Search Results - "Nakamae, Kanako"
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Facially Dispersed Polyhydride Cu9 and Cu16 Clusters Comprising Apex‐Truncated Supertetrahedral and Square‐Face‐Capped Cuboctahedral Copper Frameworks
Published in Angewandte Chemie International Edition (03-02-2020)“…By using a linear tetraphosphine, meso‐bis[(diphenylphosphinomethyl)phenylphosphino]methane (dpmppm), nona‐ and hexadecanuclear copper hydride clusters,…”
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Multinuclear Copper Hydride Complexes Supported by Polyphosphine Ligands
Published in European journal of inorganic chemistry (23-06-2020)“…Copper hydride compounds have attracted interest in diverse fields as base metallic material in place of rare and noble metals, which have widely been utilized…”
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3
Octapalladium Strings Trap C60 and C70 Fullerenes Affording Metal‐Chain‐Wired Bucky Balls
Published in Chemistry : a European journal (09-09-2021)“…Reactions of Pd8 strings supported by meso‐Ph2PCH2P(Ph)CH2P(Ph)CH2PPh2 (meso‐dpmppm) ligands, [Pd8(meso‐dpmppm)4(L)2]4+ (L=CH3CN (1), XylNC (2)) with C60…”
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Tri- and Tetranuclear Copper Hydride Complexes Supported by Tetradentate Phosphine Ligands
Published in Inorganic chemistry (04-09-2018)“…Three types of tetradentate phosphine ligands with different central methylene chains and configurations, meso- and rac-Ph2PCH2P(Ph)(CH2) n P(Ph)CH2PPh2 (n…”
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Alloyed Tetranuclear Metal Chains of Pd4−nPtn (n=0–3) Scaffolded by a New Linear Tetraphosphine Containing a PNP Bridge
Published in Chemistry : a European journal (21-06-2019)“…A new linear tetraphosphine containing a PNP phosphazane bridge, rac‐bis[(diphenylphosphinomethyl)phenylphosphino]phenylamine (rac‐dpmppan), was synthesized…”
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Tetranuclear zigzag Ag4 and Ag2Pt2 complexes supported by rac-Ph2PCH2P(Ph)CH2P(Ph)CH2PPh2 (rac-dpmppm)
Published in Journal of organometallic chemistry (15-10-2020)“…•Tetraphosphine rac-dpmppm supports tetranuclear Ag4 and PtAg2Pt zigzag arrays.•The detailed tetranuclear structures were characterized by X-ray…”
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Fine Tunable, Redox Active Octapalladium Chains Supported by Linear Tetraphosphines, Leading to Dynamically 1D Self‐Assembled Coordination Polymers
Published in Chemistry : a European journal (19-08-2021)“…A series of the octapalladium chains supported by meso‐Ph2PCH2P(Ph)CH2P(Ph)CH2PPh2 (meso‐dpmppm) ligands, [Pd8(meso‐dpmppm)4(L)2](BF4)4 (L=none (1), solvents:…”
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Chiral Octapalladium Chains Supported by Enantiopure P-Stereogenic Linear Tetraphosphines, (R,R)- and (S,S)-Ph2PCH2P(Ph)CH2P(Ph)CH2PPh2
Published in Inorganic chemistry (01-03-2021)Get full text
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Self-Alignment of Low-Valent Octanuclear Palladium Atoms
Published in Angewandte Chemie International Edition (12-01-2015)“…A linear tetraphosphine, meso‐bis[(diphenylphosphinomethyl)phenylphosphino]methane (dpmppm) was used to synthesize linear octapalladium‐extended metal atom…”
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10
Chiral Dinuclear EuIII, TbIII, and YIII Complexes Supported by P‐Stereogenic Linear Tetraphosphine Tetraoxide
Published in Chemistry : a European journal (07-02-2022)“…A P‐stereogenic linear tetraphosphine tetraoxide, (R,R)‐ or (S,S)‐dpmppm(=O)4, was synthesized to prepare C2 dinuclear M(hfa)3 complexes (M=Eu, Tb, Y) as the…”
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11
Dinuclear Copper Complexes Triply Bridged by a Tetraphosphane, rac‐Ph2PCH2P(Ph)CH2P(Ph)CH2PPh2
