Search Results - "Neu, Mary P."
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Experimental and Theoretical Comparison of Actinide and Lanthanide Bonding in M[N(EPR2)2]3 Complexes (M = U, Pu, La, Ce; E = S, Se, Te; R = Ph, iPr, H)
Published in Inorganic chemistry (07-01-2008)“…Treatment of M[N(SiMe3)2]3 (M = U, Pu (An); La, Ce (Ln)) with NH(EPPh2)2 and NH(EPiPr2)2 (E = S, Se), afforded the neutral complexes M[N(EPR2)2]3 (R = Ph,…”
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2
Enhanced Exopolymer Production and Chromium Stabilization in Pseudomonas putida Unsaturated Biofilms
Published in Applied and Environmental Microbiology (01-03-2006)“…Chromium-contaminated soils threaten surface and groundwater quality at many industrial sites. In vadose zones, indigenous bacteria can reduce Cr(VI) to…”
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3
Plutonium(V/VI) Reduction by the Metal-Reducing Bacteria Geobacter metallireducens GS-15 and Shewanella oneidensis MR-1
Published in Applied and Environmental Microbiology (01-06-2009)“…We examined the ability of the metal-reducing bacteria Geobacter metallireducens GS-15 and Shewanella oneidensis MR-1 to reduce Pu(VI) and Pu(V). Cell…”
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4
Complexation of Pu(IV) with the Natural Siderophore Desferrioxamine B and the Redox Properties of Pu(IV)(siderophore) Complexes
Published in Inorganic chemistry (05-02-2007)“…The bioavailability and mobility of Pu species can be profoundly affected by siderophores and other oxygen-rich organic ligands. Pu(IV)(siderophore) complexes…”
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5
Biological Reduction of Np(V) and Np(V) Citrate by Metal-Reducing Bacteria
Published in Environmental science & technology (15-04-2007)“…Oxidized actinide species are often more mobile than reduced forms. Bioremediation strategies have been developed to exploit this chemistry and stabilize…”
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Plutonium(IV) Reduction by the Metal-Reducing Bacteria Geobacter metallireducens GS15 and Shewanella oneidensis MR1
Published in Applied and Environmental Microbiology (01-09-2007)“…The bacterial reduction of actinides has been suggested as a possible remedial strategy for actinide-contaminated environments, and the bacterial reduction of…”
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7
Redox Behavior of Cyclo[6]pyrrole in the Formation of a Uranyl Complex
Published in Inorganic chemistry (25-06-2007)“…A uranyl complex, the first metal complex to be formed from the cyclo[n]pyrrole series of expanded porphyrins, is formed when cyclo[6]pyrrole is treated with…”
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8
Actinide and metal toxicity to prospective bioremediation bacteria
Published in Environmental microbiology (01-01-2005)“…Summary Bacteria may be beneficial for alleviating actinide contaminant migration through processes such as bioaccumulation or metal reduction. However, sites…”
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9
Solubility of plutonium(VI) carbonate in saline solutions
Published in Geochimica et cosmochimica acta (01-06-2007)“…Among the plutonium oxidation states found to form in the environment, mobile plutonium(VI) can exist under oxidizing conditions and in waters with high…”
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10
Higher Order Speciation Effects on Plutonium L3 X-ray Absorption Near Edge Spectra
Published in Inorganic chemistry (12-01-2004)“…Pu L3 X-ray near edge absorption spectra for Pu(0−VII) are reported for more than 60 chalcogenides, chlorides, hydrates, hydroxides, nitrates, carbonates,…”
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11
Siderophore Mediated Plutonium Accumulation by Microbacterium flavescens (JG-9)
Published in Environmental science & technology (15-07-2001)“…Uptake of plutonium and uranium mediated by the siderophore desferrioxamine-B (DFOB) has been studied for the common soil aerobe Microbacterium flavescens…”
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Experimental and theoretical comparison of actinide and lanthanide bonding in M[N(EPR(2))(2)](3) complexes (M = U, Pu, La, Ce; E = S, Se, Te; R = Ph, iPr, H)
Published in Inorganic chemistry (07-01-2008)“…Treatment of M[N(SiMe3)2]3 (M = U, Pu (An); La, Ce (Ln)) with NH(EPPh2)2 and NH(EPiPr2)2 (E = S, Se), afforded the neutral complexes M[N(EPR2)2]3 (R = Ph,…”
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13
Structural and Spectroscopic Characterization of Plutonyl(VI) Nitrate under Acidic Conditions
Published in Inorganic chemistry (16-05-2011)“…The plutonyl(VI) dinitrate complex [PuO2(NO3)2(H2O)2]·H2O (1) has been structurally characterized by single-crystal X-ray diffraction and spectroscopically…”
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14
Dissolution of Plutonium(IV) Hydroxide by Desferrioxamine Siderophores and Simple Organic Chelators
Published in Inorganic chemistry (15-07-2002)“…Plutonium is thought to exist mostly as low soluble plutonium(IV) species in the environment and, therefore, has low potential of becoming mobile. Due to their…”
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15
U(IV) Chalcogenolates Synthesized via Oxidation of Uranium Metal by Dichalcogenides
Published in Inorganic chemistry (04-09-2006)“…Treatment of uranium metal with dichalcogenides in the presence of a catalytic amount of iodine in pyridine affords molecular U(IV) chalcogenolates that do not…”
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Uranium(III)/(IV) Nitrile Adducts Including UI4(N⋮CPh)4, a Synthetically Useful Uranium(IV) Complex
Published in Inorganic chemistry (17-10-2005)“…The synthesis of complexes used to elucidate an understanding of fundamental An(III) and An(IV) coordination chemistry requires the development of suitable…”
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17
Pu(VI) Hydrolysis: Further Evidence for a Dimeric Plutonyl Hydroxide and Contrasts with U(VI) Chemistry
Published in Inorganic chemistry (20-02-2006)“…A significant fraction of plutonium that is soluble in environmental waters and other aqueous solutions can be present as complexes of plutonyl, PuO2 2+. Few…”
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Covalency in the f-element-chalcogen bond Computational studies of [M(N(EPH2)2)3] (M = La, U, Pu; E = O, S, Se, Te)
Published in Journal of alloys and compounds (01-11-2007)Get full text
Conference Proceeding -
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A Molecular Actinide-Tellurium Bond and Comparison of Bonding in [MIII{N(TePiPr2)2}3] (M=U, La)
Published in Angewandte Chemie International Edition (27-02-2006)“…Are the actinides going soft? The first molecular complexes containing an actinide–tellurium bond, [U{N(TePiPr2)2}3] (see picture) and the isostructural…”
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20
Iron(III) Coordination Properties of a Pyoverdin Siderophore Produced by Pseudomonas putida ATCC 33015
Published in Inorganic chemistry (10-07-2006)“…The iron complexation of a fluorescent green pyoverdin siderophore produced by the environmental bacterium Pseudomonas putida was characterized by solution…”
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