Search Results - "Moshammer, Kai"
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Experimental and kinetic modeling study of the low- and intermediate-temperature oxidation of dimethyl ether
Published in Combustion and flame (01-04-2015)“…Recent experiments on low-temperature oxidation of dimethyl ether (DME) at atmospheric pressure reveal much lower fuel conversion than the predictions of all…”
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Unraveling the structure and chemical mechanisms of highly oxygenated intermediates in oxidation of organic compounds
Published in Proceedings of the National Academy of Sciences - PNAS (12-12-2017)“…Decades of research on the autooxidation of organic compounds have provided fundamental and practical insights into these processes; however, the structure of…”
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Selective suspension in aqueous sodium dodecyl sulfate according to electronic structure type allows simple separation of metallic from semiconducting single-walled carbon nanotubes
Published in Nano research (01-08-2009)“…Both density gradient centrifugation and gel electrophoresis have been reported to allow high throughput separation of metallic from semiconducting…”
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Quantification of the Keto-Hydroperoxide (HOOCH2OCHO) and Other Elusive Intermediates during Low-Temperature Oxidation of Dimethyl Ether
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (13-10-2016)“…This work provides new temperature-dependent mole fractions of elusive intermediates relevant to the low-temperature oxidation of dimethyl ether (DME). It…”
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A Comprehensive Analysis of the Risks Associated with the Determination of Biofuels’ Calorific Value by Bomb Calorimetry
Published in Energies (Basel) (01-04-2022)“…Two of the most commonly used solid biomass sources for fuel are wood chips and wood pellets. The calorific value and the moisture content of those biofuels…”
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An experimental and kinetic modeling study on dimethyl carbonate (DMC) pyrolysis and combustion
Published in Combustion and flame (01-02-2016)“…Dimethyl carbonate (DMC) is a promising oxygenated additive or substitute for hydrocarbon fuels, because of the absence of C–C bonds and the large oxygen…”
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Detection and Identification of the Keto-Hydroperoxide (HOOCH2OCHO) and Other Intermediates during Low-Temperature Oxidation of Dimethyl Ether
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (16-07-2015)“…In this paper we report the detection and identification of the keto-hydroperoxide (hydroperoxymethyl formate, HPMF, HOOCH2OCHO) and other partially oxidized…”
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A further experimental and modeling study of acetaldehyde combustion kinetics
Published in Combustion and flame (01-10-2018)“…Acetaldehyde is an important intermediate and a toxic emission in the combustion of fuels, especially for biofuels. To better understand its combustion…”
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Additional chain-branching pathways in the low-temperature oxidation of branched alkanes
Published in Combustion and flame (01-02-2016)“…Chain-branching reactions represent a general motif in chemistry, encountered in atmospheric chemistry, combustion, polymerization, and photochemistry; the…”
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Parametrical investigation for the optimization of spherical jet-stirred reactors design using large eddy simulations
Published in SN applied sciences (01-09-2021)“…Due to the importance of gas-phase chemical reaction kinetics in low-emission combustion, stirred tank reactors have been used for decades as an experimental…”
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Improved Metrological Methodology to Address the Challenges Associated with the Determination of Biofuels Calorific Value by Bomb Calorimeter
Published in Chemical engineering transactions (01-06-2022)“…The challenges associated with biofuel quality come from its heterogenous nature as biomass crops grow in different lands and under different conditions…”
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Review of the Influence of Oxygenated Additives on the Combustion Chemistry of Hydrocarbons
Published in Energy & fuels (02-09-2021)“…This review summarizes the chemical impact of oxygenated additives on the combustion chemistry of hydrocarbons. Experimental studies in shock tubes, rapid…”
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Exploring the Effect of Different Reactivity Promoters on the Oxidation of Ammonia in a Jet-Stirred Reactor
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (02-03-2023)“…The low reactivity of ammonia (NH3) is the main barrier to applying neat NH3 as fuel in technical applications, such as internal combustion engines and gas…”
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Experimental and kinetic modeling study of the autoignition and oxidation of ammonia/ethane mixtures in a rapid compression machine and a jet-stirred reactor
Published in Combustion and flame (01-10-2023)“…Ignition delay times and speciation data of ammonia/ethane (NH3/C2H6) fuel blends were measured in a rapid compression machine (RCM) and in a jet-stirred…”
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A detailed uncertainty analysis of EI-MBMS data from combustion experiments
Published in Combustion and flame (01-09-2022)“…Electron ionization molecular-beam mass spectrometry (EI-MBMS) is a widely used analytical method for studying the chemistry of combustion processes and for…”
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Experimental and kinetic modeling study on auto-ignition properties of ammonia/ethanol blends at intermediate temperatures and high pressures
Published in Proceedings of the Combustion Institute (2023)“…The auto-ignition properties of ammonia (NH3)/ethanol (C2H5OH) blends close to engine operating conditions were investigated for the first time. Specifically,…”
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Investigating repetitive reaction pathways for the formation of polycyclic aromatic hydrocarbons in combustion processes
Published in Combustion and flame (01-06-2017)“…Repetitive hydrogen-abstraction and methyl- and acetylene-addition reaction sequences that contribute to the formation and growth of polycyclic aromatic…”
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Comprehensive kinetic modeling and experimental study of a fuel-rich, premixed n-heptane flame
Published in Combustion and flame (01-05-2015)“…An existing comprehensive kinetic hydrocarbon oxidation model has been augmented and revised for a detailed analysis of n-heptane flame chemistry. The analysis…”
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NH3/C2H6 and NH3/C2H5OH oxidation in a shock tube: Multi-speciation measurement, uncertainty analysis, and kinetic modeling
Published in Chemical engineering journal (Lausanne, Switzerland : 1996) (15-10-2024)“…•Measure NH3, NO, and CO profiles in NH3/C2H6 and NH3/C2H5OH oxidation in shock tube.•Analyze mole fraction uncertainty and propose dynamic uncertainty for…”
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The influence of dimethoxy methane (DMM)/dimethyl carbonate (DMC) addition on a premixed ethane/oxygen/argon flame
Published in Proceedings of the Combustion Institute (01-01-2017)“…Two series of laminar premixed flames fueled by ethane-oxygenate-argon mixtures, in which ethane was incrementally replaced with either dimethoxy methane (DMM)…”
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