Search Results - "Mohandas, Janet C."
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Synthesis and Characterization of Cationic Tetramethyl Tantalum(V) Complex
Published in Catalysts (01-11-2018)“…A novel method for the synthesis of the homogeneous homoleptic cationic tantalum(V)tetramethyl complex [(TaMe4)+ MeB(C6F5)3−] from neutral tantalumpentamethyl…”
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From single-site tantalum complexes to nanoparticles of Ta x N y and TaO x N y supported on silica: elucidation of synthesis chemistry by dynamic nuclear polarization surface enhanced NMR spectroscopy and X-ray absorption spectroscopy
Published in Chemical science (Cambridge) (01-08-2017)“…Air-stable catalysts consisting of tantalum nitride nanoparticles represented as a mixture of Ta N and TaO N with diameters in the range of 0.5 to 3 nm…”
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Fischer–Tropsch synthesis: Attempt to tune FTS and WGS by alkali promoting of iron catalysts
Published in Applied catalysis. A, General (01-12-2010)“…[Display omitted] ▶ Effect of water on FT synthesis. ▶ Comparison of alkali promoters on iron catalysts. ▶ Methane selectivity increase with increase in water…”
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Fischer-Tropsch Synthesis: Effect of Water Over Iron-Based Catalysts
Published in Catalysis letters (01-12-2010)“…The effect of water on the performance of potassium-promoted precipitated iron catalyst was investigated during Fischer-Tropsch synthesis (FTS) using a…”
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From single-site tantalum complexes to nanoparticles of TaxNy and TaOxNy supported on silica: elucidation of synthesis chemistry by dynamic nuclear polarization surface enhanced NMR spectroscopy and X-ray absorption spectroscopy
Published in Chemical science (Cambridge) (01-08-2017)“…Air-stable catalysts consisting of tantalum nitride nanoparticles represented as a mixture of TaxNy and TaOxNy with diameters in the range of 0.5 to 3 nm…”
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From single-site tantalum complexes to nanoparticles of TaxNy and TaOxNy supported on silica: elucidation of synthesis chemistry by dynamic nuclear polarization surface enhanced NMR spectroscopy and X-ray absorption spectroscopyElectronic supplementary information (ESI) available: Complete experimental procedures, supporting characterization techniques, data and the details for the prepared compounds are provided. See DOI: 10.1039/c7sc01365e
Published 24-07-2017“…Air-stable catalysts consisting of tantalum nitride nanoparticles represented as a mixture of Ta x N y and TaO x N y with diameters in the range of 0.5 to 3 nm…”
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From single-site tantalum complexes to nanoparticles of Ta x N y and TaO x N y supported on silica: elucidation of synthesis chemistry by dynamic nuclear polarization surface enhanced NMR spectroscopy and X-ray absorption spectroscopy† †Electronic supplementary information (ESI) available: Complete experimental procedures, supporting characterization techniques, data and the details for the prepared compounds are provided. See DOI: 10.1039/c7sc01365e Click here for additional data file
Published in Chemical science (Cambridge) (08-06-2017)“…SOMC is exploited for synthesizing very fine nanoparticles of Ta x N y /TaO x N y on silica, elucidating the strategies with DNP SENS and EXAFS. Air-stable…”
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Facile and Efficient Synthesis of the Surface Tantalum Hydride (SiO)2TaIIIH and Tris-Siloxy Tantalum (SiO)3TaIII Starting from Novel Tantalum Surface Species (SiO)TaMe4 and (SiO)2TaMe3
Published in Organometallics (10-03-2014)“…By grafting of TaMe5 (1) on the surface of silica partially dehydroxylated at 500 °C (silica500), a mixture of (SiO)TaMe4 (2a; major, 65 ± 5%) and…”
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