Search Results - "Muniappan, Sankar"
-
1
Symmetrically Functionalized Copper and Silver Corrole‐Bis‐Tetracyanobutadiene Push‐Pull Conjugates: Efficient Population of Triplet States via Charge Transfer
Published in Chemistry : a European journal (20-07-2023)“…Copper and silver tritolylcorroles (TTC) are symmetrically functionalized to carry two tetracyanobutadiene (TCBD) entities via [2+2]…”
Get full text
Journal Article -
2
Effect of para ‐Substituents on meso ‐Functionalized Oxidovanadium(IV) Porphyrins as Catalysts for Oxygen Atom Transfer Mediated Oxidation of Benzoin to Benzil under Mild Conditions
Published in European journal of inorganic chemistry (24-10-2023)“…Systematic analysis of the effect of para ‐substituents (H, Cl, Br and OMe) on the meso ‐phenyl group in vanadyl meso ‐tetraphenylporphyrins ([V IV O(TPP)]…”
Get full text
Journal Article -
3
Facile Synthesis of β‐Brominated Manganese Porphyrins and their Catalytic Potentials for Haloperoxidases‐Like Activity
Published in European journal of inorganic chemistry (20-03-2024)“…A novel and sustainable approach has been developed for the synthesis of β‐brominated Mn porphyrins, [MnIII(Br)(TPPBr4)] (2), [MnIII(Br)(TPPBr6)] (3) and…”
Get full text
Journal Article -
4
N‐Confused Porphyrin – A Unique “Turn‐On” Chemosensor for CN− and F− ions and “Turn‐Off” Sensor for ClO4− ions
Published in Chemistry, an Asian journal (16-07-2020)“…N‐Confused meso‐tetrakis(4‐carbomethoxyphenyl)porphyrin (1) and its Ni(II) complex (1 a) have been synthesized and utilized for anion sensing studies, and the…”
Get full text
Journal Article -
5
Selective Bromination of β‐Positions of Porphyrin by Self‐Catalytic Behaviour of VOTPP: Facile Synthesis, Electrochemical Redox Properties and Catalytic Application
Published in European journal of inorganic chemistry (07-05-2021)“…Oxidovanadium(IV) complex of β‐octabromo‐meso‐tetraphenylporphyrin, {[VIVO(TPPBr8)], 2} was synthesized by self‐catalytic oxidative bromination of…”
Get full text
Journal Article -
6
Trans‐Dioxidomolybdenum(VI) Porphyrins and their Catalytic Activity Mimicking Oxidative Bromination
Published in European journal of inorganic chemistry (22-05-2024)“…Synthesis of trans‐dioxidomolybdenum(VI)‐meso‐tetraphenylporphyrin (trans‐[MoVIO2(TPP)], 1) and trans‐dioxidomolybdenum(VI)‐meso‐tetra(p‐chlorophenyl)porphyrin…”
Get full text
Journal Article -
7
Synthesis, Structural and Redox Properties of Vanadyl β‐Cyanoporphyrin and its Utilization as Efficient Catalyst for Epoxidation of Olefins and Oxidative Bromination of Phenols
Published in European journal of inorganic chemistry (20-03-2024)“…2‐Cyano‐5,10,15,20‐tetraphenylporphyrin [H2TPPCN] (1) having cyano group at one of β‐pyrrolic positions using nucleophilic substitution reaction of…”
Get full text
Journal Article -
8
Highly Efficient β‐Functionalized Oxidomolybdenum(V) Corroles for Catalytic Oxidative Bromination of Phenols at Room Temperature
Published in European journal of inorganic chemistry (01-12-2023)“…Two new β‐functionalized oxidomolybdenum(V) corroles, oxido[3‐formyl‐5,10,15‐triphenylcorrolato]molybdenum(V) (Mo‐1) and…”
Get full text
Journal Article -
9
Electrocatalytic Dinitrogen Reduction to Ammonia Using Easily Reducible N‐Fused Cobalt Porphyrins
Published in Chemistry : a European journal (17-10-2024)“…Single‐site molecular electrocatalysts, especially those that perform catalytic conversion of N2 to NH3 under mild conditions, are highly desirable to derive…”
Get full text
Journal Article -
10
Synthesis, Spectral, Electrochemical and Photovoltaic Studies of A3B Porphyrinic Dyes having Peripheral Donors
Published in Chemphyschem (16-10-2019)“…Three new ‘push‐pull’ A3B Zn(II)porphyrin dyes having meso‐pyrenyl, carbazolyl and phenothiazine as electron donors (A) and phenylcarboxylic acid as…”
