Search Results - "Moisy, Philippe"

Characterization of a Hexanuclear Plutonium(IV) Nanostructure in an Acetate Solution via Visible–Near Infrared Absorption Spectroscopy, Extended X‑ray Absorption Fine Structure Spectroscopy, and Density Functional Theory by Chupin, Geoffroy, Tamain, Christelle, Dumas, Thomas, Solari, Pier Lorenzo, Moisy, Philippe, Guillaumont, Dominique

“…A new hexanuclear plutonium cluster has been stabilized in aqueous media with acetate ligands. To probe the formation of such a complex structure, visible–near…”
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X‐ray absorption spectroscopy and actinide electrochemistry: a setup dedicated to radioactive samples applied to neptunium chemistry by Husar, Richard, Dumas, Thomas, Schlegel, Michel L., Schlegel, Daniel, Guillaumont, Dominique, Solari, Pier-Lorenzo, Moisy, Philippe

“…A spectroelectrochemical setup has been developed to investigate radioactive elements in small volumes (0.7 to 2 ml) under oxidation–reduction (redox)…”
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Molecular Dynamics Studies of Concentrated Binary Aqueous Solutions of Lanthanide Salts: Structures and Exchange Dynamics by Duvail, Magali, Ruas, Alexandre, Venault, Laurent, Moisy, Philippe, Guilbaud, Philippe

“…Concentrated binary aqueous solutions of lanthanide (Nd3+ and Dy3+) salts (ClO4 −, Cl−, and NO3 −) have been studied by means of classical molecular dynamics…”
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Multiparametric Dissolution of Thorium–Cerium Dioxide Solid Solutions by Claparede, Laurent, Clavier, Nicolas, Dacheux, Nicolas, Mesbah, Adel, Martinez, Julien, Szenknect, Stéphanie, Moisy, Philippe

“…The dissolution of Th1–x Ce x O2 solid solutions samples prepared by thermal conversion of oxalate precursors was studied by varying independently several…”
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Actinide speciation in relation to biological processes by Ansoborlo, Eric, Prat, Odette, Moisy, Philippe, Den Auwer, Christophe, Guilbaud, Philippe, Carriere, M., Gouget, Barbara, Duffield, John, Doizi, Denis, Vercouter, Thomas, Moulin, Christophe, Moulin, Valérie

“…In case of accidental release of radionuclides into the environment, actinides represent a severe health risk to human beings following internal contamination…”
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Is hydroxypyridonate 3,4,3-LI(1,2-HOPO) a good competitor of fetuin for uranyl metabolism? by Younes, Ali, Creff, Gaëlle, Beccia, Maria Rosa, Moisy, Philippe, Roques, Jérôme, Aupiais, Jean, Hennig, Christoph, Solari, Pier Lorenzo, Den Auwer, Christophe, Vidaud, Claude

“…Uranium is widespread in the environment, resulting both from natural occurrences and anthropogenic activities. Its toxicity is mainly chemical rather than…”
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Editorial: Fuel Cycle Simulation TWoFCS 2021 by Courtin, Fanny, Tillard, Léa, Álvarez-Velarde, Francisco, Moisy, Philippe

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Specific Interaction between Uranium Anionic Complexes and the Cations of Bis(trifluoromethylsulfonyl)imide Based Ionic Liquids by Cannes, Céline, Le Naour, Claire, Moisy, Philippe, Guilbaud, Philippe

“…The redox properties of uranium(IV) hexachloro complex have been investigated with a glassy carbon electrode in four bis(trifluoromethylsulfonyl)imide (Tf2N–)…”
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Thermodynamic Study of the Complexation of Trivalent Actinide and Lanthanide Cations by ADPTZ, a Tridentate N-Donor Ligand by Miguirditchian, Manuel, Guillaneux, Denis, Guillaumont, Dominique, Moisy, Philippe, Madic, Charles, Jensen, Mark P., Nash, Kenneth L.

“…To better understand the bonding in complexes of f-elements by polydentate N-donor ligands, the complexation of americium(III) and lanthanide(III) cations by…”
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Determination of formation constants of uranyl(VI) complexes with a hydrophilic SO3-Ph-BTP ligand, using liquid-liquid extraction by Steczek, Lukasz, Narbutt, Jerzy, Charbonnel, Marie-Christine, Moisy, Philippe

“…Complex formation between uranyl ion, UO , and a hydrophilic anionic form of SO -Ph-BTP ligand, L , in water was studied by liquid-liquid extraction…”
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Structural and spectroscopic studies of the complex [BuMeIm] 2[UCl 6] in the solid state and in hydrophobic room temperature ionic liquid [BuMeIm][Tf 2N] by Nikitenko, Sergey I., Hennig, Christoph, Grigoriev, Mikhail S., Naour, Claire Le, Cannes, Celine, Trubert, Didier, Bossé, Emilie, Berthon, Claude, Moisy, Philippe

