CuI sources giving rise to dicationic or neutral dimers 2,3. In these derivatives, 1 acts as a 1κN:1,2κP:2κN donor with…”
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Mimicking [2,2]Paracyclophane Topology: Molecular Clips for the Coordination-Driven Cofacial Assembly of π-Conjugated Systems
Published in Journal of the American Chemical Society (22-03-2006)“…Self-assembly of CuI dimers, featuring a bridging phosphole ligand, and ditopic cyano-substituted chromophores affords nanosize supramolecular cationic…”
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Insights About the Mechanism of the Formation of Supramolecular π-Stacked Rectangles Based on CuI Bimetallic Complexes Bearing a Bridging Phosphane Ligand
Published in European journal of inorganic chemistry (01-04-2014)“…The variation in the ratio of the reactants in the supramolecular self‐assembly reaction of the bimetallic CuI “U‐shaped” molecular clip 1 with the…”
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Insights About the Mechanism of the Formation of Supramolecular pi -Stacked Rectangles Based on Cu super(I) Bimetallic Complexes Bearing a Bridging Phosphane Ligand
Published in European journal of inorganic chemistry (01-04-2014)“…The variation in the ratio of the reactants in the supramolecular self-assembly reaction of the bimetallic Cu super(I) "U-shaped" molecular clip 1 with the…”
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Insights About the Mechanism of the Formation of Supramolecular [pi]-Stacked Rectangles Based on CuI Bimetallic Complexes Bearing a Bridging Phosphane Ligand
Published in European journal of inorganic chemistry (01-04-2014)“…The variation in the ratio of the reactants in the supramolecular self-assembly reaction of the bimetallic CuI "U-shaped" molecular clip 1 with the…”
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Insights About the Mechanism of the Formation of Supramolecular π‐Stacked Rectangles Based on Cu I Bimetallic Complexes Bearing a Bridging Phosphane Ligand
Published in European journal of inorganic chemistry (01-04-2014)“…Abstract The variation in the ratio of the reactants in the supramolecular self‐assembly reaction of the bimetallic Cu I “U‐shaped” molecular clip 1 with the…”
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Assembly of helicene-capped N,P,N,P,N-helicands within Cu(I) helicates: impacting chiroptical properties by ligand-ligand charge transfer
Published in Angewandte Chemie International Edition (11-02-2013)“…Helicat- und Helicenchemie treffen sich, wenn fünfzähnige Phosphol-Pyridin-Helicanden an CuI- oder AgI-Zentren koordinieren. Bei diesem Prozess entstehen…”
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Coordination-Driven Hierarchical Organization of π-Conjugated Systems: From Molecular to Supramolecular π-Stacked Assemblies
Published in Chemistry : a European journal (25-06-2010)“…The reaction of U‐shaped, bimetallic, CuI complexes, assembled from a heteroditopic pincer, with cyano‐capped π‐conjugated linkers gives a straightforward…”
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Chemistry of Bridging Phosphanes: Cu I Dimers Bearing 2,5‐Bis(2‐pyridyl)phosphole Ligands
Published in Chemistry : a European journal (07-04-2008)“…Abstract Bis(2‐pyridyl)phosphole 1 reacted with Cu I sources giving rise to dicationic or neutral dimers 2 , 3 . In these derivatives, 1 acts as a 1 κN :1,2 κP…”
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Aurophilicity versus Mercurophilicity: Impact of d10-d10 Metallophilic Interactions on the Structure of Metal-Rich Supramolecular Assemblies
Published in Chemistry : a European journal (09-01-2012)“…Treatment of U‐shaped, binuclear CuI complexes 1,1′ (1, counterion: BF4−; 1′, counterion: PF6−) with metal cyanide linear linkers K[Au(CN)2] (3) and Hg(CN)2…”
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Synthesis of Small Tetranuclear Cu(I) Metallacycles Based on Bridging Pseudohalogenide Ions
Published in Inorganic chemistry (04-02-2013)“…Three new ‘short’ metallacycles are selectively obtained from the reaction of a bimetallic CuI ‘U-shape’ molecular clip with, respectively, the cyano CN–,…”
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Chemistry of bridging phosphanes: a comparative study within Cu(I)-Ag(I)-Au(I) triad-based homonuclear dimers
Published in Chemistry : a European journal (2009)“…Bridging ligands in Ag(I) and Au(I) bimetallic complexes: The P moiety of bis(2-pyridyl)phosphole acts as a symmetrically, semi-, or non-bridging donor in…”
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Coordination Polymers with π-Stacked Metalloparacyclophane Motifs: F-Shaped Mixed-Coordination Dinuclear Connectors
Published in Angewandte Chemie (International ed.) (01-01-2007)“…Stringing letters together: Coordination polymers (CPs) featuring unprecedented F‐shaped dinuclear CuI connectors and π‐stacked metallocyclophane moieties are…”
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Chemistry of Bridging Phosphanes: A Comparative Study within CuI-AgI-AuI Triad-Based Homonuclear Dimers
Published in Chemistry : a European journal (27-04-2009)“…Bridging ligands in AgI and AuI bimetallic complexes: The P moiety of bis(2‐pyridyl)phosphole acts as a symmetrically, semi‐, or non‐bridging donor in AgI…”
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