Search Results - "Mkhalid, Ibraheem A. I"
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Diboron(4) Compounds: From Structural Curiosity to Synthetic Workhorse
Published in Chemical reviews (24-08-2016)“…Although known for over 90 years, only in the past two decades has the chemistry of diboron(4) compounds been extensively explored. Many interesting structural…”
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C−H Activation for the Construction of C−B Bonds
Published in Chemical reviews (10-02-2010)“…Chemical reactions involving the activation of carbon-hydrogen bonds for the purpose of forming carbon-boron bonds are examined. The barriers to cleavage of…”
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Synthesis of 2- and 2,7-Functionalized Pyrene Derivatives: An Application of Selective CH Borylation
Published in Chemistry : a European journal (16-04-2012)“…An efficient synthetic route to 2‐ and 2,7‐substituted pyrenes is described. The regiospecific direct CH borylation of pyrene with an iridium‐based catalyst,…”
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Ir-Catalyzed Borylation of CH Bonds in N-Containing Heterocycles: Regioselectivity in the Synthesis of Heteroaryl Boronate Esters
Published in Angewandte Chemie International Edition (09-01-2006)“…Blocking the way: Substitution at the 2‐position in pyridines and other N‐heterocycles blocks N‐coordination to an Ir center. This steric hindrance provides a…”
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Structural Versatility of Pyrene-2-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolane) and Pyrene-2,7-bis(4,4,5,5-tetramethyl-[1,3,2]dioxaborolane)
Published in Crystal growth & design (06-06-2012)“…Three polymorphs of pyrene-2,7-bis(Bpin)2 (1) and two of pyrene-2-(Bpin) (2), where Bpin = 4,4,5,5-tetramethyl-[1,3,2]dioxaborolane, two different 1:1…”
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Synthesis of Heterobimetallic Gold(I) Palladium(II) Bis(acyclic diaminocarbene) Complexes via the Isonitrile Route
Published in Organometallics (28-03-2022)“…A convenient one-pot approach to bridged heterobimetallic gold(I) palladium(II) bis(acyclic diaminocarbene) complexes is presented. The methodology exploits…”
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Sequential Au/Cu Catalysis: A Two Catalyst One‐Pot Protocol for the Enantioselective Synthesis of Oxazole α‐Hydroxy Esters via Intramolecular Cyclization/Intermolecular Alder‐Ene Reaction
Published in Advanced synthesis & catalysis (05-06-2018)“…A convenient protocol for the enantioselective synthesis of oxazole α‐hydroxy ester derivatives 4 from readily available propargylamides 1 and alkylglyoxylates…”
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Comparative study of the antiproliferative activity of heterometallic carbene gold(i)-platinum(ii) and gold(i)-palladium(ii) complexes in cancer cell lines
Published in Chemical science (Cambridge) (29-08-2024)“…The stepwise, one-pot synthesis of heterobimetallic carbene gold(i) platinum(ii) complexes from readily available starting materials is presented. The…”
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Iridium-catalyzed C-H borylation of pyridines
Published in Organic & biomolecular chemistry (07-10-2014)“…The iridium-catalysed C-H borylation is a valuable and attractive method for the preparation of aryl and heteroaryl boronates. However, application of this…”
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10
Ir-Catalyzed Borylation of CH Bonds in N-Containing Heterocycles: Regioselectivity in the Synthesis of Heteroaryl Boronate Esters
Published in Angewandte Chemie (09-01-2006)“…Den Weg verstellt: Substituenten in der 2‐Position von Pyridinen und anderen N‐Heterocyclen verhindern die Koordination von N an ein Ir‐Zentrum. Diese…”
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11
Synthesis of 2- and 2,7-Functionalized Pyrene Derivatives: An Application of Selective CH Borylation
Published in Chemistry : a European journal (16-04-2012)“…An efficient synthetic route to 2- and 2,7-substituted pyrenes is described. The regiospecific direct CH borylation of pyrene with an iridium-based catalyst,…”
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