Search Results - "Moad, Graeme"

Mechanism and Kinetics of Dithiobenzoate-Mediated RAFT Polymerization - Status of the Dilemma by Moad, Graeme

“…Dithiobenzoates are among the most popular agents for reversible addition‐fragmentation chain transfer (RAFT) polymerization. This is attributed to the better…”
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Reversible-deactivation radical polymerization (Controlled/living radical polymerization): From discovery to materials design and applications by Corrigan, Nathaniel, Jung, Kenward, Moad, Graeme, Hawker, Craig J., Matyjaszewski, Krzysztof, Boyer, Cyrille

“…Reversible-deactivation radical polymerization (RDRP) processes, such as atom transfer radical polymerization (ATRP), reversible addition-fragmentation chain…”
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A 20th anniversary perspective on the life of RAFT (RAFT coming of age) by Moad, Graeme, Rizzardo, Ezio

“…RAFT (reversible addition–fragmentation chain transfer) polymerization, making use of thiocarbonylthio transfer agents, was announced to the world just over 21…”
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A Critical Survey of Dithiocarbamate Reversible Addition‐Fragmentation Chain Transfer (RAFT) Agents in Radical Polymerization by Moad, Graeme

“…ABSTRACT This article provides a critical review of the properties, synthesis, and applications of dithiocarbamates Z′Z″NC(=S)SR as mediators in reversible…”
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RAFT Polymerization and Some of its Applications by Moad, Graeme, Rizzardo, Ezio, Thang, San H.

“…Reversible addition–fragmentation chain transfer (RAFT) is one of the most robust and versatile methods for controlling radical polymerization. With…”
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Synthesis of Discrete Oligomers by Sequential PET‐RAFT Single‐Unit Monomer Insertion by Xu, Jiangtao, Fu, Changkui, Shanmugam, Sivaprakash, Hawker, Craig J., Moad, Graeme, Boyer, Cyrille

“…Uniform synthetic polymers with precisely defined molar mass and monomer sequence (primary structure) have many potential high‐value applications. However, a…”
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Radical-promoted single-unit monomer insertion (SUMI) [aka. reversible-deactivation radical addition (RDRA)] by Boyer, Cyrille, Kamigaito, Masami, Satoh, Kotaro, Moad, Graeme

“…We survey progress in the development of the processes for radical-promoted single-unit monomer insertion (SUMI) or reversible deactivation radical addition…”
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Terminology for reversible-deactivation radical polymerization previously called "controlled" radical or "living" radical polymerization (IUPAC Recommendations 2010) by Jenkins, Aubrey D., Jones, Richard G., Moad, Graeme

“…This document defines terms related to modern methods of radical polymerization, in which certain additives react reversibly with the radicals, thus enabling…”
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End-functional polymers, thiocarbonylthio group removal/transformation and reversible addition-fragmentation-chain transfer (RAFT) polymerization by Moad, Graeme, Rizzardo, Ezio, Thang, San H

“…This review focuses on processes for thiocarbonylthio group removal/transformation of polymers synthesized by radical polymerization with reversible…”
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RAFT Emulsion Polymerization for (Multi)block Copolymer Synthesis: Overcoming the Constraints of Monomer Order by Khan, Murtaza, Guimarães, Thiago R, Choong, Kenneth, Moad, Graeme, Perrier, Sébastien, Zetterlund, Per B

“…Synthesis of (multi)­block copolymers using reversible addition–fragmentation chain transfer (RAFT) polymerization generally suffers from the limitation that…”
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Fundamentals of reversible addition–fragmentation chain transfer (RAFT) by Moad, Catherine L., Moad, Graeme

“…Abstract Radical polymerization is transformed into what is known as reversible addition–fragmentation chain transfer (RAFT) polymerization by the addition of…”
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Discrete and Stereospecific Oligomers Prepared by Sequential and Alternating Single Unit Monomer Insertion by Huang, Zixuan, Noble, Benjamin B, Corrigan, Nathaniel, Chu, Yingying, Satoh, Kotaro, Thomas, Donald S, Hawker, Craig J, Moad, Graeme, Kamigaito, Masami, Coote, Michelle L, Boyer, Cyrille, Xu, Jiangtao