Get full text
Journal Article -
11
Fused Nickel(II) Porphyrins—Sensing of Toxic Anions and Selected Metal Ions Through Supramolecular Interactions
Published in Frontiers in chemistry (17-11-2020)“…Ni(II) porphyrins having fused –NH group were synthesized and characterized by various spectroscopic techniques. The fused porphyrins 1 and 2 were used to…”
Get full text
Journal Article -
12
β‐Heptasubstituted Porphyrins: Synthesis, Structural, Spectral, and Electrochemical Properties
Published in European journal of inorganic chemistry (31-07-2018)“…A new series of β‐heptasubstituted porphyrins MTPP(NO2)(Me)6 (M = 2H, CoII, NiII, CuII, and ZnII) was synthesized and characterized by various spectroscopic…”
Get full text
Journal Article -
13
Persubstituted Triphenylamine Bearing Zinc Porphyrin to Host Endohedral Fullerene, Sc3N@C80: Formation and Excited State Electron Transfer
Published in The journal of physical chemistry. B (09-07-2020)“…A persubstituted porphyrin with eight entities of triphenylamines at the β-pyrrole positions of a zinc tetraphenylporphyrin, 1, was newly synthesized and…”
Get full text
Journal Article -
14
Electrochemical sensing of rifampicin in pharmaceutical samples using meso-tetrakis(4-hydroxyphenyl)porphyrinato cobalt(II) anchored carbon nanotubes
Published in Journal of applied electrochemistry (01-08-2018)“…In this work, an electrochemical sensing platform is prepared for rifampicin determination based on multiwalled carbon nanotubes (MWCNTs) modified with meso…”
Get full text
Journal Article -
15
Facile and Reversible Electrogeneration of Porphyrin Trianions and Tetraanions in Nonaqueous Media
Published in Inorganic chemistry (17-07-2017)“…The first examples for the facile, reversible, and stepwise electrogeneration of triply ring-reduced porphyrin macrocycles are presented. The investigated…”
Get full text
Journal Article -
16
Vanadyl β-tetrabromoporphyrin: synthesis, crystal structure and its use as an efficient and selective catalyst for olefin epoxidation in aqueous medium
Published in RSC advances (02-04-2019)“…We hereby report the synthesis, characterization and catalytic applications in the epoxidation of alkenes by a vanadyl porphyrin having bulky bromo…”
Get full text
Journal Article -
17
Porphyrin Framework Solids. Synthesis and Structure of Hybrid Coordination Polymers of Tetra(carboxyphenyl)porphyrins and Lanthanide-Bridging Ions
Published in Inorganic chemistry (09-07-2007)“…New types of porphyrin-based framework solids were constructed by reacting meso-tetra(3-carboxyphenyl)porphyrin and…”
Get full text
Journal Article -
18
Facile Synthesis and Electrochemical Studies of Diethoxyphosphorylphenyl-substituted Porphyrin and Its Metal Complexes
Published in Chemistry letters (05-07-2015)“…meso-Tetrakis(4′-diethoxyphosphorylphenyl)porphyrin (H2TPhPP) was synthesized via modified Lindsey method with higher yield (50%) as compared to reported…”
Get full text
Journal Article -
19
Electrochemistry of Tri‐substituted Porphyrins with β‐Appended Ethyl Acetoacetate and Acetylacetone in Neutral and Basic Nonaqueous Solvents
Published in ChemElectroChem (01-04-2020)“…The electrochemistry of β‐substituted tetraphenylporphyrins with a single ethyl acetoacetate (EAA), acetylacetone (acac), or ethyl acetate (EA) group and two…”
Get full text
Journal Article -
20
Facile Generation of A2B Corrole Radical Using Fe(III) Salts and Its Spectroscopic Properties
Published in ACS omega (31-03-2017)“…A carboxyphenyl-substituted corrole, 5,15-dimesityl-10-(4′-carboxyphenyl)corrole (1), has been synthesized and characterized by UV–vis, fluorescence, 1H NMR…”
Get full text
Journal Article