Search Results - "Neuman, I"

Effect of Apical Ligands, Substituents and Oxidation States on the Electronic Structure of Co(III) Corrolates by Neuman, Nicolás I.

“…Cobalt(III) corroles are the most commonly studied types of metallocorroles, yet the details of their electronic structure, ground spin states and place of…”
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CAAC‐Based Thiele and Schlenk Hydrocarbons by Maiti, Avijit, Stubbe, Jessica, Neuman, Nicolás I., Kalita, Pankaj, Duari, Prakash, Schulzke, Carola, Chandrasekhar, Vadapalli, Sarkar, Biprajit, Jana, Anukul

“…Diradicals have been of tremendous interest for over a century ever since the first reports of p‐ and m‐phenylene‐bridged diphenylmethylradicals in 1904 by…”
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Adherence to PALS Sepsis Guidelines and Hospital Length of Stay by Paul, Raina, Neuman, Mark I, Monuteaux, Michael C, Melendez, Elliot

“…Few studies have evaluated sepsis guideline adherence in a tertiary pediatric emergency department setting. We sought to evaluate (1) adherence to 2006…”
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Use of CT for Head Trauma: 2007-2015 by Burstein, Brett, Upton, Julia E M, Terra, Heloisa Fuzaro, Neuman, Mark I

“…International efforts have been focused on identifying children at low risk of clinically important traumatic brain injury in whom computed tomography (CT)…”
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Effective Anisotropic Interactions in Spin Pairs Containing High-Spin Ions with Large Zero-Field Splitting by Neuman, Nicolás I

“…Analytic and numeric derivations are made of the effective exchange and dipolar magnetic interactions between spin pairs containing S = 3/2 ions, such as…”
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Remarkable Enhancement of Catalytic Activity of Cu‐Complexes in the Electrochemical Hydrogen Evolution Reaction by Using Triply Fused Porphyrin by Chandra, Shubhadeep, Hazari, Arijit Singha, Song, Qian, Hunger, David, Neuman, Nicolás. I., Slageren, Joris, Klemm, Elias, Sarkar, Biprajit

“…A bimetallic triply fused copper(II) porphyrin complex (1) was prepared, comprising two monomeric porphyrin units linked through β–β, meso–meso, β′–β′ triple…”
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Directed Design of a Au I Complex with a Reduced Mesoionic Carbene Radical Ligand: Insights from 1,2,3-Triazolylidene Selenium Adducts and Extensive Electrochemical Investigations by Beerhues, Julia, Neubrand, Maren, Sobottka, Sebastian, Neuman, Nicolás I, Aberhan, Hannes, Chandra, Shubhadeep, Sarkar, Biprajit

“…Carbene-based radicals are important for both fundamental and applied chemical research. Herein, extensive electrochemical investigations of nine different…”
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Cobalt Corroles as Electrocatalysts for Water Oxidation: Strong Effect of Substituents on Catalytic Activity by Neuman, Nicolás I, Albold, Uta, Ferretti, Eleonora, Chandra, Shubhadeep, Steinhauer, Simon, Rößner, Paul, Meyer, Franc, Doctorovich, Fabio, Vaillard, Santiago E, Sarkar, Biprajit

“…Two Co­(III) complexes (1Py 2 and 2Py 2 ) of new corrole ligands H 3 L1 (5,15-bis­(p-methylcarboxyphenyl)-10-(o-methylcarboxyphenyl)­corrole) and H 3 L2…”
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Activation of Aromatic C−F Bonds by a N‐Heterocyclic Olefin (NHO) by Mandal, Debdeep, Chandra, Shubhadeep, Neuman, Nicolás I., Mahata, Alok, Sarkar, Arighna, Kundu, Abhinanda, Anga, Srinivas, Rawat, Hemant, Schulzke, Carola, Mote, Kaustubh R., Sarkar, Biprajit, Chandrasekhar, Vadapalli, Jana, Anukul

“…A N‐heterocyclic olefin (NHO), a terminal alkene selectively activates aromatic C−F bonds without the need of any additional catalyst. As a result, a…”
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A Prediction Model to Identify Febrile Infants ≤60 Days at Low Risk of Invasive Bacterial Infection by Aronson, Paul L, Shabanova, Veronika, Shapiro, Eugene D, Wang, Marie E, Nigrovic, Lise E, Pruitt, Christopher M, DePorre, Adrienne G, Leazer, Rianna C, Desai, Sanyukta, Sartori, Laura F, Marble, Richard D, Rooholamini, Sahar N, McCulloh, Russell J, Woll, Christopher, Balamuth, Fran, Alpern, Elizabeth R, Shah, Samir S, Williams, Derek J, Browning, Whitney L, Shah, Nipam, Neuman, Mark I

“…To derive and internally validate a prediction model for the identification of febrile infants ≤60 days old at low probability of invasive bacterial infection…”
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Isolable Cu(I) Complexes of Extremely Electron-Poor, Completely Unreduced o‑Quinone and “Di‑o‑Quinone” Ligands Stabilized through π–π Interactions in the Secondary Coordination Sphere by Albold, Uta, Hoyer, Carolin, Neuman, Nicolás I, Sobottka, Sebastian, Hazari, Arijit S, Lahiri, Goutam Kumar, Sarkar, Biprajit

