Search Results - "Misochko, Eugenii Ya"

Molecular Conformations and Magnetic Parameters of the Compact Trimethylenemethane-Type Triplet Diradical by Misochko, Eugenii Ya, Korchagin, Denis V, Akimov, Alexander V, Masitov, Artem A, Tolstikov, Svyatoslav E, Tretyakov, Evgeny V, Ovcharenko, Victor I

“…The ESR spectrum of compact nitroxide (NO)-substituted nitronyl nitroxide (NN) triplet diradical…”
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Quintet Dinitrenes with Negative Zero-Field Splitting: Effect of Spin–Orbit Coupling on the Sign of Magnetic Anisotropy by Korchagin, Denis V., Akimov, Alexander V., Savitsky, Anton, Chapyshev, Sergei V., Misochko, Eugenii Ya

“…We report on W-band EPR and quantum chemical investigation of novel organic tetraradicals with negative axial zero-field splitting (ZFS) parameter D. These…”
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Purely Spectroscopic Determination of the Spin Hamiltonian Parameters in High-Spin Six-Coordinated Cobalt(II) Complexes with Large Zero-Field Splitting by Misochko, Eugenii Ya, Akimov, Alexander V, Korchagin, Denis V, Nehrkorn, Joscha, Ozerov, Mykhaylo, Palii, Andrew V, Clemente-Juan, Juan Modesto, Aldoshin, Sergey M

“…Accurate determination of the spin Hamiltonian parameters in transition-metal complexes with large zero-field splitting (ZFS) is an actual challenge in…”
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Single-Ion Magnet Et4N[CoII(hfac)3] with Nonuniaxial Anisotropy: Synthesis, Experimental Characterization, and Theoretical Modeling by Palii, Andrew V, Korchagin, Denis V, Yureva, Elena A, Akimov, Alexander V, Misochko, Eugenii Ya, Shilov, Gennady V, Talantsev, Artem D, Morgunov, Roman B, Aldoshin, Sergey M, Tsukerblat, Boris S

“…In this article we report the synthesis and structure of the new Co­(II) complex Et4N­[CoII­(hfac)3] (I) (hfac = hexafluoroacetylacetonate) exhibiting…”
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Unexpected effect of substituents on the zero-field splitting of triplet phenyl nitrenes by Korchagin, Denis V., Akimov, Alexander V., Yureva, Elena A., Aldoshin, Sergei M., Misochko, Eugenii Ya

“…[Display omitted] •The ZFS of the triplet phenyl nitrenes with heavy Br atoms is discussed.•DFT calculations reproduce the experimental observation.•The SOC…”
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Steric Heavy Atom Effect on Magnetic Anisotropy of Triplet Tribromophenyl Nitrenes by Korchagin, Denis V, Akimov, Alexander V, Savitsky, Anton, Chapyshev, Sergei V, Aldoshin, Sergey M, Misochko, Eugenii Ya

“…Previously unknown the steric heavy atom effect on magnetic anisotropy parameters of triplet phenyl nitrenes is reported. The heavy bromine atom effect is…”
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Heavy Atom Effect on Magnetic Anisotropy of Matrix-Isolated Monobromine Substituted Septet Trinitrene by Misochko, Eugenii Ya, Masitov, Artem A, Akimov, Alexander V, Korchagin, Denis V, Chapyshev, Sergei V

“…The heavy atom effect on the magnetic anisotropy of septet trinitrenes is reported. Septet 1-bromo-3,5-dichloro-2,4,6-trinitrenobenzene (S-1) was generated in…”
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Molecular Structure and Magnetic Parameters of Septet 2,4,6-Trinitrenotoluene by Chapyshev, Sergei V, Misochko, Eugenii Ya, Akimov, Alexander V, Dorokhov, Viktor G, Neuhaus, Patrik, Grote, Dirk, Sander, Wolfram

“…Septet 2,4,6-trinitrenotoluene is the major paramagnetic product formed during the photolysis of 2,4,6-triazidotoluene in cryogenic matrices. This trinitrene…”
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Single-Ion Magnet Et 4 N[Co II (hfac) 3 ] with Nonuniaxial Anisotropy: Synthesis, Experimental Characterization, and Theoretical Modeling by Palii, Andrew V, Korchagin, Denis V, Yureva, Elena A, Akimov, Alexander V, Misochko, Eugenii Ya, Shilov, Gennady V, Talantsev, Artem D, Morgunov, Roman B, Aldoshin, Sergey M, Tsukerblat, Boris S

