Search Results - "Nobuto, Daisuke"

Structure and Reaction Pathway of TMP-Zincate:  Amido Base or Alkyl Base? by Uchiyama, Masanobu, Matsumoto, Yotaro, Nobuto, Daisuke, Furuyama, Taniyuki, Yamaguchi, Kentaro, Morokuma, Keiji

“…The novel directed ortho metalation (DoM) reagents for functionalized aromatic rings, TMP-Zn-ates (R2Zn(TMP)Li (R = Me, 1; t Bu, 2)), have been reported to be…”
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On the Kinetic and Thermodynamic Reactivity of Lithium Di(alkyl)amidozincate Bases in Directed Ortho Metalation by Kondo, Yoshinori, Morey, James V, Morgan, Jacqueline C, Naka, Hiroshi, Nobuto, Daisuke, Raithby, Paul R, Uchiyama, Masanobu, Wheatley, Andrew E. H

“…Sequential reaction of HTMP (= 2,2,6,6-tetramethylpiperidine) with n BuLi and Et2Zn affords unsolvated polymer chains of EtZn(μ-Et)(μ-TMP)Li 6. The scope of…”
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Ligand-Activated Lithium-Mediated Zincation of N-Phenylpyrrole by Seggio, Anne, Lannou, Marie-Isabelle, Chevallier, Floris, Nobuto, Daisuke, Uchiyama, Masanobu, Golhen, Stéphane, Roisnel, Thierry, Mongin, Florence

“…Metalation of N‐phenylpyrrole by using an in situ mixture of ZnCl2⋅TMEDA (0.5 equiv; TMEDA=N,N,N′,N′‐tetramethylethylenediamine) and LiTMP (1.5 equiv;…”
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Suppressing the Anionic Fries Rearrangement of Aryl Dialkylcarbamates; the Isolation of a Crystalline ortho-Deprotonated Carbamate by García, Felipe, McPartlin, Mary, Morey, James V., Nobuto, Daisuke, Kondo, Yoshinori, Naka, Hiroshi, Uchiyama, Masanobu, Wheatley, Andrew E. H.

“…In the presence of organolithium bases phenyl dialkylcarbamates have previously been shown to undergo facile rearrangement to yield the corresponding…”
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A New Interpretation of the Reaction Pathway of Deprotonative Metalation with TMP−Zn-ate/TMEDA Complex [TMEDA·Na(μ- t Bu)(μ-TMP)Zn( t Bu)] by Nobuto, Daisuke, Uchiyama, Masanobu

“…Density functional theory (DFT) calculations of possible reaction pathways and mechanisms for the deprotonation of benzene with Mulvey's reagent,…”
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Ligand-Activated Lithium-Mediated Zincation of N-Phenylpyrrole by Seggio, Anne, Lannou, Marie-Isabelle, Chevallier, Floris, Nobuto, Daisuke, Uchiyama, Masanobu, Golhen, Stéphane, Roisnel, Thierry, Mongin, Florence

“…Metalation of N-phenylpyrrole by using an in situ mixture of ZnCl(2)TMEDA (0.5 equiv; TMEDA=N,N,N',N'-tetramethylethylenediamine) and LiTMP (1.5 equiv;…”
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