Search Results - "Moroz, Ilia B."
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Bridging the Gap between Industrial and Well‐Defined Supported Catalysts
Published in Angewandte Chemie International Edition (28-05-2018)“…Many industrial catalysts contain isolated metal sites on the surface of oxide supports. Although such catalysts have been used in a broad range of processes…”
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Dynamic Nuclear Polarization Solid-State NMR Spectroscopy for Materials Research
Published in Annual review of materials research (01-01-2022)“…Solid-state nuclear magnetic resonance (NMR) spectroscopy has increasingly been used for materials characterization as it enables selective detection of…”
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Endogenous metal-ion dynamic nuclear polarization for NMR signal enhancement in metal organic frameworks
Published in Chemical science (Cambridge) (20-12-2023)“…Rational design of metal-organic framework (MOF)-based materials for catalysis, gas capture and storage, requires deep understanding of the host-guest…”
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BDPA-Nitroxide Biradicals Tailored for Efficient Dynamic Nuclear Polarization Enhanced Solid-State NMR at Magnetic Fields up to 21.1 T
Published in Journal of the American Chemical Society (17-10-2018)“…Dynamic nuclear polarization (DNP) solid-state nuclear magnetic resonance (NMR) has developed into an invaluable tool for the investigation of a wide range of…”
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Composition and Structure of the solid electrolyte interphase on Na-Ion Anodes Revealed by Exo- and Endogenous Dynamic Nuclear PolarizationNMR Spectroscopy
Published in Journal of the American Chemical Society (04-09-2024)“…Sodium ion batteries (SIB) are among the most promising devices for large scale energy storage. Their stable and long-term performance depends on the formation…”
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Specific Localization of Aluminum Sites Favors Ethene-to-Propene Conversion on (Al)MCM-41-Supported Ni(II) Single Sites
Published in ACS catalysis (02-08-2019)“…Single-site Ni(II) catalytic centers supported on MCM-41-type materials were prepared via surface organometallic chemistry using tailored thermolytic…”
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Silica‐Grafted Tris(neopentyl)aluminum: A Monomeric Aluminum Solid Co‐catalyst for Efficient Nickel‐Catalyzed Ethene Dimerization
Published in Angewandte Chemie International Edition (07-09-2020)“…A silica‐supported monomeric alkylaluminum co‐catalyst was prepared via surface organometallic chemistry by contacting tris(neopentyl)aluminum and partially…”
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A practical guide to metal ions dynamic nuclear polarization in materials science
Published in Journal of Magnetic Resonance Open (01-12-2024)“…•Metal-ions dynamic nuclear polarization (MI-DNP) is an efficient approach to increase NMR sensitivity in the bulk of inorganic solids.•A detailed strategy is…”
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Silica‐Grafted Tris(neopentyl)aluminum: A Monomeric Aluminum Solid Co‐catalyst for Efficient Nickel‐Catalyzed Ethene Dimerization
Published in Angewandte Chemie (07-09-2020)“…A silica‐supported monomeric alkylaluminum co‐catalyst was prepared via surface organometallic chemistry by contacting tris(neopentyl)aluminum and partially…”
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Eine Brücke zwischen industriellen und wohldefinierten Trägerkatalysatoren
Published in Angewandte Chemie (28-05-2018)“…Viele industrielle Katalysatoren enthalten isolierte Metallzentren an der Oberfläche von Oxidträgern. Derartige Katalysatoren werden seit über 40 Jahren bei…”
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Discerning γ‑Alumina Surface Sites with Nitrogen-15 Dynamic Nuclear Polarization Surface Enhanced NMR Spectroscopy of Adsorbed Pyridine
Published in Journal of physical chemistry. C (24-05-2018)“…Low-temperature 15N dynamic nuclear polarization surface enhanced NMR spectroscopy (DNP SENS) of adsorbed pyridine in combination with FTIR measurements and…”
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Propane Dehydrogenation on Ga 2 O 3 -Based Catalysts: Contrasting Performance with Coordination Environment and Acidity of Surface Sites
Published in ACS catalysis (15-01-2021)Get full text
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Eine Brücke zwischen industriellen und wohldefinierten Trägerkatalysatoren
Published in Angewandte Chemie (01-05-2018)“…Viele industrielle Katalysatoren enthalten isolierte Metallzentren an der Oberfläche von Oxidträgern. Derartige Katalysatoren werden seit über 40 Jahren bei…”
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