Search Results - "Negru,Daniela"
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1
Robust and General Late-Stage Methylation of Aryl Chlorides: Application to Isotopic Labeling of Drug-like Scaffolds
Published in ACS catalysis (01-09-2023)“…The preparation of isotopically labeled compounds for drug discovery and development presents a unique challenge. Both stable and radioactive isotopes must be…”
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2
Rhodium-Catalyzed [(3+2)+2] Carbocyclization of Alkynylidenecyclopropanes with Substituted Allenes: Stereoselective Construction of Tri- and Tetrasubstituted Exocyclic Olefins
Published in Angewandte Chemie International Edition (13-04-2015)“…The development of the stereoselective rhodium‐catalyzed [(3+2)+2] carbocyclization of alkynylidenecyclopropanes (ACPs) with substituted allenes is described…”
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3
Stereoselective Rhodium-Catalyzed [3 + 2 + 1] Carbocyclization of Alkenylidenecyclopropanes with Carbon Monoxide: Theoretical Evidence for a Trimethylenemethane Metallacycle Intermediate
Published in Journal of the American Chemical Society (26-12-2012)“…The theoretically inspired development of a Rh-catalyzed [3 + 2 + 1] carbocyclization of carbon- and heteroatom-tethered alkenylidenecyclopropanes (ACPs) with…”
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4
The Isolation and Characterization of a Rhodacycle Intermediate Implicated in Metal-Catalyzed Reactions of Alkylidenecyclopropanes
Published in Angewandte Chemie International Edition (07-04-2014)“…The isolation and characterization of a rhodacycle intermediate implicated in rhodium‐catalyzed reactions of alkylidenecyclopropanes (ACPs) is described. The…”
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5
Enantioselective Rhodium‐Catalyzed Pauson–Khand Reactions of 1,6‐Chloroenynes with 1,1‐Disubstituted Olefins
Published in Angewandte Chemie International Edition (05-06-2023)“…An enantioselective rhodium(I)‐catalyzed Pauson–Khand reaction (PKR) using 1,6‐chloroenynes that contain challenging 1,1‐disubstituted olefins is described. In…”
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6
Rhodium-catalyzed [(3+2)+1] carbocyclization reactions of alkynylidenecyclopropanes with carbon monoxide: regiospecific construction of polysubstituted phenols
Published in Organic letters (05-09-2014)“…The development of the rhodium-catalyzed [(3+2)+1] carbocyclization reaction of alkynylidenecyclopropanes with carbon monoxide to construct polysubstituted…”
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7
Sequential Reductive Amination-Hydrogenolysis: A One-Pot Synthesis of Challenging Chiral Primary Amines
Published in Advanced synthesis & catalysis (01-08-2011)“…Difficult‐to‐access chiral primary amines were formed in good to high yield and ee using a rare example of a one‐pot synthesis from prochiral ketones…”
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8
Enantioselective Rhodium‐Catalyzed Pauson–Khand Reactions of 1,6‐Chloroenynes with 1,1‐Disubstituted Olefins
Published in Angewandte Chemie (05-06-2023)“…An enantioselective rhodium(I)‐catalyzed Pauson–Khand reaction (PKR) using 1,6‐chloroenynes that contain challenging 1,1‐disubstituted olefins is described. In…”
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Journal Article -
9
Rhodium-Catalyzed [(3+2)+2] Carbocyclization of Alkynylidenecyclopropanes with Substituted Allenes: Stereoselective Construction of Tri- and Tetrasubstituted Exocyclic Olefins
Published in Angewandte Chemie (13-04-2015)“…The development of the stereoselective rhodium‐catalyzed [(3+2)+2] carbocyclization of alkynylidenecyclopropanes (ACPs) with substituted allenes is described…”
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Journal Article -
10
The Isolation and Characterization of a Rhodacycle Intermediate Implicated in Metal-Catalyzed Reactions of Alkylidenecyclopropanes
Published in Angewandte Chemie (07-04-2014)“…The isolation and characterization of a rhodacycle intermediate implicated in rhodium‐catalyzed reactions of alkylidenecyclopropanes (ACPs) is described. The…”
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11
A New Adhesıve Coatıng Solutıon Based On A Natural Anımal Polymer - Part Iı: Predıctıon Of Adhesıon Strength Of The Solutıon
Published in Tekstil ve Konfeksiyon (01-07-2012)“…The second part of the article pursues to research the adhesion properties of a new solution based on a natural animal polymer. Mathematical modeling and the…”
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12
A New Adhesıve Coatıng Solutıon Based On A Natural Anımal Polymer - Part I: Predıctıon Of Breakıng Force And Elongatıon Of Coated Cotton Yarns
Published in Tekstil ve Konfeksiyon (01-04-2012)“…In the first part of the article the influence of the coating material based on a natural animal polymer was investigated. Mathematical modeling and the…”
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Journal Article -
13
Rhodium-Catalyzed [(3+2)+1] Carbocyclization Reactions of Alkynylidenecyclopropanes with Carbon Monoxide: Regiospecific Construction of Polysubstituted Phenols
Published in Organic letters (05-09-2014)“…The development of the rhodium-catalyzed [(3+2)+1] carbocyclization reaction of alkynylidenecyclopropanes with carbon monoxide to construct polysubstituted…”
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Journal Article -
14
Rhodium-Catalyzed Carbocyclizations of Alkylidenecyclopropanes with Allenes and Carbon Monoxide: Stereoselective Construction of Six- and Seven-Membered Rings
Published 01-01-2015“…This thesis is divided in the following manner: Chapter 1 offers a short introduction, Chapter 2 describes the higher-order rhodium-catalyzed…”
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Dissertation