Palladium-catalyzed metathesis of phenylalkyl- or chloroalkyldigermanes with allylic chlorides at room temperature

Metathesis of phenylalkyldigermanes (1,2-diphenyltetraethyl-, 1,2-diphenyltetramethyl-, phenylpentaethyl- or phenylpentamethyldigermane) or chloroalkyldigermanes (1,2-dichlorotetraethyl- or 1,2-dichlorotetramethyldigermane) with allylic chlorides proceeds smoothly even at room temperature in the pre...

Full description

Saved in:

Bibliographic Details
Published in:	Journal of organometallic chemistry Vol. 553; no. 1; pp. 493 - 496
Main Authors:	Nakano, Taichi, Enokido, Tatsuki, Noda, Sigeyuki, A-ihara, Nao-aki, Kosugi, Masanori, Migita, Toshihiko
Format:	Journal Article
Language:	English
Published:	Elsevier B.V 25-02-1998
Subjects:	Allylgermanes Digermane Germanium Metathesis Palladium-catalysis Germanium Allylgermanes Digermane Palladium-catalysis Metathesis
Online Access:	Get full text
Tags:	Add Tag No Tags, Be the first to tag this record!

Description
Summary:	Metathesis of phenylalkyldigermanes (1,2-diphenyltetraethyl-, 1,2-diphenyltetramethyl-, phenylpentaethyl- or phenylpentamethyldigermane) or chloroalkyldigermanes (1,2-dichlorotetraethyl- or 1,2-dichlorotetramethyldigermane) with allylic chlorides proceeds smoothly even at room temperature in the presence of tris(dibenzylideneacetone)dipalladium(0) to afford the corresponding 2-alkenylgermanes in good to high yields.
ISSN:	0022-328X 1872-8561
DOI:	10.1016/S0022-328X(97)00651-7