Search Results - "Mostafa Taoufik"
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Polyolefins, a Success Story
Published in Polymers (24-05-2017)“…This paper reports the principal discoveries which have played a major role in the polyolefin field and have positioned polyolefins as the most produced…”
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High‐Field NMR, Reactivity, and DFT Modeling Reveal the γ‐Al2O3 Surface Hydroxyl Network
Published in Angewandte Chemie International Edition (12-09-2022)“…Aluminas are strategic materials used in many major industrial processes, either as catalyst supports or as catalysts in their own right. The transition…”
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Direct conversion of trans-2-butene into a mixture of monomers with different composition over vanadium supported catalysts
Published in Catalysis communications (01-09-2022)“…Terpolymerization of 1,3-butadiene, ethylene and propylene became an important process to access EPDM rubbers materials with unique properties. Having a…”
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Highly Active Immobilized Catalyst for Ethylene Polymerization: Neutral Single Site Y(III) Complex Bearing Bulky Silylallyl Ligand
Published in Chemistry : a European journal (17-10-2024)“…Exploring the surface organometallic chemistry on silica of highly electrophilic yttrium complexes is a relatively uncommon endeavor, particularly when…”
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Metathesis of Alkanes and Related Reactions
Published in Accounts of chemical research (16-02-2010)“…The transformation of alkanes remains a difficult challenge because of the relative inertness of the C−H and C−C bonds. The rewards for asserting synthetic…”
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“Hydro-metathesis” of Olefins: A Catalytic Reaction Using a Bifunctional Single-Site Tantalum Hydride Catalyst Supported on Fibrous Silica (KCC-1) Nanospheres
Published in Angewandte Chemie (International ed.) (14-03-2011)“…Tantalizing hydrocarbons: Tantalum hydride supported on fibrous silica nanospheres (KCC‐1) catalyzes, in the presence of hydrogen, the direct conversion of…”
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Pd, Cu and Bimetallic PdCu NPs Supported on CNTs and Phosphine‐Functionalized Silica: One‐Pot Preparation, Characterization and Testing in the Semi‐Hydrogenation of Alkynes
Published in European journal of inorganic chemistry (21-12-2021)“…Triphenylphosphine stabilized Pd, Cu and PdCu nanocatalysts supported on carbon nanotubes (CNTs) or phosphorus functionalised silica (P−SiO2) were prepared via…”
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Ethenolysis of Renewable Methyl Oleate Catalyzed by Readily Accessible Supported Group VI Oxo Catalysts
Published in Organometallics (13-04-2020)“…The conversion of methyl oleate by cross-metathesis with ethylene using readily accessible supported group VI oxo species was addressed. TON up to 500 and 5000…”
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Non-Oxidative Coupling Reaction of Methane to Ethane and Hydrogen Catalyzed by the Silica-Supported Tantalum Hydride: (SiO)2Ta−H
Published in Journal of the American Chemical Society (16-04-2008)“…Silica-supported tantalum hydride, (SiO)2Ta−H (1), proves to be the first single-site catalyst for the direct non-oxidative coupling transformation of methane…”
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High‐Field NMR, Reactivity, and DFT Modeling Reveal the γ‐Al2O3 Surface Hydroxyl Network
Published in Angewandte Chemie (12-09-2022)“…Aluminas are strategic materials used in many major industrial processes, either as catalyst supports or as catalysts in their own right. The transition…”
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Ammonia and Dinitrogen Activation by Surface Organometallic Chemistry on Silica-Grafted Tantalum Hydrides
Published in European Journal of Inorganic Chemistry (01-03-2011)“…Ammonia N–H bond activation and dinitrogen N≡N cleavage with dihydrogen on an isolated metal atom have been achieved with the silica‐grafted TaIII and TaV…”
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Book Review Journal Article -
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NH3-Selective Catalytic Reduction of NOx to N2 over Ceria Supported WOx Based Catalysts: Influence of Tungsten Content
Published in Catalysts (01-08-2021)“…A series of HPW/CeO2 catalysts generated from 12-tungstophosphoric acid, H3PW12O40 (HPW), supported on ceria and presenting different tungsten loadings (2,…”
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Enforcing Z-selectivity in olefin metathesis through use of catalysts grafted on well-defined phenolic hybrid material
Published in Catalysis today (15-10-2014)“…[Display omitted] •New olefin metathesis catalysts were prepared by replacing surface silanol by phenol.•SOMC of a W-perhydrocarbyl on supported phenol.•SOMC…”
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Journal Article Conference Proceeding -
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Molecular Understanding of Alumina Supported Single-Site Catalysts by a Combination of Experiment and Theory
Published in Journal of the American Chemical Society (19-07-2006)“…The nature and structure of grafted organometallic complexes on γ-alumina are studied from a combination of experimental data (mass balance analysis, IR, NMR)…”
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Primary Products and Mechanistic Considerations in Alkane Metathesis
Published in Journal of the American Chemical Society (22-06-2005)“…Alkane metathesis, a reaction catalyzed by the silica-supported tantalum hydride [(⋮SiO)2Ta−H], 1, which transforms acyclic alkanes into their higher and lower…”
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Grafting Reaction of Platinum Organometallic Complexes on Silica-Supported or Unsupported Heteropolyacids
Published in Organometallics (11-04-2011)“…Silica-supported Keggin-type heteropolyacids react with platinum(II) complexes displaying a Pt-CH3 group, leading to the evolution of methane and the formation…”
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Shifting From Ziegler-Natta to Philips-Type Catalyst? A Simple and Safe Access to Reduced Titanium Systems for Ethylene Polymerization
Published in Macromolecular rapid communications. (01-12-2011)“…Silica‐supported titanium(IV) chloride is readily reduced by Mashima and co‐workers' reagent (1‐methyl‐3,6‐bis(trimethylsilyl)‐1,4‐cyclohexadiene) to afford…”
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Titanacalixarenes in Homogeneous Catalysis: Synthesis, Conformation and Catalytic Activity in Ethylene Polymerisation
Published in European Journal of Inorganic Chemistry (01-03-2010)“…Variously substituted titanacalixarenes were synthesised and tested for their performance as catalysts in ethylene polymerisation: p‐tert‐butylcalix[4]arene…”
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Book Review Journal Article -
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Development of Tungsten-Based Heterogeneous Alkane Metathesis Catalysts Through a Structure-Activity Relationship
Published in Angewandte Chemie International Edition (21-10-2005)Get full text
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