Search Results - "Nocera, Daniel G."
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Self-healing catalysis in water
Published in Proceedings of the National Academy of Sciences - PNAS (19-12-2017)“…Principles for designing self-healing water-splitting catalysts are presented together with a formal kinetics model to account for the key chemical steps…”
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General Paradigm in Photoredox Nickel‐Catalyzed Cross‐Coupling Allows for Light‐Free Access to Reactivity
Published in Angewandte Chemie International Edition (08-06-2020)“…Self‐sustained NiI/III cycles are established as a potentially general paradigm in photoredox Ni‐catalyzed carbon–heteroatom cross‐coupling reactions through a…”
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A Functionally Stable Manganese Oxide Oxygen Evolution Catalyst in Acid
Published in Journal of the American Chemical Society (23-04-2014)“…First-row metals have been a target for the development of oxygen evolution reaction (OER) catalysts because they comprise noncritical elements. We now report…”
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Photocatalytic Hydromethylation and Hydroalkylation of Olefins Enabled by Titanium Dioxide Mediated Decarboxylation
Published in Journal of the American Chemical Society (21-10-2020)“…A versatile method for the hydromethylation and hydroalkylation of alkenes at room temperature is achieved by using the photooxidative redox capacity of the…”
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In Situ Formation of an Oxygen-Evolving Catalyst in Neutral Water Containing Phosphate and Co2
Published in Science (American Association for the Advancement of Science) (22-08-2008)“…The utilization of solar energy on a large scale requires its storage. In natural photosynthesis, energy from sunlight is used to rearrange the bonds of water…”
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6
Self-healing oxygen evolution catalysts
Published in Nature communications (10-03-2022)“…Electrochemical and photoelectrochemical water splitting offers a scalable approach to producing hydrogen from renewable sources for sustainable energy…”
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Mechanistic Studies of the Oxygen Evolution Reaction Mediated by a Nickel–Borate Thin Film Electrocatalyst
Published in Journal of the American Chemical Society (06-03-2013)“…A critical determinant of solar-driven water splitting efficiency is the kinetic profile of the O2 evolving catalyst (OEC). We now report the kinetic profiles…”
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Mechanistic Studies of the Oxygen Evolution Reaction by a Cobalt-Phosphate Catalyst at Neutral pH
Published in Journal of the American Chemical Society (24-11-2010)“…The mechanism of the oxygen evolution reaction (OER) by catalysts prepared by electrodepositions from Co2+ solutions in phosphate electrolytes (Co-Pi) was…”
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Nature of Activated Manganese Oxide for Oxygen Evolution
Published in Journal of the American Chemical Society (02-12-2015)“…Electrodeposited manganese oxide films (MnOx) are promising stable oxygen evolution catalysts. They are able to catalyze the oxygen evolution reaction in…”
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Powering the Planet: Chemical Challenges in Solar Energy Utilization
Published in Proceedings of the National Academy of Sciences - PNAS (24-10-2006)“…Global energy consumption is projected to increase, even in the face of substantial declines in energy intensity, at least 2-fold by midcentury relative to the…”
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Light-driven fine chemical production in yeast biohybrids
Published in Science (American Association for the Advancement of Science) (16-11-2018)“…Inorganic-biological hybrid systems have potential to be sustainable, efficient, and versatile chemical synthesis platforms by integrating the light-harvesting…”
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12
Nickel-borate oxygen-evolving catalyst that functions under benign conditions
Published in Proceedings of the National Academy of Sciences - PNAS (08-06-2010)“…Thin catalyst films with electrocatalytic water oxidation properties similar to those of a recently reported Co-based catalyst can be electrodeposited from…”
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Elucidation of a Redox-Mediated Reaction Cycle for Nickel-Catalyzed Cross Coupling
Published in Journal of the American Chemical Society (09-01-2019)“…A reaction cycle for redox-mediated, Ni-catalyzed aryl etherification is proposed under both photoredox and electrochemically mediated conditions. We…”
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14
Reversible, Long-Range Radical Transfer in E. coli Class Ia Ribonucleotide Reductase
Published in Accounts of chemical research (19-11-2013)“…Ribonucleotide reductases (RNRs) catalyze the conversionof nucleotides to 2′-deoxynucleotides and are classified on the basis of the metallo-cofactor used to…”
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Influence of iron doping on tetravalent nickel content in catalytic oxygen evolving films
Published in Proceedings of the National Academy of Sciences - PNAS (14-02-2017)“…Iron doping of nickel oxide films results in enhanced activity for promoting the oxygen evolution reaction (OER). Whereas this enhanced activity has been…”
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16
Structure–Activity Correlations in a Nickel–Borate Oxygen Evolution Catalyst
Published in Journal of the American Chemical Society (18-04-2012)“…An oxygen evolution catalyst that forms as a thin film from Ni(aq)2+ solutions containing borate electrolyte (Ni–Bi) has been studied by in situ X-ray…”
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17
Ten-percent solar-to-fuel conversion with nonprecious materials
Published in Proceedings of the National Academy of Sciences - PNAS (30-09-2014)“…Direct solar-to-fuels conversion can be achieved by coupling a photovoltaic device with water-splitting catalysts. We demonstrate that a solar-to-fuels…”
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Design of template-stabilized active and earth-abundant oxygen evolution catalysts in acid
Published in Chemical science (Cambridge) (01-07-2017)“…Oxygen evolution reaction (OER) catalysts that are earth-abundant and are active and stable in acid are unknown. Active catalysts derived from Co and Ni oxides…”
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Probing Edge Site Reactivity of Oxidic Cobalt Water Oxidation Catalysts
Published in Journal of the American Chemical Society (30-03-2016)“…Differential electrochemical mass spectrometry (DEMS) analysis of the oxygen isotopologues produced by 18O-labeled Co-OEC in H2 16O reveals that water…”
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Fractionalized excitations in the spin-liquid state of a kagome-lattice antiferromagnet
Published in Nature (London) (20-12-2012)“…Neutron scattering measurements on single-crystal samples of the mineral herbertsmithite, which is a spin-1/2 kagome-lattice antiferromagnet, provide evidence…”
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