Search Results - "Minato, Makoto"

Formation of Metal-coordinated Doubly Chelating Pentadentate Ligands by the Reactions of [MoH4(Ph2PCH2CH2PPh2)2] with Organohydrodisilanes by Minato, Makoto, Nanami, Toshiki, Kogoma, Kenzi, Ito, Takashi

“…Thermal reaction of [MoH4(dppe)2] (dppe = Ph2PCH2CH2PPh2) with RR′HSiSiHRR′ (R = Ph, Me, t-Bu; R′ = Me, H) occurs with formation of molybdenum silyl complexes,…”
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Coordination studies of 1,2-bis(diphenylphosphino)ethane with di-μ-hydroxo dinuclear complexes of tungsten(IV) and molybdenum(IV) by Minato Makoto, Ito Takashi, Ren Jian-Guo

“…The new trifluoroethoxo phosphine complexes [Cp2M(η1-dppe)(CF3CH2O)]+ and [Cp2(CF3CH2O)M(μ-dppe)MCp2(CF3CH2O)]2+ (M = Mo or W, Cp = η-C5H5 and dppe =…”
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Synthesis of the new chiral tridentate ligand bis(pyrid-2-ylethyl) menthylphosphine and its use in the palladium-catalyzed allylic alkylations by Minato, Makoto, Kaneko, Takefumi, Masauji, Shogo, Ito, Takashi

“…A new asymmetric P, N, N′-tridentate ligand (bis(pyrid-2-ylethyl) menthylphosphine, BPEMP), containing two pyridyl rings and (1 S,2 R,5 S)-menthylphosphino…”
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Dehydropolymerization of arylsilanes catalyzed by a novel silylmolybdenum complex by Minato, Makoto, Matsumoto, Takaomi, Ichikawa, Miyuki, Ito, Takashi

“…A complex [MoH3(Si(Ph)[Ph2PCH2CH2P(Ph)C6H4-o]2)] (1) can act as single-component catalyst for dehydrogenative polymerization of ArSiH2R (Ar = Ph, p-tolyl,…”
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Synthesis and Crystal Structure of N-Heterocyclic Carbene Complexes of Bis(η5-cyclopentadienyl)molybdenum by Yamaguchi, Yoshitaka, Oda, Ryoji, Sado, Katsunori, Kobayashi, Kimiko, Minato, Makoto, Ito, Takashi

“…The one-pot reaction of [Mo(η5-C5H5)2(H)(OTs)] (1) with 1,3-diisopropylimidazolium chloride (IiPr·HCl, 2a) in the presence of two equivalents of KOtBu in THF…”
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Reactions of 1-Alkynes with a Molybdenum-Silyl Complex: Stable σ-Acetylide Complexes Containing a Pentadentate Ligand Comprised of a P 2 SiP 2 Framework by Minato, Makoto, Watanabe, Kyosuke, Maeda, Kengo

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Osmium tetraoxide catalyzed vicinal hydroxylation of higher olefins by using hexacyanoferrate(III) ion as a cooxidant by Minato, Makoto, Yamamoto, Keiji, Tsuji, Jiro

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Reactions of 1-Alkynes with a Molybdenum-Silyl Complex: Stable σ-Acetylide Complexes Containing a Pentadentate Ligand Comprised of a P2SiP2 Framework by Minato, Makoto, Watanabe, Kyosuke, Maeda, Kengo

“…Reactions of molybdenum-silyl hydrido complex 2 ([MoH3{Si(Ph)[Ph2PCH2CH2P(Ph)C6H4-o]2}]) with 1.5 equiv of 1-alkynes RC≡CH occur readily at room temperature…”
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Molybdenum Hydrido Complex Containing a Novel Quinquidentate (P,P,Ge,P,P) Ligand by Minato, Makoto, Hirabayashi, Ryo, Matsumoto, Takaomi, Yamaguchi, Yoshitaka, Ito, Takashi

“…The reaction of [MoH4(Ph2PCH2CH2PPh2)2] with PhGeH3 or Ph2GeH2 resulted in the formation of a novel molybdenum–germyl complex…”
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Formation of Metal-coordinated Doubly Chelating Pentadentate Ligands by the Reactions of [MoH4(Ph2PCH2CH2PPh2)2] with Organohydrodisilanes by Minato, Makoto, Nanami, Toshiki, Kogoma, Kenzi, Ito, Takashi

