Search Results - "Nocentini, Tiziano"

gem-Heterosubstituted (stannyl)methylsilanes as synthetic equivalents of functionalized α-stannyl(methyl) anions by Tanini, Damiano, Nocentini, Tiziano, Capperucci, Antonella

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HMDST as Useful Tool in Organic Synthesis: A Further Step in the Delivery of Sulfur Functionalities by Capperucci, Antonella, Degl'Innocenti, Alessandro, Nocentini, Tiziano, Castagnoli, Giulio, Malesci, Irene, Cerreti, Arianna

“…Bis(trimethylsilyl)sulfide (HMDST) was demostrated to be a very efficient reagent in the delivery of sulfur functionalities, allowing us to synthesize a wide…”
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Development of a Scalable Synthesis of Oligomeric Piperidine‑N‑O‑alkyl Ethers by Cote, Everett, Chafin, Laura, DiFazio, Mike, Robbins, Jim, Kotrola, Joe, Nocentini, Tiziano, Schoening, Kai-Uwe

“…An efficient two-step manufacturing process for a novel polypiperidine-N-O-alkyl ether was developed. Starting from an oligomeric 2,2,6,6-tetramethylpiperidine…”
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Synthesis, metallation and nucleophilic reactivity of 2,6-bis(trialkylsilyl)-4H-thiopyrans by Nocentini, Tiziano, Bouillon, Jean-Philippe, Capperucci, Antonella, Portella, Charles

“…We report herein (i) the synthesis of 2,6-bis(trialkylsilyl)-4H-thiopyrans by thionation-cylisation of 1,5-bis(acylsilanes) and (ii) the lithiation of these…”
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Organothiosilanes in the synthesis of functionalized benzothiophenes and benzofurans by Capperucci, Antonella, Degl'Innocenti, Alessandro, Nocentini, Tiziano, Pollicino, Salvatore

“…Fluoride-ion-induced reactivity of bromo(phenylthio)methyltrimethylsilane with o-hydroxy benzaldehyde and o-mercaptobenzyl alcohol afforded direct and simple…”
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An easy access to α,β-unsaturated thioacylsilanes: a useful route to silylated 1,2-dithiins by Capperucci, Antonella, Degl'Innocenti, Alessandro, Biondi, Simona, Nocentini, Tiziano, Rinaudo, Giuseppe

“…Treatment of different silylated allenes with hexamethyldisilathiane (HMDST) in the presence of CoCl 2·6H 2O affords an easy and high yielding access to…”
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Fluoride-induced coupling of perfluoroketene dithioacetals with silyl alkynes: A way towards new polyfunctionalized trifluoromethyl building blocks by Nocentini, Tiziano, Brulé, Cédric, Bouillon, Jean-Philippe, Gouault-Bironneau, Sonia, Portella, Charles

“…Under fluoride activation, the vinyl fluorine of perfluoroketene dithioacetal may be substituted by silylated nucleophiles. Using silyl alkynes, a formal…”
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2-Trimethylsilyl-1,3-dithiolane as a masked dithiolane anion by Degl'Innocenti, Alessandro, Capperucci, Antonella, Nocentini, Tiziano

“…2-Trimethylsilyl-1,3-dithiolane, easily obtainable through transthioacetalization of corresponding silylated acetals, can be efficiently reacted, under…”
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α,β-Unsaturated thioacylsilanes as efficient dienes in hetero Diels–Alder reactions by Capperucci, Antonella, Degl'Innocenti, Alessandro, Nocentini, Tiziano, Biondi, Simona, Dini, Francesca

“…Reaction of several α,β-unsaturated thioacylsilanes with in situ generated thioaldehydes and thioacylsilanes affords under mild conditions a clean and…”
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Acetylenic silyl ketone as polysynthetic equivalent of useful building blocks in organic synthesis by Capperucci, Antonella, Degl'Innocenti, Alessandro, Dondoli, Paolo, Nocentini, Tiziano, Reginato, Gianna, Ricci, Alfredo

“…Ethynyl silyl ketone 1 proved to be a very efficient Michael acceptor in carbocupration and metallocupration reactions. In particular, when using…”
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Synthesis and Stereoselective Functionalization of Sulfur-Containing Silyl Heterocycles by Degl'Innocenti, Alessandro, Capperucci, Antonella, Castagnoli, Giulio, Malesci, Irene, Nocentini, Tiziano

“…2-Silylated five-membered heterocycles can be easily accessed through reaction of bromo(methoxy)methylsilane and dithiols, mercapto amines, and mercapto…”
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Synthesis and Reactivity of New Silylated Sulfur-Containing Heterocyles Through Thionation of Bis(Acylsilanes) by Nocentini, Tiziano, Bouillon, Jean-Philippe, Capperucci, Antonella, Portella, Charles, Degl'Innocenti, Alessandro

“…The optimization of the synthesis of 2,6-bis(trialkylsilyl)4H-thiopyranes and some aspects of the reactivity of the corresponding lithium salts with alkyl…”
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