New Stable Germylenes, Stannylenes, and Related Compounds. 1. Stable Germanium(II) and Tin(II) Compounds M(OCH2CH2NMe2)2 (M = Ge, Sn) with Intramolecular Coordination Metal−Nitrogen Bonds. Synthesis and Structure

New Stable Germylenes, Stannylenes, and Related Compounds. 1. Stable Germanium(II) and Tin(II) Compounds M(OCH2CH2NMe2)2 (M = Ge, Sn) with Intramolecular Coordination Metal−Nitrogen Bonds. Synthesis and Structure

New stable monomeric germanium(II) and tin(II) compounds M(OCH2CH2NMe2)2 (M = Ge (1); M = Sn (2)), stabilized by two intramolecular coordination M←N bonds and containing no bulky groups on the metal atoms, were synthesized. The molecular and crystal structures of these compounds, and that of the pre...

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Bibliographic Details
Published in:Organometallics Vol. 22; no. 8; pp. 1675 - 1681
Main Authors: Zemlyansky, Nikolay N, Borisova, Irina V, Kuznetsova, Marianna G, Khrustalev, Victor N, Ustynyuk, Yuri A, Nechaev, Mikhael S, Lunin, Valery V, Barrau, Jacques, Rima, Ghassoub
Format: Journal Article
Language:English
Published: American Chemical Society 14-04-2003
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Summary:New stable monomeric germanium(II) and tin(II) compounds M(OCH2CH2NMe2)2 (M = Ge (1); M = Sn (2)), stabilized by two intramolecular coordination M←N bonds and containing no bulky groups on the metal atoms, were synthesized. The molecular and crystal structures of these compounds, and that of the previously synthesized compound (ArO)2Sn (3; Ar = 2,4,6-(Me2NCH2)3C6H2), were determined by X-ray diffraction analysis. The electronic structures of 1 and 2 were studied by the DFT method.
Bibliography:istex:8315EF74AA25B5FED9EC96A43E4B9FE86A26941D
ark:/67375/TPS-NR325957-6
ISSN:0276-7333
1520-6041
DOI:10.1021/om020719a