“…Thermal reaction of [MoH4(dppe)2] (dppe = Ph2PCH2CH2PPh2) with RR′HSiSiHRR′ (R = Ph, Me, t-Bu; R′ = Me, H) occurs with formation of molybdenum silyl complexes,…”
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One-pot synthesis of polysiloxanes using catalytic reaction of dihydroorganosilanes with DMF: A new approach to functional polysiloxanes by Minato, Makoto, Watanabe, Hiroshi, Shimizu, Takahiro, Shibuya, Takito, Yamamoto, Riko, Ishikura, Ken, Zhou, Da-Yang

“…•Synthesis of polysiloxanes bearing sensitive functional groups•The polymerization was catalyzed by silyl-molybdenum complexes•Using a chiral complex afforded…”
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Synthesis and Structural Characterization of the New Dioxygen Complexes of Molybdenum (IV) by Zhou, Da-Yang, Zhang, Li-Bin, Minato, Makoto, Ito, Takashi, Osakada, Kohtaro

“…The molybdenum trihydrido complexes, [MoH3{[Ph2PCH2CH2P(Ph)C6H4-o]2(Ar)Si-P,P,P,P,Si}], which were readily formed by the thermal reaction of…”
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Reactions of Molybdenum Hydrides with Organochlorosilanes: Silicon–Silicon Bond Formation under Mild Conditions by Asaeda, Takahiro, Lee, Joo Yeon, Watanabe, Kyosuke, Minato, Makoto

“…Reactions of molybdenum hydrides containing polydentate phosphinoalkylsilyl ligands with a number of chlorosilanes have been investigated; this has led to the…”
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Novel Concurrent Formation of Mo–Si and Si–C Bonds by the Reaction between [MoH4(Ph2PCH2CH2PPh2)2] and PhSiH3 by Zhou, Da-Yang, Minato, Makoto, Ito, Takashi, Yamasaki, Mikio

“…Reaction of [MoH4(Ph2PCH2CH2PPh2)2] with PhSiH3 in refluxing toluene yielded doubly chelated novel complexes with the Si–C–C–P–Mo framework as a result of the…”
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Reactions of Molybdenum Hydrides with Organochlorosilanes by Asaeda, Takahiro, Yeon Lee, Joo, Watanabe, Kyosuke, Minato, Makoto

“…Reactions of molybdenum hydrides containing polydentate phosphinoalkylsilyl ligands with a number of chlorosilanes have been investigated; this has led to the…”
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Syntheses and Spectroscopic Properties of Substituted Phthalimido Complexes of Molybdenum(II) by Minato, Makoto, Ikeya, Masatoshi, Ohkubo, Fumihiko, Ito, Takashi

“…[MoH2(OMe)2(dppe)2] reacts with a series of phthalimide derivatives, each of which contains an electron-donor, an electron-acceptor, or redox-active center, to…”
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Synthesis and Characterization of Novel Phosphido-Bridged Bimetallic Complexes of Molybdenum and Tungsten by Minato, Makoto, Nakamura, Takashi, Ito, Takashi, Koizumi, Takeaki, Osakada, Kohtaro

“…The phosphido-bridged molybdenum and tungsten complexes [Cp2M(H)(μ-PPh2)M′(H)Cp2]+(OTs)− (M, M′ = Mo, W) were prepared and characterized. The X-ray…”
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Reactivity Patterns of O 2 , CO 2 , Carboxylic Acids, and Triflic Acid with Molybdenum Silyl Hydrido Complexes Bearing Polydentate Phosphinoalkyl–Silyl Ligands: Pronounced Effects of Silyl Ligands on Reactions by Minato, Makoto, Zhou, Da-Yang, Sumiura, Ken-ichiro, Oshima, Yuki, Mine, Shigeki, Ito, Takashi, Kakeya, Masaki, Hoshino, Kei, Asaeda, Takahiro, Nakada, Takushi, Osakada, Kohtaro

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Molybdocenes and tungstenocenes derived from molybdenum(IV) and tungsten(IV) dihydride by Minato, Makoto, Ito, Takashi

“…Recent results of our studies on preparation of group 6 (Mo, W) metallocenes are reviewed. Molybdenum(IV) and tungsten(IV) dihydride Cp 2MH 2 (M = Mo, W; Cp =…”
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Synthesis and Some Reactions of Molybdenocene Derivatives Coordinated with the Chiral Carboxylato Ligands by Ito, Takashi, Wan, Lin-Ming, Minato, Makoto

“…Molybdenocene derivatives with some chiral carboxylato ligand of the types, Cp2MoH(OCOR*), Cp2Mo(OCOR*)2, Cp2MoH(OCO-E*-OCO)MoHCp2, [Cp2Mo(OCOR*)]+R*CO2−, are…”
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