Search Results - "Muir, Kenneth W."
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Self-Assembly of Polymer and Sheet Structures in Palladium(II) Complexes Containing Carboxylic Acid Substituents
Published in Inorganic chemistry (07-10-2002)“…A series of complexes trans-[PdCl2L2] has been prepared by the reaction of [PdCl2(PhCN)2] and/or Na2[PdCl4] with L = pyridine or quinoline ligands having one…”
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The Remarkable Effect of Cosolvent on a Samarium(II)-Mediated 4-exo-trig Cyclization: Further Synthetic Studies on Pestalotiopsin A
Published in Journal of organic chemistry (18-04-2003)“…A samarium(II)-mediated 4-exo-trig cyclization in which a remote stereocenter serves to control the facial selectivity of the cyclization is described. The…”
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Di-Iron Aza Diphosphido Complexes: Mimics for the Active Site of Fe-Only Hydrogenase, and Effects of Changing the Coordinating Atoms of the Bridging Ligand in [Fe2{μ-(ECH2)2NR}(CO)6]
Published in Inorganic chemistry (27-12-2004)“…The bis(phosphido)-bridged complex [Fe2(μ-PPhH)2(CO)6] (1) undergoes double deprotonation to give the phosphorus-centered dianionic derivative…”
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Synthesis of sulfur containing dihydro-pyrrolo derivatives and their biological evaluation as antioxidants
Published in Bioorganic & medicinal chemistry (01-09-2012)“…The 1,3-dipolar cycloaddition to N-phenylmaleimide of azomethine ylides, generated in situ from sulfanyl-substituted imines of glycine esters, yields…”
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Chiral Schiff base complexes of copper (II), vanadium (IV) and nickel (II) as oxidation catalysts. X-ray crystal structures of [Cu (R-salpn) (OH 2)] and [Cu (±-busalcx)]
Published in Polyhedron (01-11-1998)“…Several new complexes of chiral and achiral tetradentate Schiff bases with copper (II), nickel (II) and oxovanadyl (IV) ions have been synthesised and…”
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Switching between Novel Samarium(II)-Mediated Cyclizations by a Simple Change in Alcohol Cosolvent
Published in Organic letters (11-12-2003)“…γ,δ-Unsaturated ketones undergo two very different stereoselective cyclization reactions mediated by samarium(II) iodide depending upon the alcohol cosolvent…”
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Reactions of Di- and Polynuclear Complexes. 14. Synthesis of Permethylated-Cyclopentadienyl Chalcogeno-Bridged Compounds: A Route to the Stable Thiolatosulfidocarbonyldimolybdenum(III) Complex [Cp2Mo2(CO)2(.mu.-SMe)2(.mu.-S)]. Crystal Structure Determination of [Cp2Mo2(CO)2(.mu.-SMe)2(.mu.-SH)][BF4]
Published in Organometallics (01-05-1995)“…The new diamagnetic carbonyl-containing sulfido complex [Cp*2Mo2(CO)2 (μ-SMe)2(μ-S)] (8) has been obtained by the thermal reaction of the…”
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A Bridging Side-on Allenylidene Dimolybdenum Complex without Carbonyl Stabilization
Published in Organometallics (23-10-2006)“…The bis(nitrile) complex [Mo2Cp2(μ-SMe)3(NCCH3)2](BF4) (1) reacts with HC⋮CCPh2(OH) to give the μ-alkyne product [Mo2Cp2(μ-SMe)3{HC⋮CCPh2(OH)}](BF4) (2)…”
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Formation of C−C, C−N, and C−O Links between Isonitrile, Cyclopentadienyl, and Hydroxide Ligands Bound to Molybdenum(III): Syntheses and Crystal Structures of μ-Aminocarbyne and μ-Amino-oxycarbene Dimolybdenum Complexes
Published in Organometallics (31-07-2006)“…Reaction of the bis-isonitrile complex [Mo2Cp2(μ-SMe)3(xylNC)2](BF4) (2b) with NaOH (suspension) under reflux in tetrahydrofuran produced, in quantitative…”
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The addition of oxygen to a Pt3Re cluster complex: a model for dissociative chemisorption of oxygen
Published in Journal of the American Chemical Society (01-08-1993)Get full text
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The first synthetic studies on pestalotiopsin A. A stereocontrolled approach to the functionalised bicyclic core
Published in Organic & biomolecular chemistry (21-01-2003)“…Pestalotiopsin A is a structurally unique, caryophyllene-type sesquiterpene which has shown immunosuppressive activity and cytotoxicity in preliminary assays…”
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Models for Bimetallic Catalysts: Anion Additions to Pt3Re Cluster Cations
Published in Organometallics (01-05-1995)Get full text
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Unexpected Coupling of Cp and Two RNC Ligands at a {Mo2(μ-SMe)3} Nucleus
Published in Organometallics (13-10-2003)“…Reaction of the bis-isonitrile complex [Mo2Cp2(μ-SMe)3(t-BuNC)2](BF4) (1) with n-BuLi (in hexane) produced the dealkylated derivative…”
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Hydrated forms of N-[(3R)-3-(4-methyl-3,5-dioxo-1,2,4-triazolidin-1-yl)-2-methylenebutanoyl]-(1S,2R)-bornane-10,2-sultam and its enantiomer
Published in Acta crystallographica. Section C, Crystal structure communications (01-08-2006)“…Triazolidinediones react with each enantiomeric bornanesultam derivative of tiglic acid to produce the appropriate ene adduct in high yield and with excellent…”
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A Model for a Lipid Membrane Stabilized by C−H···X Bonds: The Crystal Structure of the Paraffinic Ylide Trimethylammonio n-Hexadecylsulfonamidate CH3(CH2)15SO2N(−)N(+)Me3
Published in Crystal growth & design (05-01-2005)“…The crystal structure of trimethylammonio n-hexadecylsulfonamidate contains antiparallel monolayers stabilized by strong C−H···O bonds (C···O 3.22 Å). There…”
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Dinuclear molybdenum thiolato-bridged compounds: syntheses, reactivities and electrochemical studies of site–substrate interactions
Published in Coordination chemistry reviews (01-12-1998)“…The synthesis, reactivity, structures and electrochemistry of dimolybdenum complexes jointly stabilized by cyclopentadienyl and bridging thiolate ligands are…”
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Electrochemical Cleavage of NN Bonds at a Mo2(μ-SMe)3 Site Relevant to the Biological Reduction of Dinitrogen at a Bimetallic Sulfur Centre
Published in Chemistry : a European journal (15-07-2002)“…The reduction of diazene complexes [Mo2Cp2(μ‐SMe)3(μ‐η2‐HNNR)]+ (R=Ph (3 a); Me (3 b)) and of the hydrazido(2−) derivative [Mo2Cp2(μ‐SMe)3{μ‐η1‐NN(Me)H}]+…”
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Transformations and Agostic Interactions of Hydrocarbyl Ligands Bonded to the Sulfur-Rich Dimolybdenum Site {Mo2Cp2(μ-SMe)3}: Chemical and Electrochemical Formation of μ-Alkyl and μ-Vinyl Compounds from a μ-Alkylidene Derivative
Published in Organometallics (05-12-2005)“…A series of chemical and electrochemical transformations of systems in which a {Mo2Cp2(μ-SMe)3} core is bridged by a μ-C2H n R ligand (n = 0−4) are described…”
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