“…In this article we report the synthesis and structure of the new Co(II) complex Et N[Co (hfac) ] (I) (hfac = hexafluoroacetylacetonate) exhibiting single-ion…”
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Infrared spectroscopic observation of the radical • XeF 3 generated in solid argon by Misochko, Eugenii Ya, Akimov, Alexander V., Belov, Vasilii A., Tyurin, Daniil A.

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Infrared spectroscopic observation of the radical •XeF3 generated in solid argon by Misochko, Eugenii Ya, Akimov, Alexander V, Belov, Vasilii A, Tyurin, Daniil A

“…Xenon trifluoride radicals were generated by the solid-state chemical reaction of mobile fluorine atoms with XeF2 molecules isolated in a solid argon matrix…”
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Molecular Conformations and Magnetic Parameters of the Compact Trimethylenemethane-Type Triplet Diradical by MISOCHKO, Eugenii Ya, KORCHAGIN, Denis V, AKIMOV, Alexander V, MASITOV, Artem A, TOLSTIKOV, Svyatoslav E, TRETYAKOV, Evgeny V, OVCHARENKO, Victor I

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High selectivity of fluorine atom addition to the asymmetric chemical bonds of C70 fullerene by Misochko, Eugenii Ya, Akimov, Alexander V., Belov, Vasilii A., Tyurin, Daniil A., Laikov, Dmitry N.

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High selectivity of fluorine atom addition to the asymmetric chemical bonds of C 70 fullerene by Misochko, Eugenii Ya, Akimov, Alexander V., Belov, Vasilii A., Tyurin, Daniil A., Laikov, Dmitry N.

“…New assignment of EPR spectra of low-temperature F + C 70 reaction products shows an unexpectedly high selectivity of the addition of the F atom to the…”
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Molecular Structure and Magnetic Parameters of Septet 2,4,6-Trinitrenotoluene by CHAPYSHEV, Sergei V, MISOCHKO, Eugenii Ya, AKIMOV, Alexander V, DOROKHOV, Viktor G, NEUHAUS, Patrik, GROTE, Dirk, SANDER, Wolfram

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Photochemical Formation and Reaction of Radical Pairs from NH 3 −F 2 Complexes Isolated in Solid Argon by Akimov, Alexander V., Goldschleger, Ilia U., Misochko, Eugenii Ya, Wight, Charles A.

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Infrared Spectroscopic Observation of the Stabilized Intermediate Complex FO 3 Formed by Reaction of Mobile Fluorine Atoms with Ozone Molecules Trapped in an Argon Matrix by Misochko, Eugenii Ya, Akimov, Alexander V., Wight, Charles A.

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Infrared Spectroscopic Observation of the Stabilized Intermediate Complex FO3 Formed by Reaction of Mobile Fluorine Atoms with Ozone Molecules Trapped in an Argon Matrix by Misochko, Eugenii Ya, Akimov, Alexander V, Wight, Charles A

“…Chemical reaction of F atoms with O3 molecules in a solid argon matrix was studied with FTIR spectroscopy. Fluorine atoms were generated by UV photolysis of F2…”
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Photochemical Formation and Reaction of Radical Pairs from NH3−F2 Complexes Isolated in Solid Argon by Akimov, Alexander V, Goldschleger, Ilia U, Misochko, Eugenii Ya, Wight, Charles A

“…Photoinduced reactions in binary NH3−F2 complexes in solid argon are studied by FTIR spectroscopy. Analysis of the IR spectra and kinetics of product formation…”
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Addition reactions of translationally hot fluorine atoms as a probe of long-range migration in crystalline argon: F+CO by Misochko, Eugenii Ya, Akimov, Alexander V., Wight, Charles A.

“…Reactions of F atoms were studied in freestanding crystals (FSC) of argon doped with F 2 and CO. Laser photolysis of the F 2 at 355 nm produces stabilized FCO…”
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