Search Results - "Mingos, D. Michael P."
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Circumventing Redox Chemistry: Synthesis of Transition Metal Boryl Complexes from a Boryl Nucleophile by Decarbonylation
Published in Journal of the American Chemical Society (05-11-2014)“…The very strong reducing capabilities of the boryllithium nucleophile (THF)2Li{B(NDippCH)2} (1, Dipp = 2,6-iPr2C6H3) render impractical its use for the direct…”
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2
Tetrameric Iridium Hydride-Rich Clusters Formed under Hydrogenation Conditions
Published in Angewandte Chemie (International ed.) (01-01-2009)“…Butterfly clusters: Hydrogenation of a cationic iridium complex with the sterically bulky N‐ligand tetrahydroquinoline (thq) leads to the formation of two…”
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3
Cobalt Boryl Complexes: Enabling and Exploiting Migratory Insertion in Base-Metal-Mediated Borylation
Published in Angewandte Chemie International Edition (10-08-2015)“…Cobalt boryl complexes, which have only been sporadically reported, can be accessed systematically with remarkable (but controllable) variation in the nature…”
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4
Anion-Templated Synthesis of Metallacages as a Means for the Colorimetric Detection of Chlorides
Published in Inorganic chemistry (29-11-2004)“…In the presence of chloride or bromide in the appropriate mixture of solvents, 6 equiv of nickel(II) and 8 equiv of Hatu [Hatu = H2NC(NH)NHC(S)NH2] assemble…”
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5
Development of Bonding Models Based on the Periodic Table
Published in Chimia (27-03-2019)“…Kossel and Lewis' description of the chemical bonding in ionic and covalent compounds in 1916 made an important contribution, which connected the Periodic…”
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6
Effects of microwave dielectric heating on heterogeneous catalysis
Published in Catalysis letters (01-05-2003)“…The effect of microwave dielectric heating on both endothermic and exothermic reactions was investigated. Apparent equilibrium shifts for both reactions were…”
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7
Anion-Templated Syntheses of Rhombohedral Silver-Alkynyl Cage Compounds
Published in Angewandte Chemie International Edition (17-09-2001)“…A templating anion is a must for the formation of the cage compounds [Ag14(C≡CtBu)12X]OH (X=Cl, Br), in which a rhombic dodecahedron of silver atoms surrounds…”
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8
Crabtree's catalyst revisited; ligand effects on stability and durability
Published in Chemical communications (Cambridge, England) (01-01-2008)“…The extent of time-dependent deactivation of monophosphine monoamine iridium hydrogenation catalysts by trimer formation is strongly dependent on ligand…”
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9
Carbon dioxide reforming of methane with Pt catalysts using microwave dielectric heating
Published in Catalysis letters (01-06-2003)“…Microwave heating was applied to the catalytic reforming reaction of methane with carbon dioxide over platinum catalysts. It was found that CO2 and CH4…”
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10
Anion Control in the Self-Assembly of a Cage Coordination Complex
Published in Angewandte Chemie International Edition (18-05-1998)“…An anion is encapsulated in the center of the new cage compound [Ni6(atu)8X]X3 (X=Cl—for the structure see picture—or Br; Hatu=amidinothiourea). A combination…”
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11
Further studies on oscillations over nickel wires during the partial oxidation of methane
Published in Catalysis letters (01-03-2003)“…Oscillatory reactions over nickel wires during the partial oxidation of methane were investigated in a tubular continuous flow reactor made of quartz at…”
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12
Cobalt Boryl Complexes: Enabling and Exploiting Migratory Insertion in Base-Metal-Mediated Borylation
Published in Angewandte Chemie (10-08-2015)“…Cobalt boryl complexes, which have only been sporadically reported, can be accessed systematically with remarkable (but controllable) variation in the nature…”
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13
Dielectric properties of MoS2 and Pt catalysts: effects of temperature and microwave frequency
Published in Catalysis letters (01-12-2002)“…The effects of temperature and microwave frequency on the dielectric properties of MoS2 and Pt catalysts together with an aluminum oxide support were…”
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14
Microwave Dielectric Heating Behavior of Supported MoS2 and Pt Catalysts
Published in Industrial & engineering chemistry research (27-06-2001)“…The temperature of supported MoS2 and Pt catalysts was measured during microwave heating at constant input power by inserting a thermocouple into the center of…”
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15
Rate oscillations during partial oxidation of methane over chromel-alumel thermocouples
Published in Catalysis letters (01-04-2001)“…A chromel–alumel thermocouple has been found to catalyse the methane/oxygen reaction, the main products being CO, H2 with some CO2 and H2O. Regular…”
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16
Oscillatory behaviour during the oxidation of methane over palladium metal catalysts
Published in Applied catalysis. A, General (10-02-2003)“…Oscillatory reactions over palladium foil and wire catalysts during the oxidation of methane have been investigated over a wide range of reaction temperatures…”
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Electronic Structure of Linearly Coordinated EQ Complexes of the Type [(N3N)W(EQ)] [N3N = N(CH2CH2NSiMe3)3; E = P, As, Sb, Bi; Q = O, S, Se, Te]: A DFT Study
Published in European Journal of Inorganic Chemistry (01-06-2007)“…Density functional theory (DFT) calculations were carried out on the terminal EQ complexes [(N3N)W(EQ)] {N3N = N(CH2CH2NSiMe3)3; E = P, As, Sb, Bi; Q = O, S,…”
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Oxidative coupling of methane using microwave dielectric heating
Published in Applied catalysis. A, General (20-08-2003)“…Microwave heating was applied in the oxidative coupling of methane to higher hydrocarbons over alumina supported La 2O 3/CeO 2 catalysts. It was found that…”
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19
Polyhedral skeletal electron pair approach
Published in Accounts of chemical research (01-09-1984)Get full text
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20
A theoretical analysis of ambivalent and ambiphilic Lewis acid/bases with symmetry signatures
Published in Coordination chemistry reviews (15-06-2015)“…•DFT calculations have been completed which define the relative abilities of ligands to adopt non-linear and non-planar geometries.•The trans-influences of…”
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