Search Results - "Nakagawa, Naohisa"
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Iron-Catalyzed Diboration and Carboboration of Alkynes
Published in Chemistry : a European journal (09-03-2015)“…An iron‐catalyzed diboration reaction of alkynes with bis(pinacolato)diboron (B2pin2) and external borating agents (MeOB(OR)2) affords diverse symmetrical or…”
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Iron‐Catalyzed anti‐Selective Carbosilylation of Internal Alkynes
Published in Angewandte Chemie International Edition (16-10-2017)“…Reported is the anti‐selective carbosilylation of internal alkynes with silylborane and alkyl halides using a FeBr2/DPPE catalyst system. The iron catalyst…”
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Iron-Catalyzed Negishi Coupling Toward an Effective Olefin Synthesis
Published in Organic letters (15-10-2009)“…A selective iron-catalyzed cross-coupling of alkyl halides with alkenylzinc reagents is described. Primary and secondary alkyl chlorides, bromides, and iodides…”
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Investigation of Organoiron Catalysis in Kumada–Tamao–Corriu-Type Cross-Coupling Reaction Assisted by Solution-Phase X-ray Absorption Spectroscopy
Published in Bulletin of the Chemical Society of Japan (2015)“…Solution-phase synchrotron X-ray absorption spectroscopy (XAS) is a powerful tool for structural and mechanistic investigations of paramagnetic organoiron…”
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Reactivity of CA19-9 and CA125 in histological subtypes of epithelial ovarian tumors and ovarian endometriosis
Published in Acta medica Okayama (01-08-2015)“…Previous reports have shown that some ovarian endometrioid adenocarcinomas and ovarian clear cell adenocarcinomas derive from ovarian endometriosis (OE), and…”
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Iron‐Catalyzed anti‐Selective Carbosilylation of Internal Alkynes
Published in Angewandte Chemie (16-10-2017)“…Reported is the anti‐selective carbosilylation of internal alkynes with silylborane and alkyl halides using a FeBr2/DPPE catalyst system. The iron catalyst…”
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Iron-catalyzed Suzuki–Miyaura Coupling Reaction of Unactivated Alkyl Halides with Lithium Alkynylborates
Published in Chemistry letters (2015)“…A Suzuki–Miyaura coupling reaction between unactivated alkyl halides and lithium alkynylborates was performed using an iron–bisphosphine catalyst. The reaction…”
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Carbonylative and Hydrosilylative Carbocyclization of 1,5-Diynes for the Synthesis of Cyclic Dienones
Published in Organometallics (24-03-2008)“…A rhodium complex, [Rh(acac)(CO)2], has been identified to catalyze the cyclization of various 1,5-diynes with hydrosilanes under an atmospheric pressure of…”
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