Search Results - "Miyakawa, Sho"
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A syn-Selective Aza-Aldol Reaction of Boron Aza-Enolates Generated from N-Sulfonyl-1,2,3-Triazoles and 9-BBN-H
Published in Angewandte Chemie International Edition (18-07-2016)“…A syn‐selective aza‐aldol reaction of boron aza‐enolates, generated from N‐sulfonyl‐1,2,3‐triazoles and 9‐BBN‐H, is reported. It provides a sequential one‐pot…”
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Journal Article -
2
Synthesis of Tetraarylphosphonium Salts from Triarylphosphines and Aryl Bromides Exploiting Light and Palladium
Published in Chemistry letters (05-05-2022)“…We herein report that an onium salt-forming reaction of triarylphosphines with aryl bromides is promoted by the sequential cooperation of light with palladium…”
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3
A DFT Mechanistic Study on the Aza-Aldol Reaction of Boron Aza-Enolates: Relative Stability of Six-Membered Transition State and Its Relevance to the Coordination Mode of the Leaving Group
Published in Journal of organic chemistry (04-10-2024)“…The mechanism of the aza-aldol reaction between boron aza-enolate and benzaldehyde is investigated by using density functional theory calculations. The result…”
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4
Highly Enantioselective Radical Cation [2 + 2] and [4 + 2] Cycloadditions by Chiral Iron(III) Photoredox Catalysis
Published in Journal of the American Chemical Society (19-07-2023)“…Radical cations show a unique reactivity that is fundamentally different from that of conventional cations and have thus attracted considerable attention as…”
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5
Generation of Boron Aza-Enolates by a Nickel-catalyzed Reaction of Triazoles with Pinacolborane and Their Addition to Aldehydes
Published in Chemistry letters (05-08-2019)“…An aldol-type reaction of boron aza-enolates with aldehydes is reported. N-Sulfonyl-1,2,3-triazoles react with pinacolborane in the presence of a nickel(0)…”
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6
Synthesis of Alkyl Sulfones from Alkenes and Tosylmethylphosphonium Iodide through Photo-promoted C–C Bond Formation
Published in Chemistry letters (05-11-2020)“…A new synthetic method for alkyl sulfones through C–C bond formation between alkenes and tosylmethylphosphonium iodide is reported. A tosylmethyl radical is…”
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7
A syn-Selective Aza-Aldol Reaction of Boron Aza-Enolates Generated from N-Sulfonyl-1,2,3-Triazoles and 9-BBN-H
Published in Angewandte Chemie (18-07-2016)“…A syn‐selective aza‐aldol reaction of boron aza‐enolates, generated from N‐sulfonyl‐1,2,3‐triazoles and 9‐BBN‐H, is reported. It provides a sequential one‐pot…”
Get full text
Journal Article