Cationic hydrogel and graphene oxide based cationic hydrogel with embedded palladium nanoparticles in the aerobic oxidation of olefins

Cationic hydrogel and graphene oxide based cationic hydrogel with embedded palladium nanoparticles in the aerobic oxidation of olefins

Poly(3-acrylamidopropyl) trimethyl ammonium chloride, p(APMACl), has been synthesized from (3-acrylamidopropyl) trimethyl ammonium chloride, (APTMACl), via free radical polymerization reaction technique under mild conditions. In addition, in the presence of cationic monomer APTMACl, graphene oxide (...

Full description

Saved in:
Bibliographic Details
Published in:Journal of porous materials Vol. 26; no. 2; pp. 433 - 441
Main Authors: Ghorbanloo, Massomeh, Moharramkhani, Nafiseh, Yazdely, Tahereh Mokary, Monfared, Hassan Hosseini
Format: Journal Article
Language:English
Published: New York Springer US 01-04-2019
Springer Nature B.V
Subjects:
Alkenes
Ammonium chloride
Atomic absorption analysis
Atomic beam spectroscopy
Atomic properties
Catalysis
Catalysts
Catalytic activity
Cations
Characterization and Evaluation of Materials
Chemical synthesis
Chemistry
Chemistry and Materials Science
Fourier transforms
Free radical polymerization
Free radicals
Graphene
Hydrogels
Microscopy
Morphology
Nanoparticles
Oxidation
Palladium
Physical Chemistry
Porous materials
Scanning electron microscopy
Transmission electron microscopy
Graphene oxide
Oxidation
Nano-catalyst
Ionic liquid
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Poly(3-acrylamidopropyl) trimethyl ammonium chloride, p(APMACl), has been synthesized from (3-acrylamidopropyl) trimethyl ammonium chloride, (APTMACl), via free radical polymerization reaction technique under mild conditions. In addition, in the presence of cationic monomer APTMACl, graphene oxide (GO) forms supramolecular stable hydrogel, p(APTMACl)/GO. P(APTMACl) and p(APTMACL)/GO have been successfully utilized for the in situ synthesis and stabilization of Pd nanoparticles within the hydrogel matrix. These hydrogel composites were characterized by Fourier transform infrared (FT-IR), field-emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM) and atomic absorption spectroscopy (AA). The morphology of the p(APTMACl) reveals the formation of homogeneous and highly porous material. Catalytic activity of p(APTMACl)-Pd and p(APTMACL)/GO-Pd catalysts were investigated in the aerobic oxidation of olefins by emphasizing the effects of different parameters such as temperature, substituent effect, etc. Under similar experimental conditions, catalyst p(APTMACl)/GO-Pd resulted in higher oxidation conversion than p(APTMACl)-Pd. The catalyst was easily recovered from the reaction medium and it could be re-used for other three runs without significant loss of activity.
ISSN:1380-2224
1573-4854
DOI:10.1007/s10934-018-0620-5