Electrooxidation of Urea in Alkaline Solution Using Nickel Hydroxide Activated Carbon Paper Electrodeposited from DMSO Solution

Electrooxidation of Urea in Alkaline Solution Using Nickel Hydroxide Activated Carbon Paper Electrodeposited from DMSO Solution

Electrooxidation of urea plays a substantial role in the elimination of urea-containing wastewater and industrial urea. Here, we report the electrodeposition of nickel hydroxide catalyst on commercial carbon paper (CP) electrodes from dimethyl sulphoxide solvent (Ni(OH)2-DMSO/CP) for urea electrooxi...

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Bibliographic Details
Published in:Catalysts Vol. 11; no. 1; p. 102
Main Authors: Saba A. Aladeemy, Abdullah M. Al-Mayouf, Maged N. Shaddad, Mabrook S. Amer, Nawier K. Almutairi, Mohamed A. Ghanem, Nouf H. Alotaibi, Prabhakarn Arunachalam
Format: Journal Article
Language:English
Published: MDPI AG 01-01-2021
Subjects:
electrodeposition
electrooxidation
nickel hydroxide
non-aqueous solvents
urea
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Summary:Electrooxidation of urea plays a substantial role in the elimination of urea-containing wastewater and industrial urea. Here, we report the electrodeposition of nickel hydroxide catalyst on commercial carbon paper (CP) electrodes from dimethyl sulphoxide solvent (Ni(OH)2-DMSO/CP) for urea electrooxidation under alkaline conditions. The physicochemical features of Ni(OH)2-DMSO/CP catalysts using scanning electron microscopy and X-ray photoelectron spectroscopy revealed that the Ni(OH)2-DMSO/CP catalyst shows nanoparticle features, with loading of <1 wt%. The cyclic voltammetry and electrochemical impedance spectroscopy revealed that the Ni(OH)2-DMSO/CP electrode has a urea oxidation onset potential of 0.33 V vs. Ag/AgCl and superior electrocatalytic performance, which is a more than 2-fold higher activity in comparison with the counterpart Ni(OH)2 catalyst prepared from the aqueous electrolyte. As expected, the enhancement in electrocatalytic activity towards urea was associated with the superficial enrichment in the electrochemically active surface area of the Ni(OH)2-DMSO/CP electrodes. The results might be a promising way to activate commercial carbon paper with efficient transition metal electrocatalysts, for urea electrooxidation uses in sustainable energy systems, and for relieving water contamination.
ISSN:2073-4344
DOI:10.3390/catal11010102