Search Results - "Milsmann, Carsten"

Low power threshold photochemical upconversion using a zirconium() LMCT photosensitizer by Yang, Mo, Sheykhi, Sara, Zhang, Yu, Milsmann, Carsten, Castellano, Felix N

“…The current investigation demonstrates highly efficient photochemical upconversion (UC) where a long-lived Zr( iv ) ligand-to-metal charge transfer (LMCT)…”
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Delayed fluorescence from a zirconium(iv) photosensitizer with ligand-to-metal charge-transfer excited states by Zhang, Yu, Lee, Tia S., Favale, Joseph M., Leary, Dylan C., Petersen, Jeffrey L., Scholes, Gregory D., Castellano, Felix N., Milsmann, Carsten

“…Advances in chemical control of the photophysical properties of transition-metal complexes are revolutionizing a wide range of technologies, particularly…”
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Four-Coordinate Cobalt Pincer Complexes: Electronic Structure Studies and Ligand Modification by Homolytic and Heterolytic Pathways by Semproni, Scott P, Milsmann, Carsten, Chirik, Paul J

“…A family of cobalt chloride, methyl, acetylide and hydride complexes bearing both intact and modified tert-butyl substituted bis­(phosphino)­pyridine pincer…”
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Catalytic Hydrogenation Activity and Electronic Structure Determination of Bis(arylimidazol-2-ylidene)pyridine Cobalt Alkyl and Hydride Complexes by Yu, Renyuan Pony, Darmon, Jonathan M, Milsmann, Carsten, Margulieux, Grant W, Stieber, S. Chantal E, DeBeer, Serena, Chirik, Paul J

“…The bis(arylimidazol-2-ylidene)pyridine cobalt methyl complex, (iPrCNC)CoCH3, was evaluated for the catalytic hydrogenation of alkenes. At 22 °C and 4 atm of…”
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Long-Lived Photoluminescence of Molecular Group 14 Compounds through Thermally Activated Delayed Fluorescence by Gowda, Anitha S., Lee, Tia S., Rosko, Michael C., Petersen, Jeffrey L., Castellano, Felix N., Milsmann, Carsten

“…Photoluminescent molecules exploiting the sizable spin–orbit coupling constants of main group metals and metalloids to access long-lived triplet excited states…”
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Redox Chemistry of Bis(pyrrolyl)pyridine Chromium and Molybdenum Complexes: An Experimental and Density Functional Theoretical Study by Gowda, Anitha S, Petersen, Jeffrey L, Milsmann, Carsten

“…The three- and four-membered redox series [Cr­(MePDP)2] z (z = 1–, 2–, 3−) and [Mo­(MePDP)2] z (z = 0, 1–, 2–, 3−) were synthesized to study the redox…”
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N–N Bond Cleavage of 1,2-Diarylhydrazines and N–H Bond Formation via H‑Atom Transfer in Vanadium Complexes Supported by a Redox-Active Ligand by Milsmann, Carsten, Semproni, Scott P, Chirik, Paul J

“…Addition of stoichiometric quantites of 1,2-diaryl­hydrazines to the bis­(imino)­pyridine vanadium dinitrogen complex, [{( iPrBPDI)­V­(THF)}2(μ2-N2)] ( iPrBPDI…”
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Synthesis and Molecular and Electronic Structures of Reduced Bis(imino)pyridine Cobalt Dinitrogen Complexes: Ligand versus Metal Reduction by Bowman, Amanda C, Milsmann, Carsten, Hojilla Atienza, Crisita Carmen, Lobkovsky, Emil, Wieghardt, Karl, Chirik, Paul J

“…Sodium amalgam reduction of the aryl-substituted bis(imino)pyridine cobalt dihalide complexes (ArPDI)CoCl2 and (iPrBPDI)CoCl2 (ArPDI =…”
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Synthesis and Electronic Structure of Cationic, Neutral, and Anionic Bis(imino)pyridine Iron Alkyl Complexes: Evaluation of Redox Activity in Single-Component Ethylene Polymerization Catalysts by Tondreau, Aaron M, Milsmann, Carsten, Patrick, Andrew D, Hoyt, Helen M, Lobkovsky, Emil, Wieghardt, Karl, Chirik, Paul J

“…A family of cationic, neutral, and anionic bis(imino)pyridine iron alkyl complexes has been prepared, and their electronic and molecular structures have been…”
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Oxidation and Reduction of Bis(imino)pyridine Iron Dicarbonyl Complexes by Tondreau, Aaron M, Milsmann, Carsten, Lobkovsky, Emil, Chirik, Paul J

“…The oxidation and reduction of a redox-active aryl-substituted bis(imino)pyridine iron dicarbonyl has been explored to determine whether electron-transfer…”
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Synthesis and Structure of a Functionalized [9]Cycloparaphenylene Bearing Three Indeno[2,1‑a]fluorene-11,12-dione-2,9-diyl Units by Li, Shuangjiang, Aljhdli, Merfat, Thakellapalli, Haresh, Farajidizaji, Behzad, Zhang, Yu, Akhmedov, Novruz G, Milsmann, Carsten, Popp, Brian V, Wang, Kung K

