Search Results - "Mougharbel, Ali S."
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Polyoxometalates in Biomedicine: Update and Overview
Published in Current medicinal chemistry (01-01-2020)“…Polyoxometalates (POMs) are negatively charged metal-oxo clusters of early transition metal ions in high oxidation states (e.g., WVI, MoVI, VV). POMs are of…”
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High-Affinity Binding of Metallacarborane Cobalt Bis(dicarbollide) Anions to Cyclodextrins and Application to Membrane Translocation
Published in Journal of organic chemistry (20-09-2019)“…Metallacarboranes are a class of inorganic boron clusters that have recently been recognized as biologically active compounds. Herein, we report on the…”
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3
Peroxo-Cerium(IV)-Containing Polyoxometalates: [CeIV 6(O2)9(GeW10O37)3]24–, a Recyclable Homogeneous Oxidation Catalyst
Published in Inorganic chemistry (03-09-2019)“…The class of peroxo-cerium-containing polyoxometalates has been discovered via the synthesis of the 9-peroxo-6-cerium(IV)-containing 30-tungsto-3-germanate,…”
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Organorhodium(III)- and Iridium(III)-Substituted 20-Tungstobismuthates(III) and -Antimonates(III), [(MCp)2X2W20O70]10– (M = RhIII and IrIII; X = BiIII and SbIII)
Published in ACS omega (21-12-2021)“…The synthesis of four organometallic RhCp*- and IrCp*-containing heteropoly-20-tungstates, [{RhCp*}2Bi2W20O70]10– (1), [{IrCp*}2Bi2W20O70]10– (2),…”
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Preyssler‐Pope‐Jeannin Polyanions [NaP5W30O110]14– and [AgP5W30O110]14–: Microwave‐Assisted Synthesis, Structure, and Biological Activity
Published in Zeitschrift für anorganische und allgemeine Chemie (1950) (02-08-2018)“…The Preyssler‐Pope‐Jeannin polyanion [NaP5W30O110]14– (1) was prepared by microwave‐assisted synthesis in only 2 h with a yield comparable to the reported…”
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Uniform trend in layer-by-layer deposition of heteropolytungstates
Published in Journal of colloid and interface science (01-01-2019)“…[Display omitted] The layer-by-layer deposition of films including polyoxometalates (POMs) results in a very interesting range of applications in various…”
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Palladium(II)-Containing Tungstoarsenate(V), [PdII 4(As2W15O56)2]16–, and Its Catalytic Properties
Published in Inorganic chemistry (21-09-2020)“…We have synthesized and structurally characterized the 4-palladium(II)-containing 30-tungsto-4-arsenate(V), [Pd4(As2W15O56)2]16– (1), which represents the…”
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Anti-zika virus activity of polyoxometalates
Published in Antiviral research (01-03-2019)“…Zika virus (ZIKV) is an emerging infectious viral pathogen associated with severe fetal cerebral anomalies and the paralytic Guillain-Barrè syndrome in adults…”
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Discovery of a Neutral 40-Pd II -Oxo Molecular Disk, [Pd 40 O 24 (OH) 16 {(CH 3 ) 2 AsO 2 } 16 ]: Synthesis, Structural Characterization, and Catalytic Studies
Published in Inorganic chemistry (15-11-2021)“…We report on the synthesis and structural characterization of the giant discrete and neutral molecular disk, [Pd40O24(OH)16{(CH3)2AsO2}16] (Pd40), comprising a…”
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Discovery of Polythioplatinate(II) [Pt3S2(SO3)6]10– and Study of Its Solution and Catalytic Properties
Published in Inorganic chemistry (01-08-2022)“…We have discovered the first polythioplatinate(II), [PtII 3S2(SO3)6]10– (1), which was synthesized in aqueous basic medium (pH 11) by hydrothermal heating at…”
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Lanthanide-Containing 22-Tungsto-2-germanates [Ln(GeW11O39)2]13–: Synthesis, Structure, and Magnetic Properties
Published in Inorganic chemistry (06-04-2020)“…We report on the synthesis and structural characterization of two series of lanthanide-containing 22-tungsto-2-germanates. The first series corresponds to a…”
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Tetra‑(p‑tolyl)antimony(III)-Containing Heteropolytungstates, [{(p‑tolyl)SbIII}4(A‑α-XW9O34)2] n− (X = P, As, or Ge): Synthesis, Structure, and Study of Antibacterial and Antitumor Activity
Published in Inorganic chemistry (02-03-2020)“…We have synthesized and structurally characterized three tetra-(p-tolyl)antimony(III)-containing heteropolytungstates, [{(p-tolyl)SbIII}4(A-α-XW9O34)2] n−…”
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In Operando X‑ray Studies of High-Performance Lithium-Ion Storage in Keplerate-Type Polyoxometalate Anodes
Published in ACS applied materials & interfaces (09-09-2020)“…Polyoxometalates (POMs) have emerged as potential anode materials for lithium-ion batteries (LIBs) owing to their ability to transfer multiple electrons…”
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Bismuth(III)‐Containing Heteropolytungstates [Bi(XW11O39)2]n– (X = Si, Ge, n = 13; X = P, n = 11) and [Bi(P2W17O61)2]17
Published in European journal of inorganic chemistry (31-01-2019)“…We report on the synthesis and structural characterization of four bismuth(III)‐containing sandwich‐type heteropolytungstates with Bi in 8‐coordination. The…”
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Polyoxometalate‐graphene Electrocatalysts for the Hydrogen Evolution Reaction
Published in ChemElectroChem (01-01-2018)“…Electrocatalytic reduction of water, also known as the hydrogen evolution reaction (HER), may be one of the solutions for a sustainable energy supply in the…”
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Toxicity evaluation of two polyoxotungstates with anti-acetylcholinesterase activity
Published in Toxicology and applied pharmacology (15-10-2017)“…A toxicity evaluation of two Keggin-type heteropolytungstates, K7[Ti2PW10O40]·6H2O and K6H[SiV3W9O40]·3H2O, with different inhibitory potencies toward…”
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Reinvestigation of Dilacunary 19‐Tungsto‐2‐arsenate(III) [AsIII2W19O67(H2O)]14– Including 183W NMR Study in Solution
Published in European journal of inorganic chemistry (02-10-2017)“…We have reinvestigated the dilacunary 19‐tungsto‐2‐arsenate(III) [AsIII2W19O67(H2O)]14– (1), resulting in the mixed potassium–sodium salt…”
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In vivo toxicity evaluation of two polyoxotungstates with potential antidiabetic activity using Wistar rats as a model system
Published in RSC advances (15-01-2020)“…In this study, the hypoglycemic effect of a donut-shaped polyanion salt (NH ) [Na@P W O ]·31H O {NaP W } and its Ag-containing derivative K [Ag@P W O ]·22H…”
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Dithallium(III)-Containing 30-Tungsto-4-phosphate, [Tl2Na2(H2O)2(P2W15O56)2]16–: Synthesis, Structural Characterization, and Biological Studies
Published in Inorganic chemistry (18-06-2018)“…Here we report on the synthesis and structural characterization of the dithallium(III)-containing 30-tungsto-4-phosphate [Tl2Na2(H2O)2{P2W15O56}2]16– (1) by…”
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Fast Microwave-Assisted Synthesis of Wells-Dawson-Type 18-Tungsto-2-Phosphate [P2W18O62]6
Published in Inorganics (15-02-2019)“…We report on a fast microwave-assisted synthetic procedure of the Wells-Dawson-type 18-tungsto-2-phosphate [P2W18O62]6− with a 35% yield in 24 h, rather than a…”
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