Search Results - "Motokura, Ken"
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Development of Multiactive Site Catalysts for Surface Concerted Catalysis Aimed at One-Pot Synthesis
Published in Bulletin of the Chemical Society of Japan (2017)“…Multiactive site catalysts have been developed for conducting one-pot synthesis and highly efficient reactions based on the principle of concerted catalysis…”
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2
Mg–Al hydrotalcite-based catalysts for one-pot synthesis of quinoline derivatives
Published in Tetrahedron Green Chem (2023)“…This mini-review discusses Mg–Al hydrotalcite-based catalyst systems used for modified Friedländer quinoline synthesis. The metal-grafted Mg–Al hydrotalcites…”
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3
Organic bases catalyze the synthesis of urea from ammonium salts derived from recovered environmental ammonia
Published in Scientific reports (18-02-2020)“…Ammonia from sewage and livestock manure is a major environmental pollutant. To consume environmental ammonia, we investigated the organic base-catalyzed…”
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Montmorillonite-based heterogeneous catalysts for efficient organic reactions
Published in Nano express (01-03-2022)“…Abstract In this review, we give a brief overview of recently developed montmorillonite-based heterogeneous catalysts used for efficient organic reactions…”
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Heterogeneous Supported Palladium Catalysts for Liquid‐Phase Allylation of Nucleophiles
Published in ChemPlusChem (Weinheim, Germany) (01-11-2020)“…In recent years, palladium‐catalyzed allylation has become the focus of much research. However, conventional homogeneous Pd catalysts face problems regarding…”
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6
Silica-supported Alkylammonium Formate Catalyst for Hydrosilylation of Carbon Dioxide
Published in Chemistry letters (05-11-2019)“…An amorphous silica-supported alkylammonium formate catalyst for the reductive transformation of carbon dioxide using silane as a reductant was developed…”
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Rhodium–Iodide Complex on a Catalytically Active SiO2 Surface for One‐Pot Hydrosilylation–CO2 Cycloaddition
Published in Chemistry : a European journal (24-01-2022)“…In this study, a novel Rh–iodide complex was synthesized through a surface reaction between an immobilized Rh cyclooctadiene complex and alkylammonium iodide…”
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Direct Alkylation of Benzene at Lower Temperatures in the Liquid Phase: Catalysis by Montmorillonites as Noble‐Metal‐Free Solid Acids
Published in ChemPlusChem (Weinheim, Germany) (01-03-2020)“…Alkylated benzenes are widely used as raw materials for the production of a variety of chemical compounds. Conventionally, they are obtained by the…”
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Heterogeneous Synergistic Catalysis by a Palladium Complex and an Amine on a Silica Surface for Acceleration of the Tsuji-Trost Reaction
Published in Angewandte Chemie International Edition (06-08-2012)“…The cooperative surface‐catalysis strategy of a Brønsted acid and an organic base can be extended to a metal complex and organic base pair. A silica‐supported…”
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Formate-Catalyzed Selective Reduction of Carbon Dioxide to Formate Products Using Hydrosilanes
Published in ACS sustainable chemistry & engineering (01-07-2019)“…Formate salts were found to be active and selective homogeneous catalysts for the hydrosilylation of CO2. Counter cations and solvents strongly affected their…”
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Heterogeneous Organic Base-Catalyzed Reactions Enhanced by Acid Supports
Published in Journal of the American Chemical Society (08-08-2007)“…Amorphous silica-alumina-supported amines (SA-NR2) were found to be excellent heterogeneous catalysts for a variety of carbon−carbon bond-forming reactions,…”
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SiO2‑Supported Rh Catalyst for Efficient Hydrosilylation of Olefins Improved by Simultaneously Immobilized Tertiary Amines
Published in ACS catalysis (07-07-2017)“…The simultaneous immobilization of a Rh complex and a tertiary amine on a SiO2 surface afforded a highly active supported catalyst for the hydrosilylation of…”
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13
Organic group decorated heterogeneous Pd complex on mesoporous silica toward catalytic allylation in aqueous media
Published in Catalysis today (01-03-2023)“…The use of water as a reaction solvent is ideal for green chemistry. However, carrying out catalytic reactions with transition metal catalysts in aqueous media…”
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Porous FeO(OH) Dispersed on Mg‐Al Hydrotalcite Surface for One‐Pot Synthesis of Quinoline Derivatives
Published in ChemCatChem (18-06-2021)“…The use of ubiquities elements such as iron instead of expensive precious metals as catalysts is one goal toward realizing environmentally benign synthetic…”
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Multifunctional Solid Surfaces for Enhanced Catalysis
Published in ChemCatChem (01-11-2014)“…Consider it solid! Multifunctional solid surfaces enhance heterogeneous catalysis by promoting efficient reaction sequences, fine‐tuning of hydrophilic and…”
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Catalytic Conversion of Biomass-Derived Carbohydrates to Methyl Lactate by Acid–Base Bifunctional γ‑Al2O3
Published in ACS sustainable chemistry & engineering (02-07-2018)“…We report the catalytic conversion of biomass-derived carbohydrates to methyl lactate using metal oxides. The combination of Lewis acid–base sites on γ-Al2O3…”
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Multifunctional Catalytic Surface Design for Concerted Acceleration of One-Pot Hydrosilylation–CO2 Cycloaddition
Published in Organic letters (06-12-2019)“…Silica-supported Rh-ammonium iodide catalyst showed high performance for hydrosilylation–CO2 cycloaddition reaction sequences. The catalyst was prepared by…”
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Cooperative Catalysis of Primary and Tertiary Amines Immobilized on Oxide Surfaces for One-Pot C----C Bond Forming Reactions
Published in Angewandte Chemie (International ed.) (01-01-2008)“…D'you know what amine? Primary and tertiary amines are both immobilized on the same silica–alumina surface by silane‐coupling reactions. The resultant…”
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Accumulation of Active Species in Silica Mesopore: Effect of the Pore Size and Free Base Additives on Pd‐catalyzed Allylation using Allylic Alcohol
Published in ChemCatChem (20-05-2020)“…A mesoporous silica‐supported Pd complex was prepared using various types of porous silica supports (pore size: 16–31 Å). The effects of the pore size and base…”
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Influence of a Co-immobilized Tertiary Amine on the Structure and Reactivity of a Rh Complex: Accelerating Effect on Heterogeneous Hydrosilylation
Published in Journal of physical chemistry. C (13-06-2019)“…Co-immobilization of a Rh complex and a tertiary amine on the same silica surface enhances the hydrosilylation reaction of olefins. In our previous study, the…”
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