Search Results - "Musolino, Stefania F."
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Flexible polyfluorinated bis-diazirines as molecular adhesives
Published in Chemical science (Cambridge) (01-02-2021)“…Motivated by a desire to develop flexible covalent adhesives that afford some of the same malleability in the adhesive layer as traditional polymer-based…”
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Polyamine–Diazirine Conjugates for Use as Primers in UHMWPE–Epoxy Composite Materials
Published in ACS applied polymer materials (11-03-2022)“…Ultra-high-molecular weight polyethylene (UHMWPE) fibers show promise for use in fiber-reinforced polymer composites but have poor interfacial adhesion to the…”
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Design, Exploitation, and Rational Improvements of Diazirine-Based Universal Polymer Crosslinkers
Published in Accounts of chemical research (19-11-2024)“…Conspectus Addition of new covalent bonds between the chains of thermoplastic polymers (i.e., crosslinking) provides improved mechanical strength and enhanced…”
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Structure-function relationships in aryl diazirines reveal optimal design features to maximize C-H insertion
Published in Chemical science (Cambridge) (22-09-2021)“…Diazirine reagents allow for the ready generation of carbenes upon photochemical, thermal, or electrical stimulation. Because carbenes formed in this way can…”
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Crosslinking Vinyl‐Addition Polynorbornenes via Difunctional Diazirines to Generate Low Dielectric‐Constant and Low Dielectric‐Loss Thermosets
Published in Macromolecular rapid communications. (01-09-2024)“…Thermosets having low dielectric constant (Dk < 3) and low dielectric dissipation factor (Df < 0.003), high glass transition temperature (Tg > 150 °C), and…”
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Functionalization of Polydimethylsiloxane with Diazirine-Based Linkers for Covalent Protein Immobilization
Published in ACS applied materials & interfaces (10-01-2024)“…Biomolecule attachment to solid supports is critical for biomedical devices, such as biosensors and implants. Polydimethylsiloxane (PDMS) is commonly used for…”
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Arylboronic Acid-Catalyzed Racemization of Secondary and Tertiary Alcohols
Published in Journal of organic chemistry (07-10-2022)“…The use of 2-carboxyphenylboronic acid (5 mol %) and oxalic acid (10 mol %) with 2-butanone as a solvent for the racemization of a range of enantiomerically…”
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Direct Photopatterning of Colloidal Quantum Dots with Electronically Optimized Diazirine Cross-Linkers
Published in Journal of the American Chemical Society (23-10-2024)“…Colloidal quantum dots (QDs) with a wide color gamut and high luminescent efficiency are promising for next-generation electronic and photonic devices…”
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Isothiourea-Catalysed Acylative Kinetic Resolution of Aryl-Alkenyl (sp2 vs. sp2) Substituted Secondary Alcohols
Published in Chemistry : a European journal (23-12-2016)“…The non‐enzymatic acylative kinetic resolution of challenging aryl–alkenyl (sp2 vs. sp2) substituted secondary alcohols is described, with effective…”
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Synthesis of the natural product descurainolide and cyclic peptides from lignin-derived aromatics
Published in Organic & biomolecular chemistry (2018)“…Alternative sources of potential feedstock chemicals are of increasing importance as the availability of oil decreases. The biopolymer lignin is viewed as a…”
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Light-Induced Anti-Bacterial Effect Against Staphylococcus aureus of Porphyrin Covalently Bonded to a Polyethylene Terephthalate Surface
Published in ACS omega (23-08-2022)“…Antimicrobial photodynamic inactivation represents a promising and potentially greener alternative to conventional antimicrobials, and a solution for…”
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Crosslinking Vinyl‐Addition Polynorbornenes via Difunctional Diazirines to Generate Low Dielectric‐Constant and Low Dielectric‐Loss Thermosets
Published in Macromolecular rapid communications. (01-09-2024)“…Front Cover: 5G and 6G telecommunications devices operate at high frequencies, necessitating the use of photoactive polymer compositions with ultra‐low…”
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Antimicrobial photodynamic inactivation of planktonic and biofilm cells by covalently immobilized porphyrin on polyethylene terephthalate surface
Published in International biodeterioration & biodegradation (01-03-2023)“…The appearance of resistant strains and the persistence of biofilms on different surfaces in a wide range of settings represent serious public health threats…”
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Surface Modification and Dyeing of Ultrahigh-Molecular-Weight Polyethylene Fabrics Using Diazirine-Based Polymers
Published in ACS applied polymer materials (09-02-2024)“…Ultrahigh-molecular-weight polyethylene (UHMWPE) fibers are valued for their high strength-to-weight ratio and are employed in a wide variety of commercial…”
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Isothiourea-Catalysed Acylative Kinetic Resolution of Aryl-Alkenyl (sp super(2) vs. sp super(2)) Substituted Secondary Alcohols
Published in Chemistry : a European journal (01-12-2016)“…The non-enzymatic acylative kinetic resolution of challenging aryl-alkenyl (sp super(2) vs. sp super(2)) substituted secondary alcohols is described, with…”
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