“…Single-crystal XRD data of the complex [BuMeIm] 2[UCl 6] reveal the existence of a hydrogen bond between the most acidic H atom of the imidazolium ring (C2)…”
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Electrochemical Behavior of Ce(IV)/Ce(III) Couple in N,N‐Di(2‐ethylhexyl)‐n‐butanamide (DEHBA), N,N‐Di(2‐ethylhexyl)‐iso‐butanamide (DEHiBA), and N,N‐Di(2‐ethylhexyl)‐3,3‐dimethyl Butanamide (DEHDMBA) by Amoudji, Amivi Felicite, Arpigny, Sylvie, Moisy, Philippe, Bedioui, Fethi

“…In this work we report on the electrochemical behavior of Ce(IV)/Ce(III) redox couple in pure N,N‐dialkyl amides (N,N‐DA), namely…”
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Dissolution of Th$_{0.25}$U$_{0.75}$O$_2$ sintered pellets: Impact of nitrate ions and nitrous acid by Dalger, Thomas, Claparede, Laurent, Szenknect, Stéphanie, Moisy, Philippe, Dacheux, Nicolas

“…In order to gain insights on the kinetics of the dissolution of Gen(IV) MOX fuels, sintered pellets of Th$_{0.25}$U$_{0.75}$O$_2$ were prepared as surrogates…”
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Pourbaix Diagram of Astatine Revisited: Experimental Investigations by Liu, Lu, Maurice, Rémi, Galland, Nicolas, Moisy, Philippe, Champion, Julie, Montavon, Gilles

“…The Pourbaix diagram of an element displays its stable chemical forms with respect to the redox potential and pH of the solution, whose knowledge is…”
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Real-Time Observation of Solvation Dynamics of Electron in Actinide Extraction Binary Solutions of Water and n‑Tributyl Phosphate by Bahry, Teseer, Denisov, Sergey A, Moisy, Philippe, Ma, Jun, Mostafavi, Mehran

“…The excess electron in solution is a highly reactive radical involved in various radiation-induced reactions. Its solvation state critically determines the…”
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Dipolar and Contact Paramagnetic NMR Chemical Shifts in An IV Complexes with Dipicolinic Acid Derivatives by Islam, Md. Ashraful, Autillo, Matthieu, Guérin, Laetitia, Tamain, Christelle, Moisy, Philippe, Bolvin, Hélène, Berthon, Claude

“…Actinide +IV complexes (AnIV = ThIV, UIV, NpIV, and PuIV) with two dipicolinic acid derivatives (DPA and Et-DPA) have been studied by 1H and 13C NMR…”
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Macrocyclic Ligand Coordinating Amide-Arm Hydrolysis Reaction Activation in Aqueous Solutions: Tetravalent Uranium Does It Better by Dovrat, Gev, Pevzner, Svetlana, Maimon, Eric, Bogoslavsky, Benny, Ben-Eliyahu, Yeshayahu, Moisy, Philippe, Bettelheim, Armand, Zilbermann, Israel

“…Chelation of lanthanide and actinide cations within a suitable macrocyclic ligand often results in a rigid, kinetically inert, and thermodynamically stable…”
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Dipolar and contact paramagnetic NMR chemical shifts in An$^{IV}$ complexes with dipicolinic acid derivatives by Islam, Md. Ashraful, Autillo, Matthieu, Guérin, Laetitia, Tamain, Christelle, Moisy, Philippe, Bolvin, Hélène, Berthon, Claude

“…Actinide +IV complexes (AnIV = ThIV, UIV, NpIV, and PuIV) with two dipicolinic acid derivatives (DPA and Et-DPA) have been studied by 1H and 13C NMR…”
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Multiparametric Study of the Synthesis of ThSiO4 under Hydrothermal Conditions by Estevenon, Paul, Welcomme, Eleonore, Szenknect, Stephanie, Mesbah, Adel, Moisy, Philippe, Poinssot, Christophe, Dacheux, Nicolas

“…A multiparametric study of the hydrothermal synthesis of ThSiO4, thorite, was performed with the aim of determining the most efficient conditions to form…”
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Speciation and chemical behavior of molybdenum in uranium dioxide samples prepared by hydroxide precipitation by Husainy, Mohammad, Szenknect, Stéphanie, Podor, Renaud, Le Goff, Xavier, Kaczmarek, Thibault, Moisy, Philippe, Dacheux, Nicolas

“…This work aims to investigate the behavior of Mo in UO2±x for being an abundant fission product with a high fission yield and a complex speciation linked to…”
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