“…Natural biopolymers, such as DNA and proteins, have uniform microstructures with defined molecular weight, precise monomer sequence, and stereoregularity along…”
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Anthraquinone-Mediated Reduction of a Trithiocarbonate Chain-Transfer Agent to Initiate Electrochemical Reversible Addition–Fragmentation Chain Transfer Polymerization by Strover, Lisa T, Postma, Almar, Horne, Michael D, Moad, Graeme

“…A goal in applying electrochemical methods to reversible addition–fragmentation chain transfer (RAFT) polymerization is to use electrochemical reduction to…”
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Light‐Induced RAFT Single Unit Monomer Insertion in Aqueous Solution—Toward Sequence‐Controlled Polymers by Aerts, Annelore, Lewis, Reece W., Zhou, Yanyan, Malic, Nino, Moad, Graeme, Postma, Almar

“…First report on the sequential, visible light‐initiated, single unit monomer insertion (SUMI) of N,N‐dimethylacrylamide (DMAm) into the reversible addition…”
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Thiocarbonylthio End Group Removal from RAFT-Synthesized Polymers by Radical-Induced Reduction by Chong, Yen K, Moad, Graeme, Rizzardo, Ezio, Thang, San H

“…The removal of thiocarbonylthio groups from polymers synthesized by radical polymerization with reversible addition−fragmentation chain transfer (RAFT) by…”
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Selective Bond Cleavage in RAFT Agents Promoted by Low‐Energy Electron Attachment by Izadi, Farhad, Arthur‐Baidoo, Eugene, Strover, Lisa T., Yu, Li‐Juan, Coote, Michelle L., Moad, Graeme, Denifl, Stephan

“…Radical polymerization with reversible addition‐fragmentation chain transfer (RAFT polymerization) has been successfully applied to generate polymers of…”
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Selective and Rapid Light‐Induced RAFT Single Unit Monomer Insertion in Aqueous Solution by Zhou, Yanyan, Zhang, Zhengbiao, Reese, Cassandra M., Patton, Derek L., Xu, Jiangtao, Boyer, Cyrille, Postma, Almar, Moad, Graeme

“…The photocatalyst Zn(II) meso‐tetra(4‐sulfonatophenyl)porphyrin (ZnTPPS) is found to substantially accelerate visible‐light‐initiated (red, yellow, green…”
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Switchable Reversible Addition–Fragmentation Chain Transfer (RAFT) Polymerization in Aqueous Solution, N,N-Dimethylacrylamide by Keddie, Daniel J, Guerrero-Sanchez, Carlos, Moad, Graeme, Rizzardo, Ezio, Thang, San H

“…Reversible addition–fragmentation chain transfer (RAFT) polymerization of a “more activated monomer” (MAM), N,N-dimethylacrylamide (DMAm), has been…”
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Initiation of RAFT Polymerization: Electrochemically Initiated RAFT Polymerization in Emulsion (Emulsion eRAFT), and Direct PhotoRAFT Polymerization of Liquid Crystalline Monomers by Bray, Caroline, Li, Guoxin, Postma, Almar, Strover, Lisa T, Wang, Jade, Moad, Graeme

“…We report on two important advances in radical polymerization with reversible addition–fragmentation chain transfer (RAFT polymerization). (1)…”
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Effect of Scandium Triflate on the RAFT Copolymerization of Methyl Acrylate and Vinyl Acetate Controlled by an Acid/Base “Switchable” Chain Transfer Agent by Tselepy, Ashton, Schiller, Tara L, Harrisson, Simon, Guerrero-Sanchez, Carlos, Moad, Graeme, Keddie, Daniel J

“…Modulation of the activity of an acid/base switchable dithiocarbamate RAFT agent, cyanomethyl (4-fluorophenyl)­(pyridin-4-yl)­carbamodithioate, with the Lewis…”
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