Search Results - "Nash, John J"
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1
Reactivity of the 3,4,5-Tridehydropyridinium Cation--An Aromatic σ,σ,σ-Triradical
Published in Angewandte Chemie (International ed.) (08-12-2008)“…Seeing the sites: Reactivity studies on the σ,σ,σ‐triradical 3,4,5‐tridehydropyridinium cation by using a Fourier transform ion cyclotron resonance mass…”
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2
Dehydration Pathways for Glucose and Cellobiose During Fast Pyrolysis
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (18-10-2018)“…A full understanding of all possible elementary reactions applicable to cellulose fast pyrolysis is key to developing a comprehensive kinetic model for fast…”
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3
Management and Outcomes of Facial Paralysis from Intratemporal Blunt Trauma: A Systematic Review
Published in The Laryngoscope (2010)“…To systematically review the existing literature on outcomes and management of facial paralysis resulting from intratemporal blunt trauma. Systematic review of…”
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4
Relative Reactivities of Three Isomeric Aromatic Biradicals with a 1,4‐Biradical Topology Are Controlled by Polar Effects
Published in Chemistry : a European journal (02-05-2019)“…Unexpectedly, the 5‐dehydroquinoline radical cation was formed in the gas phase from the 5‐iodo‐8‐nitroquinolinium cation upon ion‐trap collision‐activated…”
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5
Gas-Phase Reactivity of Quinoline-Based Singlet Oxenium Cations
Published in Journal of organic chemistry (19-04-2024)“…Isomeric quinolyloxenium cations were generated in the gas phase in an ion trap mass spectrometer to explore their reactions. The structures of some products…”
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6
Gas-Phase Reactivity of Phenylcarbyne Anions
Published in Journal of the American Chemical Society (18-05-2022)“…Gas-phase reactivities of the phenylcarbyne anion and its four derivatives were studied using a linear quadrupole ion trap mass spectrometer. The phenylcarbyne…”
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7
Effects of the Distance between Radical Sites on the Reactivities of Aromatic Biradicals
Published in Journal of organic chemistry (02-07-2020)“…Coupling of the radical sites in isomeric benzynes is known to hinder their radical reactivity. In order to determine how far apart the radical sites must be…”
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8
Measurement of the Proton Affinities of a Series of Mono- and Biradicals of Pyridine
Published in Journal of the American Chemical Society (13-05-2020)“…The proton affinity (PA) of a neutral molecule is defined as the negative of the enthalpy change for the gas-phase reaction between a proton and the neutral…”
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9
Studies of the Fragmentation Mechanisms of Deprotonated Lignin Model Compounds in Tandem Mass Spectrometry
Published in Analytical chemistry (Washington) (01-09-2020)“…Unlabeled and deuterium-labeled dimeric lignin model compounds with β-O-4 linkages were evaporated and ionized using negative ion mode electrospray ionization,…”
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10
Spin‐Spin Coupling Controls the Gas‐Phase Reactivity of Aromatic σ‐Type Triradicals
Published in Chemistry : a European journal (03-01-2022)“…Examination of the reactions of σ‐type quinolinium‐based triradicals with cyclohexane in the gas phase demonstrated that the radical site that is the least…”
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11
Protonated Ground-State Singlet meta-Pyridynes React from an Excited Triplet State
Published in Journal of organic chemistry (19-02-2021)“…The gaseous 2,6-didehydropyridinium cation and its derivatives transfer a proton to reagents for which the reaction for their singlet ground states is too…”
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12
Reactivity of an Aromatic σ,σ,σ-Triradical: The 2,4,6-Tridehydropyridinium Cation
Published in Angewandte Chemie (International ed.) (01-01-2007)“…Tri‐, bi‐, and monoradicals: The reactivity of a σ,σ,σ‐triradical, 2,4,6‐tridehydropyridinium cation, was compared with that of related mono‐ and biradicals in…”
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13
Spin–Spin Coupling Between Two meta‐Benzyne Moieties In a Quinolinium Tetraradical Cation Increases Their Reactivities
Published in Chemistry : a European journal (21-03-2019)“…The reactivity of a carbon‐centered σ,σ,σ,σ‐type singlet‐ground‐state tetraradical containing two meta‐benzyne moieties was examined in the gas phase…”
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14
Quinoline Triradicals: A Reactivity Study
Published in Journal of the American Chemical Society (24-04-2019)“…The gas-phase reactivities of several protonated quinoline-based σ-type (carbon-centered) mono-, bi-, and triradicals toward dimethyl disulfide (DMDS) were…”
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15
(-)ESI/CAD MSn Procedure for Sequencing Lignin Oligomers Based on a Study of Synthetic Model Compounds with β-O-4 and 5-5 Linkages
Published in Analytical chemistry (Washington) (19-12-2017)“…Seven synthesized G-lignin oligomer model compounds (ranging in size from dimers to an octamer) with 5-5 and/or β-O-4 linkages, and three synthesized S-lignin…”
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16
Spin‐Spin Coupling between the Biradical Moieties in Aromatic Tetraradicals Increases their Reactivity
Published in Israel journal of chemistry (01-08-2023)“…The reactivity of a carbon‐centered σ,σ,σ,σ‐type singlet tetraradical containing two meta‐benzyne moieties, the 2,4,5,7‐tetradehydroquinolinium cation, was…”
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17
Medical Malpractice and Corticosteroid Use
Published in Otolaryngology-head and neck surgery (01-01-2011)“…Objective. To analyze malpractice litigation trends related to the administration of corticosteroids and the reported complications. Study Design…”
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18
An Oxygen‐peri‐Bridged Quinolinium Cation and Its Monoradical Counterpart
Published in European journal of organic chemistry (17-03-2017)“…Generation of a σ,σ,π‐triradical was attempted by collision‐activated dissociation (CAD) of two iodine atoms and an NO· radical from…”
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Substituent Effects on the Reactivity of the 2,4,6‐Tridehydropyridinium Cation, an Aromatic σ,σ,σ‐Triradical
Published in European journal of organic chemistry (13-12-2018)“…2,4,6‐Tridehydropyridinium cation (7) undergoes three consecutive atom or atom group ions from reagent molecules in the gas phase. By placing a…”
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20
Fast Pyrolysis of 13C‑Labeled Cellobioses: Gaining Insights into the Mechanisms of Fast Pyrolysis of Carbohydrates
Published in Journal of organic chemistry (06-02-2015)“…A fast-pyrolysis probe/tandem mass spectrometer combination was utilized to determine the initial fast-pyrolysis products for four different selectively…”
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