“…A synthetic pathway to a functionalized [9]­cycloparaphenylene bearing three indeno­[2,1-a]­fluorene-11,12-dione-2,9-diyl units in the macrocyclic ring…”
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Synthesis, Electronic Structure, and Alkene Hydrosilylation Activity of Terpyridine and Bis(imino)pyridine Iron Dialkyl Complexes by Tondreau, Aaron M, Atienza, Crisita Carmen Hojilla, Darmon, Jonathan M, Milsmann, Carsten, Hoyt, Helen M, Weller, Keith J, Nye, Susan A, Lewis, Kenrick M, Boyer, Julie, Delis, Johannes G. P, Lobkovsky, Emil, Chirik, Paul J

“…Iron dialkyl complexes, [N3]Fe(CH2SiMe3)2, with three different classes of tridentate, nitrogen-based “[N3]” ligands, aryl-substituted bis(imino)pyridines,…”
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Oxidation and Reduction of Bis(imino)pyridine Iron Dinitrogen Complexes: Evidence for Formation of a Chelate Trianion by Tondreau, Aaron M, Stieber, S. Chantal E, Milsmann, Carsten, Lobkovsky, Emil, Weyhermüller, Thomas, Semproni, Scott P, Chirik, Paul J

“…Oxidation and reduction of the bis(imino)pyridine iron dinitrogen compound, (iPrPDI)FeN2 (iPrPDI = 2,6-(2,6-iPr2–C6H3–NCMe)2C5H3N) has been examined to…”
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Synthesis and Electronic Structure Determination of N-Alkyl-Substituted Bis(imino)pyridine Iron Imides Exhibiting Spin Crossover Behavior by Bowman, Amanda C, Milsmann, Carsten, Bill, Eckhard, Turner, Zoë R, Lobkovsky, Emil, DeBeer, Serena, Wieghardt, Karl, Chirik, Paul J

“…Three new N-alkyl substituted bis(imino)pyridine iron imide complexes, (iPrPDI)FeNR (iPrPDI = 2,6-(2,6-iPr2–C6H3–NCMe)2C5H3N; R = 1-adamantyl (1Ad),…”
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Synthesis, Electronic Structure, and Ethylene Polymerization Activity of Bis(imino)pyridine Cobalt Alkyl Cations by Hojilla Atienza, Crisita Carmen, Milsmann, Carsten, Lobkovsky, Emil, Chirik, Paul J.

“…A new spin on polymers: The title cations comprise low‐spin CoII centers with neutral bis(imino)pyridine chelating ligands. These complexes serve as…”
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Reversible Carbon–Carbon Bond Formation Induced by Oxidation and Reduction at a Redox-Active Cobalt Complex by Hojilla Atienza, Crisita Carmen, Milsmann, Carsten, Semproni, Scott P, Turner, Zoë R, Chirik, Paul J

“…The electronic structure of the diamagnetic pyridine imine enamide cobalt dinitrogen complex, (iPrPIEA)­CoN2 (iPrPIEA =…”
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Synthesis, Electronic Structure, and Catalytic Activity of Reduced Bis(aldimino)pyridine Iron Compounds: Experimental Evidence for Ligand Participation by Russell, Sarah K, Milsmann, Carsten, Lobkovsky, Emil, Weyhermüller, Thomas, Chirik, Paul J

“…The two-electron reduction chemistry of the aryl-substituted bis(aldimino)pyridine iron dibromide, (iPrPDAI)FeBr2 (iPrPDAI = 2,6-(2,6-iPr2-C6H3−NCH)2C5H3N),…”
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Redox-Induced N2 Hapticity Switching in Zirconocene Dinitrogen Complexes by Semproni, Scott P., Knobloch, Donald J., Milsmann, Carsten, Chirik, Paul J.

“…N2 shuffle: One‐electron reduction of the ansa‐zirconocene complex with a side‐on dinitrogen ligand furnished the corresponding anion in which the hapticity of…”
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Spin Crossover in a 3,5-Bis(2-pyridyl)-1,2,4-triazolate-Bridged Dinuclear Iron(II) Complex [{Fe(NCBH3)(py)}2(μ-L1)2] - Powder versus Single Crystal Study by Schneider, Caspar J., Cashion, John D., Chilton, Nicholas F., Etrillard, Céline, Fuentealba, Mauricio, Howard, Judith A. K., Létard, Jean-François, Milsmann, Carsten, Moubaraki, Boujemaa, Sparkes, Hazel A., Batten, Stuart R., Murray, Keith S.

“…The structural characteristics and physical properties of the 3,5‐bis(2‐pyridyl)‐1,2,4‐triazolate (L1) bridged dinuclear iron(II) spin‐crossover complex…”
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Striking Stabilization of Ni⁰(η⁶-Arene) Complexes by an Ylide-Like Silylene Ligand by Meltzer, Antje, Präsang, Carsten, Milsmann, Carsten, Driess, Matthias

“…The right mix does the trick: Elusive {Ni⁰(η⁶-arene)} moieties can be dramatically stabilized by the N-heterocyclic silylene ligand 1, which has a zwitterionic…”
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