Search Results - "Musso, Janis V."

Cationic Group VI Metal Imido Alkylidene N‐Heterocyclic Carbene Nitrile Complexes: Bench‐Stable, Functional‐Group‐Tolerant Olefin Metathesis Catalysts by Benedikter, Mathis J., Musso, Janis V., Frey, Wolfgang, Schowner, Roman, Buchmeiser, Michael R.

“…Despite their excellent selectivities and activities, Mo‐and W‐based catalysts for olefin metathesis have not gained the same widespread use as Ru‐based…”
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Molybdenum Alkylidyne Silyloxy N‐Heterocyclic Carbene Complexes – Highly Active Alkyne Metathesis Catalysts that can be Handled in Air by Musso, Janis V., Gramm, Vincent, Stein, Sarjano, Frey, Wolfgang, Buchmeiser, Michael R.

“…A series of molybdenum alkylidyne silyloxy N‐heterocyclic carbene (NHC) complexes of the general formula [Mo(≡C(R))(OSiPh3)3(NHC)] (R=tBu, 4‐methoxyphenyl,…”
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Cationic Group VI Metal Imido Alkylidene N‐Heterocyclic Carbene Nitrile Complexes: Bench‐Stable, Functional‐Group‐Tolerant Olefin Metathesis Catalysts by Benedikter, Mathis J., Musso, Janis V., Frey, Wolfgang, Schowner, Roman, Buchmeiser, Michael R.

“…Despite their excellent selectivities and activities, Mo‐and W‐based catalysts for olefin metathesis have not gained the same widespread use as Ru‐based…”
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Tungsten Oxo and Tungsten Imido Alkylidene N‑Heterocyclic Carbene Complexes for the Visible-Light-Induced Ring-Opening Metathesis Polymerization of Dicyclopentadiene by Musso, Janis V., Gebel, Paul, Gramm, Vincent, Frey, Wolfgang, Buchmeiser, Michael R.

“…A system for the visible-light-controlled ring-opening metathesis polymerization (ROMP) of endo,endo-dicyclopentadiene (DCPD) was developed by combining…”
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Cationic Tungsten Imido Alkylidene N‑Heterocyclic Carbene Complexes That Contain Bulky Ligands by Schowner, Roman, Musso, Janis V, Frey, Wolfgang, Buchmeiser, Michael R

“…Neutral and cationic tungsten imido alkylidene complexes of the general formulas W­(NtBu)­(CHR1)­(OR2)­Cl­(NHC),…”
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Neutral and Cationic Molybdenum Imido Alkylidene Cyclic Alkyl Amino Carbene (CAAC) Complexes for Olefin Metathesis by Kundu, Koushani, Musso, Janis V, Benedikter, Mathis J, Frey, Wolfgang, Gugeler, Katrin, Kästner, Johannes, Buchmeiser, Michael R

“…The first neutral and cationic Mo imido alkylidene cyclic alkyl amino carbene (CAAC) complexes of the general formulae [Mo(N-Ar)(CHCMe Ph)(X) (CAAC)] and…”
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Tuning the Latent Behavior of Molybdenum Imido Alkylidene N‑Heterocyclic Carbene Complexes in Dicyclopentadiene Polymerization by Momin, Mohasin, Musso, Janis V, Frey, Wolfgang, Buchmeiser, Michael R

“…We report the synthesis of O- and N-chelated hexacoordinated molybdenum imido alkylidene N-heterocyclic carbene (NHC) bistriflate and pentacoordinated…”
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Cationic Tungsten Oxo Alkylidene N‑Heterocyclic Carbene Complexes via Hydrolysis of Cationic Alkylidyne Progenitors by Hauser, Philipp M, Musso, Janis V, Frey, Wolfgang, Buchmeiser, Michael R

“…A route to cationic tungsten alkylidyne N-heterocyclic carbene (NHC) complexes of the general formula [W­(CR)­X2(NHC)­(tBuCN) y +B­(ArF)4 –] (R = tBu,…”
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Cationic molybdenum oxo alkylidenes stabilized by N-heterocyclic carbenes: from molecular systems to efficient supported metathesis catalysts by Musso, Janis V, De Jesus Silva, Jordan, Benedikter, Mathis J, Groos, Jonas, Frey, Wolfgang, Copéret, Christophe, Buchmeiser, Michael R

“…Cationic d 0 group 6 olefin metathesis catalysts have been recently shown to display in most instances superior activity in comparison to their neutral…”
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Predicting Catalytic Activity from 13CCH Alkylidene Chemical Shift in Cationic Tungsten Oxo Alkylidene N‐Heterocyclic Carbene Complexes by Musso, Janis V., Schowner, Roman, Falivene, Laura, Frey, Wolfgang, Cavallo, Luigi, Buchmeiser, Michael R.

“…A series of cationic tungsten oxo alkylidene N‐heterocyclic carbene (NHC) complexes was synthesized and structurally characterized by single crystal X‐ray…”
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Reaction Mechanism of Ring-Closing Metathesis with a Cationic Molybdenum Imido Alkylidene N‑Heterocyclic Carbene Catalyst by Kesharwani, Manoj K, Elser, Iris, Musso, Janis V, Buchmeiser, Michael R, Kästner, Johannes

“…DFT calculations were carried out to explore all relevant pathways for the ring-closing metathesis (RCM) reaction of a cationic molybdenum imido alkylidene…”
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Synthesis of Tungsten(VI) Imido Alkylidene Bispyrrolide Complexes via the Isocyanate Route by Musso, Janis V, Benedikter, Mathis J, Gebel, Paul, Elser, Iris, Frey, Wolfgang, Buchmeiser, Michael R

“…A general route to tungsten­(VI) imido alkylidene bispyrrolide complexes via the extrusion of CO2 from the reaction of one equivalent of an aryl isocyanate…”
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Reversible N‐Heterocyclic Carbene‐Induced α‐H Abstraction in Tungsten(VI) Imido Dialkyl Dialkoxide Complexes by Musso, Janis V., Benedikter, Mathis J., Wang, Dongren, Frey, Wolfgang, Altmann, Hagen J., Buchmeiser, Michael R.

“…The first reversible N‐heterocyclic carbene (NHC) induced α‐H ion in tungsten(VI) imido‐dialkyl dialkoxide complexes is reported. Treatment of…”
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Predicting Catalytic Activity from 13 C CH Alkylidene Chemical Shift in Cationic Tungsten Oxo Alkylidene N‐Heterocyclic Carbene Complexes by Musso, Janis V., Schowner, Roman, Falivene, Laura, Frey, Wolfgang, Cavallo, Luigi, Buchmeiser, Michael R.

“…Abstract A series of cationic tungsten oxo alkylidene N ‐heterocyclic carbene (NHC) complexes was synthesized and structurally characterized by single crystal…”
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