“…The copper–quinone interaction plays important roles in diverse fields such as biochemistry, catalysis, and optically/magnetically switchable materials…”
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Nitric Oxide Is Reduced to HNO by Proton-Coupled Nucleophilic Attack by Ascorbate, Tyrosine, and Other Alcohols. A New Route to HNO in Biological Media? by Suarez, Sebastián A, Neuman, Nicolás I, Muñoz, Martina, Álvarez, Lucı́a, Bikiel, Damián E, Brondino, Carlos D, Ivanović-Burmazović, Ivana, Miljkovic, Jan Lj, Filipovic, Milos R, Martí, Marcelo A, Doctorovich, Fabio

“…The role of NO in biology is well established. However, an increasing body of evidence suggests that azanone (HNO), could also be involved in biological…”
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Discussing Endogenous NO•/HNO Interconversion Aided by Phenolic Drugs and Vitamins by Hamer, Mariana, Suarez, Sebastian A, Neuman, Nicolás I, Alvarez, Lucía, Muñoz, Martina, Marti, Marcelo A, Doctorovich, Fabio

“…The reduction of NO• to HNO/NO– under biologically compatible conditions has always been thought as unlikely, mostly because of the negative reduction…”
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EPR as a Tool for Study of Isolated and Coupled Paramagnetic Centers in Coordination Compounds and Macromolecules of Biological Interest by Rizzi, Alberto C., Neuman, Nicolás I., González, Pablo J., Brondino, Carlos D.

“…Continuous Wave Electron Paramagnetic Resonance (CW EPR) is an essential spectroscopic tool for study of systems containing unpaired electrons. The potential…”
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A prospective study of sleep duration and pneumonia risk in women by Patel, Sanjay R, Malhotra, Atul, Gao, Xiang, Hu, Frank B, Neuman, Mark I, Fawzi, Wafaie W

“…Experimental data suggest sleep deprivation may impair host immunity. We sought to assess the effect of poor sleep on pneumonia risk. Prospective,…”
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Twisted Push–Pull Alkenes Bearing Geminal Cyclicdiamino and Difluoroaryl Substituents by Kundu, Abhinanda, Chandra, Shubhadeep, Mandal, Debdeep, Neuman, Nicolás I, Mahata, Alok, Anga, Srinivas, Rawat, Hemant, Pal, Sudip, Schulzke, Carola, Sarkar, Biprajit, Chandrasekhar, Vadapalli, Jana, Anukul

“…The systematic combination of N-heterocyclic olefins (NHOs) with fluoroarenes resulted in twisted push–pull alkenes. These alkenes carry electron-donating…”
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Placental trophoblast-specific overexpression of chemerin induces preeclampsia-like symptoms by Tan, Lunbo, Chen, Zhilong, Sun, Fen, Zhou, Zhuoqun, Zhang, Baozhen, Wang, Baobei, Chen, Jie, Li, Mengxia, Xiao, Tianxia, Neuman, Rugina I, Niu, Jianmin, Verdonk, Koen, Lu, Xifeng, Zhang, Jian V, Danser, A H Jan, Yang, Qing, Fan, Xiujun

“…Maternal circulating levels of the adipokine chemerin are elevated in preeclampsia, but its origin and contribution to preeclampsia remain unknown. We…”
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Electrochemistry and Spin‐Crossover Behavior of Fluorinated Terpyridine‐Based Co(II) and Fe(II) Complexes by Nößler, Maite, Jäger, René, Hunger, David, Reimann, Marc, Bens, Tobias, Neuman, Nicolás I., Singha Hazari, Arijit, Kaupp, Martin, Slageren, Joris, Sarkar, Biprajit

“…Due to their ability to form stable molecular complexes that have tailor‐made properties, terpyridine ligands are of great interest in chemistry and material…”
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Directed Design of a AuI Complex with a Reduced Mesoionic Carbene Radical Ligand: Insights from 1,2,3‐Triazolylidene Selenium Adducts and Extensive Electrochemical Investigations by Beerhues, Julia, Neubrand, Maren, Sobottka, Sebastian, Neuman, Nicolás I., Aberhan, Hannes, Chandra, Shubhadeep, Sarkar, Biprajit

“…Carbene‐based radicals are important for both fundamental and applied chemical research. Herein, extensive electrochemical investigations of nine different…”
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Isomerization Reactions in Anionic Mesoionic Carbene-Borates and Control of Properties and Reactivities in the Resulting Co II  Complexes through Agostic Interactions by Stubbe, Jessica, Neuman, Nicolás I, McLellan, Ross, Sommer, Michael G, Nößler, Maite, Beerhues, Julia, Mulvey, Robert E, Sarkar, Biprajit

“…We present herein anionic borate-based bi-mesoionic carbene compounds of the 1,2,3-triazol-4-ylidene type that undergo C-N isomerization reactions. The…”
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