Search Results - "Mom, Sophal"
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Congested Ferrocenyl Polyphosphanes Bearing Electron-Donating or Electron-Withdrawing Phosphanyl Groups: Assessment of Metallocene Conformation from NMR Spin Couplings and Use in Palladium-Catalyzed Chloroarenes Activation
Published in Inorganic chemistry (21-11-2011)“…The synthesis of novel substituted cyclopentadienyl salts that incorporate both a congested branched alkyl group (tert-butyl, (triphenyl)methyl, or…”
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Direct Arylation of Heterocycles: The Performances of Ferrocene-Based Polyphosphane Ligands in Palladium-Catalyzed CH Bond Activation
Published in ChemCatChem (08-03-2010)“…The palladium‐catalyzed direct arylation of alkylated‐ furan, thiophene, and thiazole and benzoxazole heterocycles with electronically and sterically…”
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Versatile Palladium/Triphosphane System for Direct Arylation of Heteroarenes with Chloroarenes at Low Catalyst Loading
Published in Angewandte Chemie (International ed.) (03-09-2010)“…Put a ring on it: The use of an air‐stable, robust palladium/tridentate phosphane catalyst in direct CH and CCl activation reactions is reported (see scheme;…”
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Palladium-Catalyzed Direct Arylation of Heteroaromatics with Activated Aryl Chlorides Using a Sterically Relieved Ferrocenyl-Diphosphane
Published in ACS catalysis (01-06-2012)“…The palladium-catalyzed direct arylations at C3 or C4 positions of heteroaromatics are known to be more challenging than at C2 or C5 positions. Aryl chlorides…”
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Etherification of Functionalized Phenols with Chloroheteroarenes at Low Palladium Loading: Theoretical Assessment of the Role of Triphosphane Ligands in CO Reductive Elimination
Published in Advanced synthesis & catalysis (01-12-2011)“…The present study highlights the potential of robust tridentate ferrocenylphosphanes with controlled conformation as catalytic auxiliaries in CO bond…”
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Direct Arylation of Heteroaromatic Compounds with Congested, Functionalised Aryl Bromides at Low Palladium/Triphosphane Catalyst Loading
Published in Chemistry : a European journal (27-05-2011)“…A new ferrocenyl triphosphane ligand associated to palladium was found to be an efficient catalyst for the direct coupling of highly congested, functionalised…”
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Kinetic and Electrochemical Studies of the Oxidative Addition of Demanding Organic Halides to Pd(0): the Efficiency of Polyphosphane Ligands in Low Palladium Loading Cross-Couplings Decrypted
Published in Inorganic chemistry (21-10-2013)“…Oxidative addition (OA) of organic halides to palladium(0) species is a fundamental reaction step which initiates the C–C bond formation catalytic processes…”
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Palladium-catalyzed formation of secondary and tertiary amines from aryl dihalides with air-stable ferrocenyl tri- and diphosphines: Synthesis and X-ray structure of efficient catalysts beyond [PdCl2(DPPF)]
Published in Catalysis communications (05-06-2014)“…Robust, air-stable tridentate and bidentate ferrocenylphosphines 1,2-bis(diphenylphosphino)-1′-(diisopropylphosphino)-4-tert-butylferrocene, L5, and…”
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A Versatile Palladium-Triphosphane System for Direct Arylation of Heteroaromatics with Chlorides at Low Catalyst Loading
Published in Angewandte Chemie International Edition (2010)“…Put a ring on it: The use of an air-stable, robust palladium/tridentate phosphane catalyst in direct C[BOND]H and C[BOND]Cl activation reactions is reported…”
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A Versatile Palladium/Triphosphane System for Direct Arylation of Heteroarenes with Chloroarenes at Low Catalyst Loading
Published in Angewandte Chemie (03-09-2010)“…Ein luftbeständiger Palladiumkatalysator mit dreizähnigem Phosphanligand aryliert elektronenreiche wie elektronenarme mehrfach substituierte Furane (X=O),…”
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A Versatile Palladium/Triphosphane System for Direct Arylation of Heteroarenes with Chloroarenes at Low Catalyst Loading
Published in Angewandte Chemie (03-09-2010)Get full text
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