Published in European journal of inorganic chemistry (09-10-2019)“…Reaction of [Cu(MeCN)4]BF4 with rac‐Ph2PCH2P(Ph)CH2P(Ph)CH2PPh2 (rac‐dpmppm) gave [Cu2(µ‐rac‐dpmppm)(MeCN)4](BF4)2 (1), and that of CuCl with rac‐dpmppm in the…”
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12
A decanuclear Pt complex comprised of an unbridged Pt4 chain capped by two Pt3 A-frame units supported by meso-Ph2PCH2P(Ph)CH2P(Ph)CH2PPh2
Published in Journal of organometallic chemistry (15-03-2019)“…A linear tetraphosphine meso-bis[(diphenylphosphinomethyl)phenylphosphino]methane (meso-dpmppm), was utilized to prepare a PtI dinuclear complex,…”
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13
Tetranuclear Rh4 chains supported by meso-Ph2PCH2P(Ph)CH2P(Ph)CH2PPh2 (meso-dpmppm) capturing H2 to afford Rh4H3 hydride complexes
Published in Journal of organometallic chemistry (01-05-2021)“…•Tetraphosphine meso-dpmppm supports bent tetranuclear Rh4 chains.•The Rh4 core reacted with H2 (1 atm) to afford Rh4H3 hydride complexes.•The linear Rh4H3…”
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14
Stepwise Expansion of Pd Chains from Binuclear Palladium(I) Complexes Supported by Tetraphosphine Ligands
Published in Inorganic chemistry (08-09-2015)“…Reaction of [Pd2(XylNC)6]X2 (X = PF6, BF4) with a linear tetraphosphine, meso-bis[(diphenylphosphinomethyl)phenylphosphino]methane (dpmppm), afforded…”
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Synthesis and structure of trihydride hexaplatinum complex supported by triphosphine ligands, [Pt6(μ-H)(H)2(μ-dpmp)4]BH4 (dpmp = bis(diphenylphosphino-methyl)phenylphosphine)
Published in Journal of organometallic chemistry (15-07-2016)“…From a reaction of [Pt3(μ-dpmp)2(XylNC)2](PF6)2 (1a) with NaBH4 and [Pt(dba)2] in N,N-dimethyl formamide (DMF), a trihydride hexaplatinum complex,…”
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Linear Triplatinum Tetrahydride Complex Supported by Triphosphine Ligands, [Pt3(µ‐H)2(H)2(µ‐dpmp)2](BF4)2 {dpmp = bis(diphenylphosphinomethyl)phenylphosphine}
Published in European journal of inorganic chemistry (17-03-2017)“…By treating [Pt6(µ‐H)(H)2(µ‐dpmp)4]BH4 [4, dpmp = bis(diphenylphosphinomethyl)phenylphosphine] with an excess amount of HBF4 in N,N‐dimethylformamide (DMF), a…”
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17
Gold and Silver Chains Supported by Linear Hexaphosphine Ligands
Published in Chemistry, an Asian journal (01-12-2015)“…A new linear hexaphosphine, rac‐cis,cis,trans‐ bis{[(diphenylphosphinomethyl)phenylphosphinomethyl]phenylphosphino}methane (P6), was synthesized and isolated…”
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Electron-Deficient Pt2M2Pt2 Hexanuclear Metal Strings (M = Pt, Pd) Supported by Triphosphine Ligands
Published in Organometallics (28-04-2014)“…Electron-deficient Pt2M2Pt2 hexanuclear clusters, [Pt4M2(μ-dpmp)4(XylNC)2](PF6)4 (M = Pt (7), Pd (8); dpmp = bis((diphenylphosphino)methyl)phenylphosphine),…”
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Linear Triplatinum Tetrahydride Complex Supported by Triphosphine Ligands, [Pt3(µ‐H)2(H)2(µ‐dpmp)2](BF4)2 {dpmp = bis(diphenylphosphinomethyl)phenylphosphine}
Published in European journal of inorganic chemistry (17-03-2017)“…Invited for the cover of this issue is the group of Tomoaki Tanase at Nara Women's University, Japan. The cover image shows the transformation of linear…”
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Chiral Self‐Recognition between Stereogenic Tetrapalladium Units Affording Pd8 Chains Supported by Homochiral Tetraphosphines
Published in Chemistry : a European journal (12-01-2017)“…By using a chiral tetraphosphine, rac‐bis[(diphenylphosphinomethyl)phenylphosphino]methane (rac‐dpmppm), linear octapalladium chains were synthesized as…”
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